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Biofuel co-products as livestock feed - Opportunities and challenges

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Feeding biofuel <strong>co</strong>-<strong>products</strong> to dairy cattle 117TABLE 2Composition of different cereal grainsMaize Sorghum Wheat Barley Triticale RyeNutrients (% of DM)NDF 9.9 ± 1.3 13.8 ± 6.2 12.9 ± 1.1 19.8 ± 1.6 14.3 ± 0.2 16.5 ± 2.3ADF 3.5 ± 0.4 5.2 ± 0.9 4.0 ± 0.4 6.9 ± 0.4 3.9 ± 0.2 5.2 ± 2.4Lignin 0.7 ± 0.4 1.1 ± 0.3 1.2 ± 0.4 1.8 ± 0.4 1.1 ± 0.2 1.1 ± 0.1Starch 73.8 ± 1.0 67.7 ± 9.9 66.9 ± 2.3 57.0 ± 2.8 64.9 ± 3.4 59.8 ± 1.9CP 9.1 ± 0.3 10.9 ± 0.7 13.2 ± 1.1 12.3 ± 0.5 12.4 ± 1.2 11.1 ± 1.8Crude fat 4.5 ± 0.6 3.3 ± 0.3 2.0 ± 0.2 2.1 ± 0.1 1.7 ± 0.1 1.6 ± 0.2Ash 1.50 ± 0.08 1.8 ± 0.26 1.9 ± 0.1 2.9 ± 0.3 2.0 ± 0.1 1.9 ± 0.2Ca 0.04 ± 0.01 0.04 ± 0.02 0.06 ± 0.02 0.07 ± 0.01 0.07 ± 0.01 0.07 ± 0.03P 0.24 ± 0.13 0.34 ± 0.01 0.40 ± 0.03 0.41 ± 0.03 0.37 ± 0.03 0.36 ± 0.02S 0.13 ± 0.02 0.11 ± 0.01 0.26 ± 0.19 0.14 ± 0.02 0.16 ± 0.01 0.14 ± 0.04Energy parameters (Mcal/kg)NEM 2.13 ± 0.05 1.98 ± 0.04 2.11 ± 0.06 2.15 ± 0.18 2.01 2.02NEG 1.45 ± 0.04 1.31 ± 0.01 1.45 ± 0.03 1.35 ± 0.01 1.37 1.34NEL 1.97 ± 0.15 1.85 ± 0.09 1.91 ± 0.16 1.80 ± 0.17 1.85 ± 0.20 1.89 ± 0.12Notes: Nutrients: NDF = neutral-detergent fibre; ADF = acid-detergent fibre; CP = crude protein. Energy parameters: NEM = net energy formaintenance; NEG = net energy for gain; <strong>and</strong> NEL = net energy for lactation. Data are reported <strong>as</strong> means ± the st<strong>and</strong>ard deviation.Sources: Adapted from NRC, 2001; FEDNA, 2003; INRA, 2004; CNCPS, 2009.most resistant to microbial fermentation (FEDNA, 2003).Consequently, this results in the lowest effective proteindegradability of all cereal grains (INRA, 2004). Its <strong>co</strong>ncentrationof starch <strong>and</strong> fat (67.7 <strong>and</strong> 3.3 percent, respectively)are slightly less than that of maize, which, together withgreater fibre <strong>co</strong>ncentration, results in a lower net energy forlactation (NEL) <strong>co</strong>ntent (1.85 Mcal/kg NEL) <strong>co</strong>mpared withmaize DGS (1.97 Mcal/kg NEL).Although with great variability between experiments,there h<strong>as</strong> been more CP reported in sorghum DGS <strong>co</strong>mparedwith maize DGS (34.1 vs 31.2 percent; Table 3), witha range between 24.4 <strong>and</strong> 45 percent. These variationswere also observed among DGS produced in the sameplant, albeit with different moisture <strong>co</strong>ntents. Depenbuschet al. (2009) reported CP <strong>co</strong>ntents of 45 percent for dried(92 percent DM) <strong>and</strong> 34 percent wet (36 percent DM)sorghum DGS. In the same experiment, however, the CP<strong>co</strong>ncentration between wet <strong>and</strong> dried maize DGS varied byonly 3 percent.The average fat values in sorghum DGS studied weresimilar to that of maize (11.3 vs 11.9 percent) in spite ofa 26 percent lower fat <strong>co</strong>ntent in sorghum than maize,which resulted in similar NEL values between both typesof DGS (2.24 Mcal/kg). The percentage of starch <strong>and</strong> aciddetergentfibre (ADF) of sorghum DGS were greater thanin maize DGS <strong>as</strong> a result of the greater resistance to degradationof the protein matrix that encapsulates the starchgranules of the sorghum endosperm.Wang et al. (2008) <strong>co</strong>mpared ethanol production characteristicsof 70 sorghum varieties with different nutrient<strong>co</strong>mposition <strong>and</strong> physical properties. The average starch<strong>co</strong>ntent varied between 64 <strong>and</strong> 74 percent, <strong>and</strong> had anefficiency of <strong>co</strong>nversion to ethanol of 86 to 93.8 percent.The authors also determined that variations in ethanolyields <strong>co</strong>uld be <strong>as</strong> high <strong>as</strong> 7.4 percent, particularly due tonegative effects on fermentation efficiency caused by highamylose <strong>co</strong>ncentration in some varieties. There were nosignificant differences due to grain <strong>co</strong>lour, except for browntannin-<strong>co</strong>ntaining varieties. Results with those varieties<strong>co</strong>nfirmed that high-tannin genetic lines are not suitablefor ethanol production. These experiments demonstrate theimportance for ethanol plants of adequate selection of thesubstrate to be used for fermentation. The darker <strong>co</strong>lour ofsorghum DGS, often mistakenly identified with excessiveheating during drying (Maillard reaction), is frequently dueto the darker <strong>co</strong>lour of the variety of sorghum, which canreduce their acceptability in the market.Wheat distillers grainWheat is <strong>co</strong>nsidered <strong>as</strong> one of the main ethanol-producingcrops in the EU (FAOSTAT data) with almost one-third ofthe bio-refineries using it <strong>as</strong> the sole substrate (Table 1). InNorth America, western Canada produces over 500 millionlitres of ethanol each year from over 1.3 million tonnes ofwheat or wheat-maize blends (University of S<strong>as</strong>katchewan,2009). Half of the bio-refineries located in Canada, usewheat <strong>as</strong> the sole substrate or together with other cerealgrains (Table 1). In <strong>co</strong>ntr<strong>as</strong>t, the United States h<strong>as</strong> only oneethanol plant that uses wheat <strong>as</strong> part of its substrates,located in Tex<strong>as</strong> (RFA, 2011).Wheat is cl<strong>as</strong>sified <strong>as</strong> hard or soft, depending on thephysical hardness of the endosperm <strong>and</strong> its resistanceto grinding (Hruskova <strong>and</strong> Svec, 2009; Saunders, 2009).Grain hardness does not affect ethanol yield (Swanston etal., 2007), but wheat varieties with harder endosperm are<strong>as</strong>sociated with processing problems (Dexter <strong>and</strong> Edwards,

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