preface to fifteenth edition

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PHYSICAL PROPERTIES 5.3 5.1 SOLUBILITIES TABLE 5.1 Solubility of Gases in Water The column (or line entry) headed “” gives the volume of gas (in milliliters) measured at standard conditions (0C and 760 mm or 101.325 kN · m 2 ) dissolved in 1 mL of water at the temperature stated (in degrees Celsius) and when the pressure of the gas without that of the water vapor is 760 mm. The line entry “A” indicates the same quantity except that the gas itself is at the uniform pressure of 760 mm when in equilibrium with water. The column headed “1” gives the volume of the gas (in milliliters) dissolved in 1 mL of water when the pressureof thegas plus that of thewater vapor is 760 mm. The column headed “q” gives the weight of gas (in grams) dissolved in 100 g of water when the pressure of thegas plus that of thewater vapor is 760 mm. Acetylene Air* Ammonia Bromine Temp. C q (10 3 ) % oxygen in air q q 0 1.73 0.200 29.18 34.91 1130 89.5 60.5 42.9 1 1.68 0.194 28.42 34.87 — — — — 2 1.63 0.188 27.69 34.82 — — 54.1 38.3 3 1.58 0.182 26.99 34.78 — — — — 4 1.53 0.176 26.32 34.74 1047 79.6 48.3 34.2 5 1.49 0.171 25.68 34.69 — — — — 6 1.45 0.167 25.06 34.65 — — 43.3 30.6 7 1.41 0.162 24.47 34.60 — — — — 8 1.37 0.157 23.90 34.56 947 72.0 38.9 27.5 9 1.34 0.154 23.36 34.52 — — — — 10 1.31 0.150 22.84 34.47 870 68.4 35.1 24.8 11 1.27 0.146 22.34 34.43 — — — — 12 1.24 0.142 21.87 34.38 857 65.1 31.5 22.2 13 1.21 0.138 21.41 34.34 837 63.6 — — 14 1.18 0.135 20.97 34.30 — — 28.4 20.0 15 1.15 0.131 20.55 34.25 770 — — — 16 1.13 0.129 20.14 34.21 775 58.7 25.7 18.0 17 1.10 0.125 19.75 34.17 — — — — 18 1.08 0.123 19.38 34.12 — — 23.4 16.4 19 1.05 0.119 19.02 34.08 — — — — 20 1.03 0.117 18.68 34.03 680 52.9 21.3 14.9 21 1.01 0.115 18.34 33.99 — — — — 22 0.99 0.112 18.01 33.95 — — 19.4 13.5 23 0.97 0.110 17.69 33.90 — — — — 24 0.95 0.107 17.38 33.86 639 48.2 17.7 12.3 25 0.93 0.105 17.08 33.82 — — — — 26 0.91 0.102 16.79 33.77 — — 16.3 11.3 27 0.89 0.100 16.50 33.73 — — — — 28 0.87 0.098 16.21 33.68 586 44.0 15.0 10.3 29 0.85 0.095 15.92 33.64 — — — — 30 0.84 0.094 15.64 33.60 530 41.0 13.8 9.5 35 — — — — — — — — 40 — — 14.18 — 400 31.6 9.4 6.3 45 — — — — — — — — 50 — — 12.97 — 290 23.5 6.5 4.1 60 — — 12.16 — 200 16.8 4.9 2.9 70 — — — — — 11.1 3.8 1.9 80 — — 11.26 — — 6.5 3.0 1.2 90 — — — — — 3.0 — — 100 — — 11.05 — — 0.0 — — * Free from NH 3 and CO 2 ; <strong>to</strong>tal pressure of air water vapor is 760 mm.
TABLE 5.1 Solubility of Gases in Water (Continued) Temp. C Carbon dioxide q Carbon monoxide q l Chlorine q Ethane q Ethylene q Hydrogen q 0 1.713 0.334 6 0.035 37 0.004 397 — — 0.098 74 0.013 17 0.226 0.028 1 0.021 48 0.000 192 2 1 1.646 0.321 3 0.034 55 0.004 293 — — 0.094 76 0.012 63 0.219 0.027 2 0.021 26 0.000 190 1 2 1.584 0.309 1 0.033 75 0.004 191 — — 0.090 93 0.012 12 0.211 0.026 2 0.021 05 0.000 188 1 3 1.527 0.297 8 0.032 97 0.004 092 — — 0.087 25 0.011 62 0.204 0.025 3 0.020 84 0.000 186 2 4 1.473 0.287 1 0.032 22 0.003 996 — — 0.083 72 0.011 14 0.197 0.024 4 0.020 64 0.000 184 3 5 1.424 0.277 4 0.031 49 0.003 903 — — 0.080 33 0.010 69 0.191 0.023 7 0.020 44 0.000 182 4 6 1.377 0.268 1 0.030 78 0.003 813 — — 0.077 09 0.010 25 0.184 0.022 8 0.020 25 0.000 180 6 7 1.331 0.258 9 0.030 09 0.003 725 — — 0.074 00 0.009 83 0.178 0.022 0 0.020 07 0.000 178 9 8 1.282 0.249 2 0.029 42 0.003 640 — — 0.071 06 0.009 43 0.173 0.021 4 0.019 89 0.000 177 2 9 1.237 0.240 3 0.028 78 0.003 559 — — 0.068 26 0.009 06 0.167 0.020 7 0.019 72 0.000 175 6 10 1.194 0.231 8 0.028 16 0.003 479 3.148 0.997 2 0.065 61 0.008 70 0.162 0.020 0 0.019 55 0.000 174 0 11 1.154 0.223 9 0.027 57 0.003 405 3.047 0.965 4 0.063 28 0.008 38 0.157 0.019 4 0.019 40 0.000 172 5 12 1.117 0.216 5 0.027 01 0.003 332 2.950 0.934 6 0.061 06 0.008 08 0.152 0.018 8 0.019 25 0.000 171 0 13 1.083 0.209 8 0.026 46 0.003 261 2.856 0.905 0 0.058 94 0.007 80 0.148 0.018 3 0.019 11 0.000 169 6 14 1.050 0.203 2 0.025 93 0.003 194 2.767 0.876 8 0.056 94 0.007 53 0.143 0.017 6 0.018 97 0.000 168 2 15 1.019 0.197 0 0.025 43 0.003 130 2.680 0.849 5 0.055 04 0.007 27 0.139 0.017 1 0.018 83 0.000 166 8 16 0.985 0.190 3 0.024 94 0.003 066 2.597 0.823 2 0.053 26 0.007 03 0.136 0.016 7 0.018 69 0.000 165 4 17 0.956 0.184 5 0.024 48 0.003 007 2.517 0.797 9 0.051 59 0.006 80 0.132 0.016 2 0.018 56 0.000 164 1 18 0.928 0.178 9 0.024 02 0.002 947 2.440 0.773 8 0.050 03 0.006 59 0.129 0.015 8 0.018 44 0.000 162 8 19 0.902 0.173 7 0.023 60 0.002 891 2.368 0.751 0 0.048 58 0.006 39 0.125 0.015 3 0.018 31 0.000 161 6 5.4
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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PHYSICAL PROPERTIES 5.53 TABLE 5.9
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
Page 1008 and 1009:
NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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Page 1012 and 1013:
9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
Page 1078 and 1079:
10.60 SECTION 10 10.4.8 Polychlorop
Page 1080 and 1081:
10.62 SECTION 10 Styrene-butadiene
Page 1082 and 1083:
10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
Page 1090 and 1091:
TABLE 10.8 Constants ofWaxes Wax Me
Page 1092:
SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
Page 1099 and 1100:
11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
Page 1113 and 1114:
TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
Page 1123 and 1124:
11.32 SECTION 11 11.4.3 Ion-Exchang
Page 1125 and 1126:
11.34 SECTION 11 TABLE 11.16 Guide
Page 1127 and 1128:
11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
Page 1133 and 1134:
11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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Page 1175 and 1176:
11.84 SECTION 11 appears becomes le
Page 1177 and 1178:
11.86 SECTION 11 TABLE 11.29 Equati
Page 1179 and 1180:
11.88 SECTION 11 TABLE 11.29 Equati
Page 1181 and 1182:
11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
Page 1185 and 1186:
11.94 SECTION 11 TABLE 11.30 Standa
Page 1187 and 1188:
TABLE 11.32 Properties and Applicat
Page 1189 and 1190:
11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
Page 1195 and 1196:
11.104 SECTION 11 TABLE 11.44 Facto
Page 1197 and 1198:
11.106 SECTION 11 11.7 LABORATORY S
Page 1199 and 1200:
11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
Page 1203 and 1204:
11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
Page 1207 and 1208:
11.116 SECTION 11 Mercurous nitrate
Page 1209 and 1210:
11.118 SECTION 11 Potassium carbona
Page 1211 and 1212:
11.120 SECTION 11 until the ammoniu
Page 1213 and 1214:
11.122 SECTION 11 TABLE 11.49 TLV C
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Page 1221 and 1222:
11.130 SECTION 11 TABLE 11.50 Chemi
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Page 1227 and 1228:
Page 1229 and 1230:
11.138 SECTION 11 of water which is
Page 1231 and 1232:
TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
Page 1235 and 1236:
TABLE 11.58 Type J Thermocouples: I
Page 1237 and 1238:
TABLE 11.60 Type N Thermocouples: N
Page 1239 and 1240:
TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
Page 1243 and 1244:
Index Terms Links 2 Acid-base indic
Page 1245 and 1246:
Index Terms Links 4 Alkynes, nomenc
Page 1247 and 1248:
Index Terms Links 6 Aurintricarboxy
Page 1249 and 1250:
Index Terms Links 8 Boron-11 chemic
Page 1251 and 1252:
Index Terms Links 10 Cellulose acet
Page 1253 and 1254:
Index Terms Links 12 Collective ino
Page 1255 and 1256:
Index Terms Links 14 Degree Fahrenh
Page 1257 and 1258:
Index Terms Links 16 Electrical res
Page 1259 and 1260:
Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
Page 1263 and 1264:
Index Terms Links 22 Halogenated hy
Page 1265 and 1266:
Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
Page 1277 and 1278:
Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
Page 1289 and 1290:
Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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