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Carbaryl, Carbofuran, and Methomyl - National Marine Fisheries ...

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Use Site<br />

Maximum Single<br />

Application Rate<br />

(lb a.i./acre)<br />

36<br />

Application<br />

Maximum<br />

Number of<br />

Applications<br />

Minimum<br />

Application<br />

Interval<br />

(days)<br />

Maximum per<br />

year<br />

(lb a.i./acre)<br />

Onions 0.9 8 x 3 crops 5 16.2<br />

Spinach 0.9 8 x 3 crops 5 10.8<br />

Turf 0.9 4 x 2 crops 5 7.2<br />

Timing. The timing of application is dependent on use, but may occur throughout the<br />

year. In most cases multiple applications are allowed to maintain pest control.<br />

Applications occur on fruit crops during the bloom, petal fall, pre-bloom, <strong>and</strong> leaf stages<br />

<strong>and</strong> when pest pressure is highest on a “When Needed” basis. On corn, application may<br />

occur during the whorl/foliar stages. With other crops, application is during the foliar or<br />

leaf stages of the crop (EPA 1998).<br />

Metabolites <strong>and</strong> Degradates<br />

Several degradates <strong>and</strong> metabolites have been identified for methomyl. The major<br />

degradate in most metabolism studies was CO 2 . Another degradate, S-methyl-Nhydroxythioacetamidate,<br />

which is highly mobile, appears primarily as a product of<br />

alkaline hydrolysis. In an aquatic metabolism study, methomyl degraded with estimated<br />

half-lives of four to five days. After seven days, acetonitrile comprised a maximum of<br />

17% <strong>and</strong> acetamide up to 14% of the amount of methomyl applied. After 102 days,<br />

volatilized acetonitrile totaled up to 27% of the applied <strong>and</strong> CO2 up to 46% of the applied<br />

material (EPA 2003).<br />

Species Addressed in the BEs<br />

EPA’s BEs considered the effects of carbaryl, carbofuran, <strong>and</strong> methomyl to 26 species of<br />

listed Pacific salmonids <strong>and</strong> their designated critical habitat. EPA determined that<br />

carbaryl, carbofuran, <strong>and</strong> methomyl may affect most of these species. Exceptions follow:<br />

EPA concluded that the registration of carbaryl products would have no effect on<br />

Northern California steelhead, SONCCal coho, Hood Canal summer-run chum, <strong>and</strong><br />

Ozette Lake sockeye. EPA also concluded that the registration of carbaryl products

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