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The Impact of Pesticides - Academy Publish

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Behavior <strong>of</strong> <strong>Pesticides</strong> and <strong>The</strong>ir Transformation Productsin River Water in JapanKuniaki Kawata and Tomohiro KoseINTRODUCTION<strong>Pesticides</strong> serve an important role in increasing agricultural productivity. Severalhundred different pesticides are used worldwide for agricultural production. InJapan, more than five hundred compounds are registered as pesticides foragricultural use. Manufactured pesticides exceeded 200 varieties and 250 metrickilotons in FY2009. Paddy rice farming has been playing an important role in cropproduction throughout the world. In Japan, paddy fields covered a total area <strong>of</strong>2.496 million ha, accounting for 54.3% <strong>of</strong> all land cultivated in FY2010.Approximately 170 pesticides designated for rice farming are applied to paddyfields in Japan.<strong>Pesticides</strong> applied to paddy fields have continually caused great concern because <strong>of</strong>pesticide run<strong>of</strong>fs into rivers: some fraction <strong>of</strong> the applied pesticides flow from thepaddy fields into the rivers through drainage channels. Numerous reports havedescribed pesticide behaviors in paddy fields and rivers in Japan. In this section, wesummarize the behaviors <strong>of</strong> applied pesticides on paddy fields and the run<strong>of</strong>f ratios<strong>of</strong> pesticides from paddy fields to rivers. Second, we describe the daily variation <strong>of</strong>pesticides based on hourly and bihourly variations. Third, the concentration levels <strong>of</strong>pesticides in river waters and the typical weekly variations <strong>of</strong> pesticideconcentrations are summarized. Fourth, we describe concentration levels <strong>of</strong> somepesticides and their transformation products in river water. Finally, from thestandpoint <strong>of</strong> the human health protection, we discuss the impact <strong>of</strong> some pesticidesregulated by the Environmental Quality Standard in Japan.FATES OF APPLIED PESTICIDES IN PADDY FIELDSInsecticides and fungicides are sprayed to paddy fields by aerial and groundapplications. A diagram <strong>of</strong> pesticides applied to a paddy field is presented in Fig. 1.Parts <strong>of</strong> the aerially applied pesticides exist in the air around the applied paddy areas(Kawata 2009). <strong>Pesticides</strong> in the air drift to leeward sites. <strong>The</strong>y can be a majorsource <strong>of</strong> that detected in the drainage channels and rivers immediately after aerialapplications (Yoshida et al. 2007). Most <strong>of</strong> the applied pesticides became distributedbetween the soil and water in the paddy fields.Regarding herbicides, most are applied by ground application (Amano et al. 2001,Maeda et al. 2008). <strong>The</strong> applied herbicides are dissolved or suspended in paddywater. Some pesticides in the paddy water are drained with drainage and leakage <strong>of</strong>the paddy water (Amano et al. 2001, Maeda et al. 2008, Morohashi et al. 2012). <strong>The</strong><strong>Academy</strong><strong>Publish</strong>.org - <strong>The</strong> <strong>Impact</strong> <strong>of</strong> <strong>Pesticides</strong>203

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