preface to fifteenth edition

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THERMODYNAMIC PROPERTIES 6.151 TABLE 6.5 Critical Properties (Continued) Substance T c , C P c , atm P c ,MPa V c ,cm 3 ·mol 1 c ,g·cm 3 3-Hexanol 309.3 33.2 3.36 2-Hexanone 313.9 32.8 3.32 3-Hexanone 309.7 32.76 3.320 1-Hexene 231.0 31.64 3.206 348 0.242 cis-2-Hexene 245 32.4 3.28 351 0.240 trans-2-Hexene 243 32.3 3.27 351 0.240 cis-3-Hexene 244 32.4 3.28 350 0.240 trans-3-Hexene 246.8 32.1 3.25 350 0.240 Hexylcyclopentane 387.0 21.1 2.14 Hydrazine 380 14.5 1.47 96.1 0.333 Hydrogen (equilibrium) 240.17 12.77 1.294 65.4 0.0308 Hydrogen (normal) 239.91 12.8 1.297 65.0 0.0310 Hydrogen bromide 89.8 84.4 8.55 100.0 0.809 Hydrogen chloride 51.40 82.0 8.31 81.0 0.45 Hydrogen cyanide 183.5 53.2 5.39 139 0.195 Hydrogen deuteride 237.25 14.64 1.483 62.8 0.048 Hydrogen fluoride 188 64 6.5 69 0.29 Hydrogen iodide 150.7 82.0 8.31 131 0.976 Hydrogen selenide 137 88 8.9 Hydrogen sulfide 100.4 88.2 8.94 98.5 0.31 Icosafluorononane 251 15.4 1.56 Icosane 494 10.3 1.04 1190 0.237 1-Icosanol 497 12.0 1.22 Indane 411.8 39.0 3.95 381 0.310 Iodine 546 115 11.7 155 0.164 Iodobenzene 448 44.6 4.52 351 0.581 Iodoethane 281.0 Iodomethane 255 65 6.59 190 0.75 1-Iodopropane 323 Isobutyl acetate 288 31.2 3.16 414 0.281 Isobutylamine 246 40.2 4.07 284 0.258 Isobutylbenzene 377 30.1 3.05 480 0.280 Isobutyl bromide 294.1 Isobutyl butanoate 338 Isobutylcyclohexane 386 30.8 3.12 Isobutyl formate 278 38.3 3.88 350 0.29 Isobutyl isobutanoate 329 Isobutyl 3-methylbutanoate 348 Isobutyl propanoate 319 Isopentyl acetate 326 Isopentyl butanoate 346 Isopentyl propanoate 338 Isopropyl acetate 258 Isopropylamine 198.7 44.8 4.54 221 0.267 Isopropylbenzene 357.9 31.67 3.209 429 0.281 Isopropylcycloheptane 334.5 Isopropylcyclohexane 367 28 2.84 Isopropylcyclopentane 328 29.6 3.00 4-Isopropylheptane 334.5 22.0 2.23 537 0.265 Isopropylmethylamine 217.6 2-Isopropyl-1-methylbenzene 397 28.6 2.90 3-Isopropyl-1-methylbenzene 393 29.0 2.94 4-Isopropyl-1-methylbenzene 380 27.9 2.83
6.152 SECTION 6 TABLE 6.5 Critical Properties (Continued) Substance T c , C P c , atm P c ,MPa V c ,cm 3 ·mol 1 c ,g·cm 3 3-Isopropyl-2-methylhexane 359.3 22.6 2.29 529 0.269 Isopropyl methyl sulfide 276.4 Isoquinoline 530 50.3 5.10 374 0.345 Isoxazole 278.9 Ketene 380 64 6.5 145 0.290 Kryp<strong>to</strong>n 63.75 54.3 5.50 91.2 0.9085 Mercury 1477 1587 160.8 Mercury(II) bromide 789 Mercury(II) chloride 700 Mercury(II) iodide 799 Methane 82.60 45.44 4.604 99.0 0.162 Methanethiol 196.8 71.4 7.23 145 0.332 Methanol 239.4 79.78 8.084 118 0.272 Methoxybenzene 372.5 41.9 4.25 0.321 Methyl acetamide 417 Methyl acetate 233.40 46.9 4.75 228 0.325 Methyl acrylate 263 42 4.26 265 0.325 Methylamine 157.6 75.14 7.614 140 0.222 N-Methylaniline 428 51.3 5.20 373 0.287 Methyl benzoate 438 36 3.65 396 0.344 2-Methyl-1,3-butadiene 211 38.0 3.85 276 0.247 3-Methyl-1,3-butadiene 223 40.6 4.11 267 0.255 2-Methylbutane 187.3 33.4 3.38 306 0.236 2-Methyl-1-butanethiol 318.8 2-Methyl-2-butanethiol 297.0 Methyl butanoate 281.3 34.3 3.475 340 0.300 3-Methylbutanoicacid 356 33.6 3.40 2-Methyl-1-butanol 302.3 38.9 3.94 322 0.274 3-Methyl-1-butanol 304.1 38.8 3.93 329 0.268 2-Methyl-2-butanol 270.6 36.6 3.71 319 0.276 3-Methyl-2-butanol 283.0 38.2 3.87 3-Methyl-2-butanone 280.3 38.0 3.85 310 0.278 2-Methyl-1-butene 196.9 34.0 3.445 294 0.239 3-Methyl-1-butene 191.6 34.7 3.52 300 0.234 2-Methyl-2-butene 207.9 34.0 3.445 318 0.221 Methylcyclohexane 299.1 34.26 3.471 368 0.267 Methylcyclopentane 259.58 37.35 3.784 319 0.264 Methyl dodecanoate 439 758 0.283 N-Methylethylamine 223.5 36.6 3.71 243 0.243 Methyl formate 214.1 59.20 5.998 172 0.349 2-Methylfuran 254 46.6 4.72 247 0.333 2-Methylheptane 286.6 24.52 2.484 488 0.234 3-Methylheptane 290.6 25.13 2.546 464 0.246 4-Methylheptane 288.7 25.09 2.542 476 0.240 2-Methylhexane 257.3 26.98 2.734 421 0.238 3-Methylhexane 262.2 27.77 2.814 404 0.248 Methylhydrazine 294 79.3 8.035 271 0.170 Methyl 2-hydroxybenzoate 436 Methyl isobutanoate 267.7 33.9 3.43 339 0.301 Methyl isocyanate 218 55 5.57 1-Methylnaphthalene 499 35.5 3.60 445 0.320 2-Methylnaphthalene 488 34.6 3.51 462 0.308 2-Methyloctane 313.9 22.80 2.310
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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Page 646 and 647: THERMODYNAMIC PROPERTIES 6.101 TABL
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Page 704 and 705: SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
Page 706 and 707: SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
Page 712 and 713: SPECTROSCOPY 7.9 TABLE 7.3 Critical
Page 714 and 715: SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
Page 716 and 717: SPECTROSCOPY 7.13 Emission line K 1
Page 718 and 719: SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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Page 722 and 723: SPECTROSCOPY 7.19 TABLE 7.9 Electro
Page 724 and 725: SPECTROSCOPY 7.21 TABLE 7.11 Absorp
Page 726 and 727: SPECTROSCOPY 7.23 TABLE 7.13 Solven
Page 728 and 729: SPECTROSCOPY 7.25 7.3 FLUORESCENCE
Page 730 and 731: SPECTROSCOPY 7.27 TABLE 7.16 Fluore
Page 732 and 733: SPECTROSCOPY 7.29 TABLE 7.18 Detect
Page 738 and 739: SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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Page 742 and 743: SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.43 TABLE 7.20 Absorp
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
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11.94 SECTION 11 TABLE 11.30 Standa
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TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
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TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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