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Table 2. (Cont.)Pesticide concentrations in river waters in Japan.PesticideCASNo.Use*ConcentrationSite(ng/L)Max MeanPrefectMonth YearurePretilachlor 51218- H 80-5100 40-Apr.-Shin R. Niigata49-6270** Sep.490-5200 160- Shinano R. Niigata Apr.-PropyzamidePyributicarb2160-7270710–Drainagechannels470 – Miya R.310-740 –13600-156001550,2020160-420 –90 – Tsurumi R. Kanag 2008-awa 2009Sakai 20101996-Shin R.440Sep. 1997Mitobe et al. 199910 Yodo R. Osaka 2008 BYQ 2011H 40-1600 30- Shin R. Niigata Apr.- 1995-240*Sep. 1997Mitobe et al. 199923950-H 440-2600 400-58-588678-67-5Pyridaphen 119-thion 12-0Simazine122-34-9TadagawaR.Aug.Shiga May-Aug.Nagan Apr.-o Oct.Hyogo Apr.-Feb.KakogawaR.– Shiratori R. Shiga Apr.-Oct.– Sakura R. Ibaraki Apr.-Aug.Hyogo May-Nov.Apr.-Mar.Niigata Apr.-1995-1997ReferenceMitobe et al. 19991996 Tanabe et al. 200120022003-20072004-20052005,20062007,2008Sudo andKawachi 2006Ishimota et al.2010Yoshida andFujimori 2005Kawasaki et al.2008Iwafune et al.20102008 Suzuki et al. 2010I82-700 29-160 Shinano R. Niigata Apr.-Aug.78-90 –TadagawaHyogo Apr.-R.Feb.7.5 7.1 Shinano R. Niigata May-1900-10000160-920*Shin R.Jul.Niigata Apr.-Sep.22-140 22-59 Shinano R. Niigata Apr.-Aug.H 40 40 Shin R. Niigata Apr.-Sep.16-180 16-99 Shinano R. Niigata Apr.-Aug.May-40-180 – 40 rivers MieFeb.1996 Tanabe et al. 20012004-20052007,20081995-1997Yoshida andFujimori 2005Goto et al. 2009Mitobe et al. 19991996 Tanabe et al. 20011996 Mitobe et al. 19991996 Tanabe et al. 20011999,2000Hayakawa et al.2000AcademyPublish.org - The Impact of Pesticides212
Table 2. (Cont.)Pesticide concentrations in river waters in Japan.Pesticide CASNo.Simetryn 1014-70-6ThenylchlorThiobencarb96491-05-328249-77-6Thiuram 1634-02-2Tricycla 41814-zole 78-2Use* Concentration Site(ng/L)Max MeanPrefectMonth YearureH 910-2100 – Shin R. Niigata Apr.-Sep.230-1600 57-170 Shinano R. Niigata Apr.-1995-1997ReferenceMitobe et al. 19991996 Tanabe et al. 2001Aug.10200- 70- Drainage May- Sudo and KawachiShiga 200225100 80** channels Aug. 2006Nagan Apr.- 2003- Ishimota et al.80 – Miya R.o Oct. 2007 2010Tadagawa160 –Hyogo Apr.- 2004- Yoshida andR.Feb. 2005 Fujimori 200512700,Apr.- 2005, Kawasaki et al.– Shiratori R. Shiga49800Oct. 2006 20082310, 2340 – Sakura R. Ibaraki Apr.- 2007,Iwafune et al. 2010Aug. 2008Kakogawa42-510 –Hyogo May- 2008 Suzuki et al. 2010R.Nov.H 50-320 76-700 Shinano R. Niigata Apr.-Aug.H900-13900 –DrainagechannelsShiga880 – Shiratori R. Shiga2200, 3500 10,Apr.-Shin R. Niigata160** Sep.May-Aug.Apr.-Oct.17 8.2 Shinano R. Niigata May-Jul.126, 169 – Sakura R. Ibaraki Apr.-Aug.300-4300 50-83 Shinano R. Niigata Apr.-440800-1600 –40,70**Shin R.DrainagechannelsAug.Niigata Apr.-Sep.May-ShigaAug.35 11 Shinano R. Niigata May-Jul.2.6 – Agano R. Niigata May-16, 20 –KakogawaR.Jul.Hyogo May-Nov.1996 Tanabe et al. 20011996,1997200220052007,20082007,2008Mitobe et al. 1999Sudo and Kawachi2006Kawasaki et al.2008Goto et al. 2009Iwafune et al. 20101996 Tanabe et al. 20011996,199720022007,20082007,2008Mitobe et al. 1999Sudo and Kawachi2006Goto et al. 2009Goto et al. 20092008 Suzuki et al. 2010F 100 Yodo R. Osaka 2008 BYQ 2011F 30-510036-770030-4800**35-7700Shin R. NiigataApr.-Sep.Shinano R. Niigata Apr.-Aug.1995-1997Mitobe et al. 19991996 Tanabe et al. 2001* F, Fungicide; H, herbicide; I, insecticide. ** Median. ** Tsurumi R,.Sakai R. andKashiwao R.AcademyPublish.org - The Impact of Pesticides213
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The Impactof PesticidesEdited by:Pr
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Other access free resources from Ac
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The Impact of PesticidesPrepared an
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Table of Contentsp.203-p.224 Behavi
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About authorspublished by Elsevier.
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About authorsof medical researchers
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About authorsdifferent spatial scal
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About authorsEducation:Bachelor’s
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About authorsSensors - A Nanotechno
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Section 1HUMAN EXPOSURE TO PESTICID
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ecently explored on preliminary stu
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individuals within 1 day (Jokanovic
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occupational environmental health r
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must be considered, since effective
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Jensen BH, Petersen A, and Christen
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Ragas AMJ, and Huijbregts MAJ (1998
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Weichenthal S, Moase C, and Chan P
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human poisoning, general acute symp
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Management of the cholinergic syndr
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1982; Lotti, 1992; Jokanović et al
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exposed populations, revealed high
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DiazepamBenzodiazepines are CNS dep
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Among the many classes of oximes in
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inhibited by dichlorvos (a dimethox
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Dawson, 1995). It appears that the
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Eddleston M, Eyer P, Worek F, Moham
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Jokanović M, Kosanović M (2010b).
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Ray DE (1998). Chronic effects of l
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Worek F, Eyer P, Kiderlen D, Thierm
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developing countries is due to suic
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count and morphology, as well as se
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PON1 modulation of genetic damageFe
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elationship between OP exposure and
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Blatter-Garin MC, James RW, Dussoix
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Hung RJ, Hall J, Brennan P, Boffett
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Rojas-García AE., Solís-Heredia M
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Occupational Exposure to Pesticides
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considered as conditions typical of
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observed adverse health outcome. Su
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within cells can oxidize biomolecul
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of the study. A face-to-face questi
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PesticidesFungicideInsecticide-Nema
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Table 4. Mixtures of pesticides use
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In pesticide applicators, Table 7 s
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DISCUSSIONThe agricultural workers
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changes in the antioxidant enzyme C
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Bajpayee, M.; Pandey, A. K.; Parmar
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Environmental health criteria 155.
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Palus, J.; Rydzynski, K.; Dziubalto
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Singh, N.P.; McCoy, M.T.; Tice, R.R
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INTRODUCTIONPopulations may be occu
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exposure scenarios on the basis of
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not present adverse health effects
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greenhouse workers exposed to malat
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Paraoxon is then either metabolized
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cyclohexene-1,2-dicarboximide, CAS
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metabolite of phthalates, such that
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scenarios were simulated, assuming
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Table 2. Biological reference value
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References N a urinarybiomarkeStudi
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Figure 2. Representation of a BRV d
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Figure 4. Conceptual representation
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Figure 6 Conceptual representation
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REFERENCESACGIH, 2011. Documentatio
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Bradway, D.E., Shafik, T.M., 1977.
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EPA, 1999b. Registration Eligibilit
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Hines, C.J., Deddens, J.A., Jaycox,
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McCollister, S.B., Kociba, R.J., Hu
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Verberk, M.M., Brouwer, D.H., Brouw
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important IGFBP for binding IGF-1 i
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secretion of IGF-1 (Tannheimer et a
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FIGURESFig. 1. An “hormetic” ef
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Landi F, Capoluongo E, Russo A, Ond
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Smith WJ, Underwood LE, Clemmons DR
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Section 2PESTICIDES IN THEENVIRONME
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vicinity of subsoil waters and ther
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Hieracium pilosella, southernwood -
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formed clusters (Figure 3). Ultrast
Page 162 and 163: Fig. 5. Fragment of hepatocyte of t
Page 164 and 165: Szarek, J, Skibniewska, K, Wojtacka
Page 166 and 167: negative effects (ZALUCKI et al., 2
Page 168 and 169: Figure 2. Appropriated sampling pro
Page 170 and 171: Figure 4. Illustration of the conse
Page 172 and 173: (HAILE et al., 1998). Earlier resul
Page 174 and 175: Table 1. Distribution of the applic
Page 176 and 177: Means followed by the same letter i
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Page 180 and 181: efore the pest emergence and their
Page 182 and 183: Table 3 (continuation)…AcademyPub
Page 184 and 185: Table 5. Effect of different fungic
Page 186 and 187: Table 6. Magament used including do
Page 188 and 189: adopted by Brazilian soybean grower
Page 190 and 191: Pickle, C.S.; Caviness, C.E. Yield
Page 192 and 193: This chapter reports on Dutch surfa
Page 194 and 195: several different occasions at any
Page 196 and 197: The greatest number of pesticides a
Page 198 and 199: Accumulated ExceedanceIt is useful
Page 200 and 201: For the years 2003-2009 the calcula
Page 202 and 203: Bonzini S, Verro R, Otto S, Lazzaro
Page 204 and 205: atios of the pesticide amounts in t
Page 206 and 207: Table 1. (Cont.) Runoff ratios of p
Page 208 and 209: mefenacet and simetrin were observe
Page 210 and 211: Table 2. (Cont.)Pesticide concentra
Page 214 and 215: Fig. 3. Typical weekly variation of
Page 216 and 217: (BAM) in water (Pukkila et al. 2009
Page 218 and 219: Table 5. Concentrations of pesticid
Page 220 and 221: Table 6. Maximum concentrations of
Page 222 and 223: Iwafune, T, Inao, K, Horio, T, Iwas
Page 224 and 225: Suzuki, M, Takemine, S, Yoshida, M,
Page 226 and 227: factor, etc. Levels of pesticides i
Page 228 and 229: factor of 10 above ambient sea wate
Page 230 and 231: weight sample. Minimum were shown f
Page 232 and 233: Figure 3. DDTs in mussel samples fo
Page 234 and 235: Figure 5. HCB in mussel samples for
Page 236 and 237: Figure 8. Methoxychlor in mussel sa
Page 238 and 239: ACKNOWLEDGEMENTAuthors thank UNEP/M
Page 240 and 241: Pesticide Risk Index of Del Azul Wa
Page 242 and 243: on that presented in Swanson et al.
Page 244 and 245: eference value for that substance.
Page 246 and 247: predict the aquatic toxicity of a s
Page 248 and 249: Calculation Model of Aggravating Fa
Page 250 and 251: To estimate the values of Human Hea
Page 252 and 253: water in comparison with the durati
Page 254 and 255: Cypermethrin (95 th percentile (P 9
Page 256 and 257: Table 8 shows the results of the De
Page 258 and 259: are many ranking systems of dangero
Page 260 and 261: REFERENCESAres J. (2004). “Estima
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Mackay D. and Paterson S. (1991).
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Long-term Monitoring of Pesticides
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Sampling sites of the survey in 200
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than those in Lake Biwa and Seta Ri
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Fig. 7 Detection of fungicides in R
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Fig. 11 Detection of herbicides in
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Monitoring of pesticides in Yanamun
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A measured volume (1000 mL) of the
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SimetrynePretilachlorConcentration
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Fig. 18 Maximum concentrations of t
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Ecological risk assessmentFig. 20 Y
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REFERENCESAgradi E, Baga R, Cillo F
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Time Trend Variation of Selected Pe
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Table 1. Physical and chemical prop
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marketed under variety of trade nam
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Figure 3. Long-term trends of globa
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laboratory animals fed or injected
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fed for a lifespan at 5-1,600 mg/kg
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Soil samplingSoil sampling was foll
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Figure 5. Map showing sampling area
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concentration (MAC) in surface soil
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Table 7. Concentrations of HCH isom
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Shanghai and Guanting Reservoir (Ch
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Contrary to the results of ΣDDT, t
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DDT metabolites, the ratio of (p,p
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2001). Therefore, the predominance
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Mean concentration (ng g -1 dw)3002
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CONCLUSIONSAn evaluation of selecte
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Hung, D.Q., Thiemann, W., (2002),
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Viet, P.H., Hoai, P.M., Minh, N.H.,
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found in tissues or fluids samples
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Study area and SamplingThis study w
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the liver, mainly to p,p'-DDE and p
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33,370 ha, whilst that of woody cro
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Increase in crops area (x1000)Ha)25
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Table 1. Blood concentrations of or
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Council Directive 90/533/EEC of 15
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Konstantinou, IK, Goutner, V, Alban
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Smith, AG (2004). “Toxicology of
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Pesticides are used in order to pro
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EXPERIMENTALMaterialsIsoproturon wa
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RESULTS AND DISCUSIONEquilibrium is
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As seen in Table 4, as the concentr
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Fig.4. Breakthrough curves of isopr
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Fig.6. Breakthrough curves of isopr
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Fig.8. Experimental and theoretical
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Section 3PESTICIDE ANALYSISAcademyP
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scandal’ are familiar to the gene
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ecoveries (>70%) for certain pH-dep
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Due the versatility of the QuEChERS
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of application, with some still sca
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The main supercritical solvent used
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extracting the pesticides from the
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would be appropriate for the routin
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chromatography with negative-ion el
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GPC was applied as a nondestructive
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Charlton A.J.A., Stuckey, V. (2009)
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Lehotay, S.J., Mastvoska, K. & Yun,
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Rodrigues, F. M., Mesquita, P. R. R
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Analytical methods to assess the im
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acetylcholine, a neurotransmitter t
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1.3 to 22.3% for all pesticides. Li
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Malathion, parathion, fenitrothion,
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Fuller, BH and Berger, GMB (1990).
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Table 1. Largest exporters of coffe
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Fig. 1: Structures of (a) Phosphate
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ELECTROCHEMICAL BIOSENSORBiosensors
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inorganic and organic species a lar
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surface area and be easily modified
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Acetylcholine + H 2 O AChE Choline
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Wang, 2010) and tetracyanoquinodime
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PDDA/AChE/PDDA/CNT/GCAChE-Au-PPy/GC
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ng/mL and good precision (RSD ) 5.3
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FUTURE PERSPECTIVESThe detection of
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Du, D; Wang, M; Cai, J; Qin, Y; Zha
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Martorell, D; Cespedes, F; Fabreaga
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The Pesticide Action Network (PAN).
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About EditorMilan JokanovićProfess
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THE IMPACT OF PESTICIDESPesticides
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