preface to fifteenth edition

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TABLE 3.2 Physical Constants of Inorganic Compounds (Continued) Name Formula Formula weight Density Melting point, C Boiling point, C Solubility in 100 parts solvent 3.16 Ammonium acetate (continued) hydrogen ()tartrate NH 4 HC 4 H 4 O 6 167.12 1.68 d 200 2.2 15 aq; i alc hydroxide NH 4 OH 35.05 77 49% dissolved NH 3 hypophosphite NH 4 H 2 PO 2 83.03 d v s aq; sl s alc; i acet iodate NH 4 IO 3 192.94 3.309 d 150 2.6 15 aq iodide NH 4 I 144.94 2.514 25 subl 551 220 vacuo 167 g/100 mL 20 aq; v s alc, acet lactate NH 4 C 3 H 5 O 3 107.11 1.2 15 92 v s aq, alc, glyc; i acet, eth magnesium arsenate NH 4 MgAsO 4 ·6H 2 O 289.36 1.923 d 0.038 20 aq 6-water molybdate(VI)(2)(NH 4 ) 2 MoO 4 196.04 25 2.276 4 d s acids nitrate NH 4 NO 3 80.04 1.725 25 169.6 d 210 g/100 mL: 192 20 aq; 3.8 20 alc; 17 20 MeOH; s acet octadecanoate NH 4 OOC(CH 2 ) 16 CH 3 301.50 21–22 sl s aq; s alc; i acet octanoate NH 4 OOC(CH 2 ) 6 CH 3 161.24 d on standing v s aq, alc, acet; sl s eth oxalate hydrate (NH 4 ) 2 C 2 O 4 ·H 2 O 142.11 1.50 d 70 5.1 20 aq; s alc oxodioxalatotitanate(IV)(NH 4 ) 2 TiO(C 2 O 4 ) 2 276.02 v s aq perchlorate NH 4 ClO 4 117.49 1.95 d 240 g/100 mL 25 : 21.9 aq, 1.49 EtOH, 0.014 BuOH, 0.029 EtOAc permanganate NH 4 MnO 4 136.97 2.208 10 explodes, 110 0.8 15 aq peroxodisulfate (NH 4 ) 2 S 2 O 8 228.20 1.982 d 120 expl 180 58 g/100 mL 0 aq phosphinate NH 4 PH 2 O 2 83.04 1.634 200 d 240 g/100 mL: 100 aq, 5 alc; i acet phosphomolybdate (NH 4 ) 3 PO 4 · 12MoO 3 ·H 2 O 1894.36 d sl s aq hydrate picrate NH 4 C 6 H 2 N 3 O 7 246.14 1.719 d expl 423 1.1 20 aq; sl s alc selenate(VI)(NH 4 ) 2 SeO 4 179.04 2.193 20 4 d 117 g/100 mL 7 aq; s HOAC; i alc stearate NH 4 C 18 H 35 O 2 301.51 0.89 22 sl s aq, bz; s alc; i acet sulfamate NH 4 NH 2 SO 3 114.13 131 d 160 v s aq; sl s alc sulfate (NH 4 ) 2 SO 4 132.14 1.769 20 d 280 43.5 g/100 mL 20 aq; i alc, acet sulfide (NH 4 ) 2 S 68.14 d 0 v s aq; s alc, alk sulfite hydrate (NH 4 ) 2 SO 3 ·H 2 O 134.16 1.41 d 60 75 g/100 mL 20 aq; i alc, acet ()tartrate (NH 4 ) 2 C 4 H 4 O 6 184.15 1.601 d 58 g/100 mL 15 aq; sl s alc tetraborate 4-water (NH 4 ) 2 B 4 O 7 ·4H 2 O 263.44 s aq; i alc
3.17 tetrachloroaluminate NH 4 [AlCl 4 ] 186.83 304 s aq, eth tetrachloropalladate(II)(NH 4 ) 2 [PdCl 4 ] 284.29 2.170 d v s aq; i abs alc tetrachloroplatinate(II)(NH 4 ) 2 [PtCl 4 ] 372.97 2.936 140 d s aq; i alc tetrachlorozincate (NH 4 ) 2 [ZnCl 4 ] 243.28 1.879 150 d subl 341 v s aq tetrafluoroborate NH 4 [BF 4 ] 104.84 1.871 subl 25 g/100 mL 16 aq thiocyanate NH 4 SCN 76.12 1.305 149.6 d 170 128 g/100 mL 0 aq; v s alc; s acet thiosulfate (NH 4 ) 2 S 2 O 3 148.21 1.679 d 150 2.15 15 aq; i alc, eth vanadate(V)(1)NH 4 VO 3 116.98 2.326 d 200 0.48 20 aq Antimony Sb 121.760(1)6.697 25 630.7 1587 s hot conc H 2 SO 4 , aqua regia arsenide SbAs 196.68 6.0 680 (III)bromide SbBr 3 361.47 4.35 96.6 280 s acet, bz, chl (III)chloride SbCl 3 228.12 3.14 20 4 73.4 220.3 10 g/100 mL 20 aq; s alc, bz, chl (V)chloride SCl 5 299.02 2.336 20 4 3.5 79 22mm d aq; s HCl, chl, CCl 4 (III)fluoride SbF 3 178.75 4.379 20 20 292 376 444 g/100 mL 20 aq (V)fluoride SbF 3 216.75 2.99 23 8.3 141 d viol aq; s HOAc; forms solids with alc, bz, CS 2 , eth hydride (stibine)SbH 3 124.78 5.475 g/L 91.5 18.4 20 mL/100 mL 20 aq; s CS 2 , alc (III)iodide SbI 3 502.47 4.92 168 401 g/100 g 25 : 1.16 bz, 1.24 tol, 0.16 chl (III)oxide (valentinite) Sb 2 O 3 291.52 5.7 655 1425 v sl s aq; s HCl, KOH (V)oxide Sb 2 O 3 323.52 3.78 O 2 , 300 v sl s aq; sl s warm KOH, eth (III)selenide Sb 2 Se 3 480.40 5.81 612 v sl s aq; s conc HCl (III)sulfate SB 2 (SO 4 ) 3 531.71 3.62 d sl s aq (III)sulfide Sb 2 S 3 339.72 4.56 546 0.002 20 aq (d); s H 2 SO 4 (V)sulfide Sb 2 S 5 403.85 4.120 75 d i aq; s HCl (d), NaOH (III)telluride Sb 2 Te 3 626.32 6.52 620 i aq; s HNO 3 triethyl Sb(C 2 H 5 ) 3 209.0 1.324 14 29 159.5 i aq trimethyl Sb(CH 3 ) 3 166.9 1.523 15 80.6 sl s aq Argon Ar 39.948(1)1.7824 g/L 0 189.38 185.87 3.36 mL/100 mL 20 aq Arsenic As 74.92159(2)5.727 25 4 817 subl 615 i aq; s HNO 3 (III)bromide AsBr 3 314.63 3.3972 25 4 31.1 220.0 hyd aq; s HCl, CS 2 ,PE (III)chloride AsCl 3 181.28 2.1497 25 4 16.2 130.2 misc chl, CCl 4 , eth; s HCl (di-)disulfide As 2 S 2 213.97 3.254 19 320 565 s alkali; v sl s bz (III)fluoride AsF 3 131.92 15 2.73 15 5.95 57.8 s alc, bz, eth, HF (V)fluoride AsF 5 169.91 7.46 g/L 79.8 52.8 hyd aq; s alc, bz, eth (III)hydride (arsine) AsH 3 77.95 3.420 g/L 116.9 62.5 28 mL/100 mL 20 aq; s bz, chl (III)iodide AsI 3 455.63 4.73 140.9 424 s bz, tol; sl s aq, alc, eth (III)oxide (arsenolite) As 2 O 3 197.84 3.86 274 460 1.8 20 aq; s alc
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
Page 1185 and 1186:
11.94 SECTION 11 TABLE 11.30 Standa
Page 1187 and 1188:
TABLE 11.32 Properties and Applicat
Page 1189 and 1190:
11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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Page 1229 and 1230:
11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
Page 1239 and 1240:
TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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