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Monitoring of pesticides in Yanamune River water from 1988 to 2009Materials and MethodsWater samples were collected from Yanamune River flowing into Lake Biwa (Fig.1) once or twice every month in 1988-1997 (Tsuda et al. 1991; 1992; 1994; 1996;1997; 1998; Takino et al. 1998), once or twice from April to August in 2007 (Tsudaet al. 2009) and on May 29 in 2009. Water samples were analyzed immediately aftersample collection.Table 3 Environmental water quality standard and guideline values by Ministry ofthe Environment, Japan________________________________________________________________________PesticideUseStandard value Guideline value 1 Guideline value 2(μg/L) (μg/L) (μg/L)Dichlorvos 8Fenobucarb 30Diazinon 5InsecticideFenitrothion 3Isoxathione 8EPN 6Iprobenfos 8Fthalide 100Flutolanil Fungicide200Isoprothiolane 40Chlorothalonil 50Molinate 5Simazine 3Propyzamide 8Bromobutide 40Simetryne Herbicide60Esprocarb 10Thiobencarb 20Thenylchlor 40Mefenacet 9AcademyPublish.org - The Impact of Pesticides274
Fig. 12 Variations in shipment amount of iprobenfos in Shiga Prefecture and itsconcentration in Lake Biwa waterConcentration (μg/L)0.500.400.300.200.100.00Site:4A200020012002Shipment amounts (t)Concentration (μg/L)20032004200520062007200820092.502.001.501.000.500.00Shipment amount (t)Concentration (μg/L)0.500.400.300.200.100.00Site:13C2000200120022003Shipment amounts (t)Concentration (μg/L)2004200520062007200820092.502.001.501.000.500.00Shipment amount (t)YearYearConcentration (μg/L)0.500.400.300.200.100.002000Site:6B200120022003Shipment amounts (t)Concentration (μg/L)2004200520062007200820092.502.001.501.000.500.00Shipment amount (t)Concentration (μg/L)0.500.400.300.200.100.002000Site:17A200120022003Shipment amounts (t)Concentration (μg/L)2004200520062007200820092.502.001.501.000.500.00Shipment amount (t)YearYearFig. 13 Variations in shipment amount of isoprothiolane in Shiga Prefecture and itsconcentration in Lake Biwa waterConcentration (μg/L)0.500.400.300.200.100.002000Site:4A200120022003Shipment amounts (t)Concentration (μg/L)2004200520062007200820098.006.004.002.000.00Shipment amount (t)Concentration (μg/L)0.500.400.300.200.100.00Site:13C2000200120022003Shipment amounts (t)Concentration (μg/L)2004200520062007200820098.006.004.002.000.00Shipment amount (t)YearYearConcentration (μg/L)0.500.400.300.200.100.002000Site:6B200120022003Shipment amounts (t)Concentration (μg/L)2004200520062007200820098.006.004.002.000.00Shipment amount (t)Concentration (μg/L)0.500.400.300.200.100.00Site:17A2000200120022003Shipment amounts (t)Concentration (μg/L)2004200520062007200820098.006.004.002.000.00Shipment amount (t)YearYearIn 1988-1997, analyses of 10 pesticides (diazinon, fenitrothion, iprobenfos,isoprothiolane, chlornitrofen (CNP), thiobencarb, molinate, bromobutide, simetryneand pretilachlor) in the water samples were performed by the following procedure.AcademyPublish.org - The Impact of Pesticides275
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The Impactof PesticidesEdited by:Pr
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Other access free resources from Ac
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The Impact of PesticidesPrepared an
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Table of Contentsp.203-p.224 Behavi
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About authorspublished by Elsevier.
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About authorsof medical researchers
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About authorsdifferent spatial scal
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About authorsEducation:Bachelor’s
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About authorsSensors - A Nanotechno
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Section 1HUMAN EXPOSURE TO PESTICID
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ecently explored on preliminary stu
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individuals within 1 day (Jokanovic
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occupational environmental health r
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must be considered, since effective
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Jensen BH, Petersen A, and Christen
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Ragas AMJ, and Huijbregts MAJ (1998
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Weichenthal S, Moase C, and Chan P
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human poisoning, general acute symp
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Management of the cholinergic syndr
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1982; Lotti, 1992; Jokanović et al
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exposed populations, revealed high
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DiazepamBenzodiazepines are CNS dep
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Among the many classes of oximes in
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inhibited by dichlorvos (a dimethox
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Dawson, 1995). It appears that the
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Eddleston M, Eyer P, Worek F, Moham
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Jokanović M, Kosanović M (2010b).
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Ray DE (1998). Chronic effects of l
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Worek F, Eyer P, Kiderlen D, Thierm
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developing countries is due to suic
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count and morphology, as well as se
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PON1 modulation of genetic damageFe
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elationship between OP exposure and
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Blatter-Garin MC, James RW, Dussoix
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Hung RJ, Hall J, Brennan P, Boffett
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Rojas-García AE., Solís-Heredia M
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Occupational Exposure to Pesticides
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considered as conditions typical of
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observed adverse health outcome. Su
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within cells can oxidize biomolecul
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of the study. A face-to-face questi
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PesticidesFungicideInsecticide-Nema
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Table 4. Mixtures of pesticides use
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In pesticide applicators, Table 7 s
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DISCUSSIONThe agricultural workers
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changes in the antioxidant enzyme C
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Bajpayee, M.; Pandey, A. K.; Parmar
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Environmental health criteria 155.
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Palus, J.; Rydzynski, K.; Dziubalto
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Singh, N.P.; McCoy, M.T.; Tice, R.R
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INTRODUCTIONPopulations may be occu
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exposure scenarios on the basis of
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not present adverse health effects
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greenhouse workers exposed to malat
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Paraoxon is then either metabolized
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cyclohexene-1,2-dicarboximide, CAS
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metabolite of phthalates, such that
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scenarios were simulated, assuming
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Table 2. Biological reference value
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References N a urinarybiomarkeStudi
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Figure 2. Representation of a BRV d
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Figure 4. Conceptual representation
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Figure 6 Conceptual representation
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REFERENCESACGIH, 2011. Documentatio
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Bradway, D.E., Shafik, T.M., 1977.
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EPA, 1999b. Registration Eligibilit
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Hines, C.J., Deddens, J.A., Jaycox,
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McCollister, S.B., Kociba, R.J., Hu
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Verberk, M.M., Brouwer, D.H., Brouw
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important IGFBP for binding IGF-1 i
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secretion of IGF-1 (Tannheimer et a
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FIGURESFig. 1. An “hormetic” ef
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Landi F, Capoluongo E, Russo A, Ond
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Smith WJ, Underwood LE, Clemmons DR
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Section 2PESTICIDES IN THEENVIRONME
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vicinity of subsoil waters and ther
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Hieracium pilosella, southernwood -
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formed clusters (Figure 3). Ultrast
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Fig. 5. Fragment of hepatocyte of t
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Szarek, J, Skibniewska, K, Wojtacka
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negative effects (ZALUCKI et al., 2
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Figure 2. Appropriated sampling pro
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Figure 4. Illustration of the conse
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(HAILE et al., 1998). Earlier resul
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Table 1. Distribution of the applic
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Means followed by the same letter i
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(involving pests and natural enemie
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efore the pest emergence and their
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Table 3 (continuation)…AcademyPub
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Table 5. Effect of different fungic
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Table 6. Magament used including do
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adopted by Brazilian soybean grower
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Pickle, C.S.; Caviness, C.E. Yield
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This chapter reports on Dutch surfa
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several different occasions at any
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The greatest number of pesticides a
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Accumulated ExceedanceIt is useful
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For the years 2003-2009 the calcula
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Bonzini S, Verro R, Otto S, Lazzaro
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atios of the pesticide amounts in t
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Table 1. (Cont.) Runoff ratios of p
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mefenacet and simetrin were observe
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Table 2. (Cont.)Pesticide concentra
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Table 2. (Cont.)Pesticide concentra
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Fig. 3. Typical weekly variation of
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(BAM) in water (Pukkila et al. 2009
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Table 5. Concentrations of pesticid
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Table 6. Maximum concentrations of
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Iwafune, T, Inao, K, Horio, T, Iwas
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Page 226 and 227: factor, etc. Levels of pesticides i
Page 228 and 229: factor of 10 above ambient sea wate
Page 230 and 231: weight sample. Minimum were shown f
Page 232 and 233: Figure 3. DDTs in mussel samples fo
Page 234 and 235: Figure 5. HCB in mussel samples for
Page 236 and 237: Figure 8. Methoxychlor in mussel sa
Page 238 and 239: ACKNOWLEDGEMENTAuthors thank UNEP/M
Page 240 and 241: Pesticide Risk Index of Del Azul Wa
Page 242 and 243: on that presented in Swanson et al.
Page 244 and 245: eference value for that substance.
Page 246 and 247: predict the aquatic toxicity of a s
Page 248 and 249: Calculation Model of Aggravating Fa
Page 250 and 251: To estimate the values of Human Hea
Page 252 and 253: water in comparison with the durati
Page 254 and 255: Cypermethrin (95 th percentile (P 9
Page 256 and 257: Table 8 shows the results of the De
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Page 260 and 261: REFERENCESAres J. (2004). “Estima
Page 262 and 263: Mackay D. and Paterson S. (1991).
Page 264 and 265: Long-term Monitoring of Pesticides
Page 266 and 267: Sampling sites of the survey in 200
Page 268 and 269: than those in Lake Biwa and Seta Ri
Page 270 and 271: Fig. 7 Detection of fungicides in R
Page 272 and 273: Fig. 11 Detection of herbicides in
Page 276 and 277: A measured volume (1000 mL) of the
Page 278 and 279: SimetrynePretilachlorConcentration
Page 280 and 281: Fig. 18 Maximum concentrations of t
Page 282 and 283: Ecological risk assessmentFig. 20 Y
Page 284 and 285: REFERENCESAgradi E, Baga R, Cillo F
Page 286 and 287: Time Trend Variation of Selected Pe
Page 288 and 289: Table 1. Physical and chemical prop
Page 290 and 291: marketed under variety of trade nam
Page 292 and 293: Figure 3. Long-term trends of globa
Page 294 and 295: laboratory animals fed or injected
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Page 298 and 299: Soil samplingSoil sampling was foll
Page 300 and 301: Figure 5. Map showing sampling area
Page 302 and 303: concentration (MAC) in surface soil
Page 304 and 305: Table 7. Concentrations of HCH isom
Page 306 and 307: Shanghai and Guanting Reservoir (Ch
Page 308 and 309: Contrary to the results of ΣDDT, t
Page 310 and 311: DDT metabolites, the ratio of (p,p
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Page 314 and 315: Mean concentration (ng g -1 dw)3002
Page 316 and 317: CONCLUSIONSAn evaluation of selecte
Page 318 and 319: Hung, D.Q., Thiemann, W., (2002),
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Page 322 and 323: found in tissues or fluids samples
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Study area and SamplingThis study w
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the liver, mainly to p,p'-DDE and p
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33,370 ha, whilst that of woody cro
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Increase in crops area (x1000)Ha)25
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Table 1. Blood concentrations of or
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Council Directive 90/533/EEC of 15
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Konstantinou, IK, Goutner, V, Alban
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Smith, AG (2004). “Toxicology of
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Pesticides are used in order to pro
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EXPERIMENTALMaterialsIsoproturon wa
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RESULTS AND DISCUSIONEquilibrium is
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As seen in Table 4, as the concentr
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Fig.4. Breakthrough curves of isopr
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Fig.6. Breakthrough curves of isopr
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Fig.8. Experimental and theoretical
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Section 3PESTICIDE ANALYSISAcademyP
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scandal’ are familiar to the gene
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ecoveries (>70%) for certain pH-dep
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Due the versatility of the QuEChERS
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of application, with some still sca
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The main supercritical solvent used
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extracting the pesticides from the
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would be appropriate for the routin
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chromatography with negative-ion el
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GPC was applied as a nondestructive
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Charlton A.J.A., Stuckey, V. (2009)
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Lehotay, S.J., Mastvoska, K. & Yun,
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Rodrigues, F. M., Mesquita, P. R. R
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Analytical methods to assess the im
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acetylcholine, a neurotransmitter t
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1.3 to 22.3% for all pesticides. Li
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Malathion, parathion, fenitrothion,
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Fuller, BH and Berger, GMB (1990).
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Table 1. Largest exporters of coffe
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Fig. 1: Structures of (a) Phosphate
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ELECTROCHEMICAL BIOSENSORBiosensors
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inorganic and organic species a lar
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surface area and be easily modified
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Acetylcholine + H 2 O AChE Choline
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Wang, 2010) and tetracyanoquinodime
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PDDA/AChE/PDDA/CNT/GCAChE-Au-PPy/GC
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ng/mL and good precision (RSD ) 5.3
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FUTURE PERSPECTIVESThe detection of
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Du, D; Wang, M; Cai, J; Qin, Y; Zha
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Martorell, D; Cespedes, F; Fabreaga
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The Pesticide Action Network (PAN).
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About EditorMilan JokanovićProfess
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THE IMPACT OF PESTICIDESPesticides
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