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Carbaryl, Carbofuran, and Methomyl - National Marine Fisheries ...

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maximum concentrations. Maximum concentrations reported for the various l<strong>and</strong> categories<br />

were: agricultural l<strong>and</strong> (7 μg/L), mixed l<strong>and</strong> use (0.678 μg/L), urban l<strong>and</strong> use (0.034 μg/L), <strong>and</strong><br />

undeveloped l<strong>and</strong> use (0.034 μg/L). An additional table summarizing NAWQA data (1984-<br />

2004) by state (California, Idaho, Oregon, <strong>and</strong> Washington) reported a maximum concentration<br />

of 32.2 μg/L. This concentration occurred in surface water sampled from Zollner Creek, near<br />

Mt. Angel, Oregon on April 17, 2002, <strong>and</strong> was also the maximum residue found in the database<br />

on a national scale. CDPR data (1990-2003) were presented by county. Zollner Creek is a<br />

tributary to the Willamette River <strong>and</strong> within the distribution of threatened Upper Willamette<br />

River Chinook salmon <strong>and</strong> Upper Willamette River steelhead. The maximum concentration<br />

measured in California was 5.5 μg/L, in Imperial County. Date <strong>and</strong> specific location were not<br />

provided.<br />

The BEs for carbaryl (EPA 2003) <strong>and</strong> methomyl (EPA 2003) provided less detailed information<br />

about monitoring data on a national basis. The BE for carbaryl provided a national maximum<br />

reported concentration of 5.5 μg/L, <strong>and</strong> noted that carbaryl was the second most commonly<br />

detected insecticide in the NAWQA database. It also noted there were more frequent detections<br />

<strong>and</strong> higher concentrations in urban streams than in streams draining agricultural or mixed l<strong>and</strong><br />

use areas. The BE for methomyl reported that few national level monitoring data were available,<br />

<strong>and</strong> reported data located in EPA’s STORET database. The highest reported concentration<br />

nationally was 1 μg/L (in Texas).<br />

Table 53. <strong>National</strong> Maximum Concentrations of <strong>Carbaryl</strong>, <strong>Carbofuran</strong>, <strong>and</strong> <strong>Methomyl</strong> as Reported<br />

in EPA BEs (EPA 2003a, EPA 2003b, <strong>and</strong> EPA 2004)<br />

Pesticide<br />

Maximum<br />

Concentration (μg/L)<br />

Data Source Years Reported<br />

<strong>Carbaryl</strong> 5.5 USGS NAWQA 1991-1998<br />

<strong>Carbofuran</strong> 32.2 USGS NAWQA 1984-2004<br />

<strong>Methomyl</strong> 1.0 EPA STORET Not Reported<br />

1-Napthol Not Reported<br />

USGS NAWQA Data for California, Idaho, Oregon, <strong>and</strong> Washington<br />

We obtained updated data from the USGS NAWQA database to evaluate the occurrence of<br />

carbofuran, carbaryl, methomyl, <strong>and</strong> 1-napthol (a degradate of carbaryl) in surface waters<br />

292

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