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Industrial Biotransformations

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EC 1.17 Acting on CH 2 groups<br />

H<br />

R 1<br />

H<br />

R 2<br />

cofactor<br />

+ [O]<br />

H<br />

R 1<br />

OH<br />

R 2<br />

The origin of the oxidizing oxygen is either molecular oxygen or water.<br />

EC 1.18 Acting on reduced ferredoxin as donor<br />

ferredoxin red<br />

cofactor<br />

ferredoxin ox<br />

EC 1.19 With dinitrogen as acceptor<br />

N 2<br />

cofactor<br />

NH 3<br />

The only enzyme classified in this subclass is nitrogenase.<br />

2.2 Enzyme Classes<br />

EC 1.20 Acting on phosphorus or arsenic in donors<br />

The nature of the substrate may differ greatly within the sub-subclasses EC 1.20.1 and<br />

1.20.4. The sub-subclasses EC 1.20.2 and EC 1.20.3 do not have any entries as yet.<br />

EC 1.20.1 Acting on phosphorus or arsenic in donors, with NAD(P) + as acceptor<br />

O<br />

O<br />

HO P OH + NAD(P) HO P OH + NAD(P)H<br />

H<br />

OH<br />

+<br />

+ H2O<br />

At present no entries for reactions including arsenic in donors are listed.<br />

EC 1.20.4 Acting on phosphorus or arsenic in donors, with disulfide as acceptor<br />

OH<br />

As<br />

HO X<br />

+<br />

X = OH or methyl group<br />

S S + H 2O<br />

O<br />

HO As OH<br />

At present no entries for reactions including phosphorus in donors are listed.<br />

X<br />

+<br />

SH HS<br />

45

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