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THERMODYNAMIC PROPERTIES 6.139 TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds (Continued) C p Substance Hm Hv Hs 400 K 600 K 800 K 1000 K SrCl 2 , Ht 6.0 727 17.5 248.1 356 78.9 83.7 90.8 105.8 SrCO 3 , Ht 19.7 924 40 95.1 107.1 116.1 124.0 SrF 2 , Ht 0.04 1148 28.5 320 451.0 74.7 79.8 81.0 85.8 Ht 0.04 1211 SrI 2 19.67 189.7 286.6 80.7 86.3 91.8(c) 110.0(lq) SrH 2 23 SrMoO 4 131.5 145.4 154.0 161.2 SrO 81 48.5 52.0 54.3 56.1 SrO 2 81.3 85.0 Sr(OH) 2 23 88.5 115.0(c) 157.8(lq) 157.8 SrS 63 50.2 53.2 54.9 56.2 SrSO 4 36 113.5 124.6 135.7 146.9 Sulfur S monoclinic 1.727 45 62.2 23.2 23.3(lq) 21.8(g) 21.5 Ht 0.400 95.2 S 8 167.1 177.9 186.7 193.6 SCl 2 32.4 53.6 56.0 56.9 57.4 S 2 Cl 2 36.0 124.3(lq) 80.8(g) 82.6 83.5 SF 4 26.4 87.5 97.3 101.7 103.8 SF 6 5.02 17.1 9.0 116.4 136.1 144.8 149.3 S 2 F 10 211.4 246.4 261.8 269.2 SO 2 7.40 24.94 22.92 43.43 48.9 52.3 54.3 SO 3 8.60 40.7 43.14 57.7 67.3 72.8 76.0 SOCl 2 31.7 31 71.3 76.4 78.9 80.3 SOF 2 21.8 64.3 72.4 76.4 78.6 SO 2 Cl 2 31.38 30.1 85.2 94.5 99.4 102.1 SO 2 ClF 81.1 92.1 97.9 101.1 SO 2 F 2 20.0 76.5 89.3 96.1 99.9 Tantalum Ta 36.57 732.8 778 25.8 26.8 27.5 27.9 TaB 2 83.7 57.6 66.6 72.2 83.3 TaBr 5 45.6 62.3 168.2 TaC 105 41.7 46.5 49.1 51.1 Ta 2 C 66.7 72.4 76.2 79.5 TaCl 5 41.6 54.8 94.1 148.(c) 129.(g) 131 132 TaF 5 18.8 56.9 182.0(lq) TaI 5 41.8 64.9 164.6 182.0(c) 120.0(g) 120.6 TaN 67 45.4 51.9 58.5 65.0 TaO 2 47.7 52.3 54.6 55.7 Ta 2 O 5 120 147.5 164.4 175.2 182.8 Technetium Tc 33.29 585.2 25.1 26.8 28.5 30.1 TcF 6 4.72 31.1 TcO 3 F 22.5 39.5 Tellurium Te 17.49 114.1 28.0 32.3(c) 37.7(lq) 37.7 TeCl 4 18.8 77 138.9(c) 222.6(lq) 108.8(g) 108.8 TeF 4 34.3 TeF 6 28.2 132.2 143.8 148.7 151.7 Te 2 F 10 39.5
6.140 SECTION 6 TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds (Continued) C p Substance Hm Hv Hs 400 K 600 K 800 K 1000 K TeH 2 23.9 TeO 2 29.1 67.9 72.5 76.1 79.2 Terbium Tb 10.15 293 389 Thallium Tl, Ht 0.38 234 4.14 165 181 27.5(c) 30.1(lq) 30.1 30.1 TlBr 16.4 99.6 53.5 59.5(c) 75.5(lq) 67.8 TlCl 15.56 102.2 53.6 55.2(c) 59.4(lq) 59.4 Tl 2 CO 3 18.4 TlF 13.87 115.9 66.8(lq) 67.3 TlI 14.73 104.7 53.9 60.6(c) 72.0(lq) 72.0 TlNO 3 9.56 Tl 2 O 30.3 Tl 2 O 3 53 Tl 2 S 12 154 Tl 2 SO 4 23.0 Thorium Th, Ht 2.73 1360 13.81 514 28.4 30.5 32.7 34.4 ThBr 4 66.9 ThCl 4 , Ht 5.0 406 40.2 146.4 126.7 132.7 136.4 139.6 ThF 4 44.0 258 ThI 4 61.4 56.9 Th 3 N 4 169.5 196.5 222.7 ThO 2 1218.0 67.4 72.4 75.3 77.7 ThOCl 2 97.0 102.5 105.9 108.6 Th(SO 4 ) 2 197.0 243.2 289.4 Thullium Tm 16.84 247 232.2 Tin Snwhite, Ht 2.09 13 7.03 296.1 28.9 28.9(c) 28.7(lq) 28.7 SnBr 2 7.2 102 SnBr 4 11.9 43.5 158.0(lq) 106.8(g) 107.3 107.5 SnCl 2 12.8 86.8 83.3(c) 92.1(lq) 92.1 92.1 SnCl 4 9.20 34.9 SnH 4 19.1 SnI 2 105 SnO 45.8 48.7 51.7 54.6 SnO 2 , Ht 1.88 410 64.4 73.9 78.5 81.8 Ht 1.26 540 SnS, Ht 0.67 602 50.5 55.5 61.3 SnS 2 71.9 75.4 79.0 82.5 Titanium Ti, Ht 4.2 893 14.15 425 469 26.9 28.6 29.5 32.1 TiB 40.3 48.6 50.9 51.9 TiB 2 100.4 54.9 66.2 72.1 76.9 TiBr 2 206.2 79.9 82.1 84.4 86.7 TiBr 3 138.8 105.8 125.5 147.3 156.7 TiBr 4 12.9 44.4 151.9(lq) 106.1(g) 106.9 107.3 TiC 71 40.7 47.7 49.9 51.2 TiCl 2 232 212 73.4 78.4 82.2 85.9
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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Page 634 and 635: THERMODYNAMIC PROPERTIES 6.89 TABLE
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Page 704 and 705: SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
Page 706 and 707: SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
Page 712 and 713: SPECTROSCOPY 7.9 TABLE 7.3 Critical
Page 714 and 715: SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
Page 716 and 717: SPECTROSCOPY 7.13 Emission line K 1
Page 718 and 719: SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
Page 720 and 721: SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
Page 722 and 723: SPECTROSCOPY 7.19 TABLE 7.9 Electro
Page 724 and 725: SPECTROSCOPY 7.21 TABLE 7.11 Absorp
Page 726 and 727: SPECTROSCOPY 7.23 TABLE 7.13 Solven
Page 728 and 729: SPECTROSCOPY 7.25 7.3 FLUORESCENCE
Page 730 and 731: SPECTROSCOPY 7.27 TABLE 7.16 Fluore
Page 732 and 733: SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.31 TABLE 7.18 Detect
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SPECTROSCOPY 7.33 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.43 TABLE 7.20 Absorp
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
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11.94 SECTION 11 TABLE 11.30 Standa
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TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
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TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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