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Thermo Scientific TVA-1000B Instruction Manual - Geotech ...

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Display Menus MI 611-185 – June 1996<br />

The <strong>TVA</strong>-<strong>1000B</strong> uses one of two different response factor formats: a Multiplier or a Curve.<br />

Response Factor Multiplier<br />

A response factor multiplier is defined as follows:<br />

Example: If 100 ppm of a compound produces an FID response of 50 ppm on an analyzer calibrated<br />

with Methane, then the FID response factor would be 2.00 (100/50).<br />

When using a response factor multiplier to correct a <strong>TVA</strong>-<strong>1000B</strong> reading, the analyzer multiplies<br />

the reading by the response factor and displays the corrected reading. As in the example<br />

give above, if a 50 ppm reading is obtained by the <strong>TVA</strong>-<strong>1000B</strong>, the analyzer would automatically<br />

multiply 50 times 2.00 to get the actual concentration of 100 ppm.<br />

Response Curve<br />

Response Factor<br />

=<br />

----------------------------------------------------------<br />

Actual Concentration<br />

Measured Concentration<br />

Response factors can change as concentration changes. The response factor for a compound<br />

determined at 500 ppm may not be the same as the response factor determined at<br />

10,000 ppm. By using a response curve, you can characterize a compounds response over a<br />

broader range of concentrations. If the actual concentration is plotted as Y vs. X (measured<br />

concentration), the resulting curve can be represented by the rational equation<br />

Y = ----------------------------------------<br />

AX<br />

⎛1<br />

+ -------------------------<br />

BX ⎞<br />

⎝ 10000ppm⎠<br />

When using the RF Calc Mode “curve”, the terms A and B are entered into the <strong>TVA</strong>-<strong>1000B</strong>.<br />

A represents the response factor multiplier at very low concentrations and B represents a<br />

change to the response for every percent concentration increase.<br />

The curve can only be defined by collecting response data at several different concentrations<br />

and using a xy math spreadsheet to calculate the “best-fit” polynomial expression.<br />

NOTE: Once the response curve has been fit, the calibration gas concentrations and<br />

number of span points should not be changed without readjusting the curve fit.<br />

To define and/or choose a response factor, choose 5=RF from the CALIBRATION menu.<br />

The following display will appear:<br />

RF0: Default<br />

Up/Dn=Next RF<br />

Enter=Accept<br />

The top line shows the currently active response factor. If no response factor is applied, the<br />

currently active response factor will be the factory DEFAULT (1.00 for FID methane and<br />

1.00 for PID isobutylene). The name and value of the default response factor cannot be<br />

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