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Biofuel co-products as livestock feed - Opportunities and challenges

Biofuel co-products as livestock feed - Opportunities and challenges

Biofuel co-products as livestock feed - Opportunities and challenges

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Utilization of lipid <strong>co</strong>-<strong>products</strong> of the biofuel industry in <strong>livestock</strong> <strong>feed</strong> 317FIGURE 4Chemical structure of polyphenolsHYDROXYBENSOIC ACIDHYDROXYCINNAMIC ACIDR 1OHR 1R 2R 3OHOOR 2Protocatechuic acid R 1=R 2=(-OH); R 3= (-H)Gallic acid R 1=R 2=R 3=(-OH)Coumaric acidR 1=(-OH);R 2=(-H)Ferulic acid R 1=(-O-CH 3);R 2=(-OH)R 1R 2R'FLAVONOIDSOR 3HOOOHOOHR''R 5R 4HOOHOOHIf R'=(=O);R''=(-H)If R'=(-H); R''=(-OH)Chlorogenic acidSTILBENESLIGNANSHOH 3COOHHOOCH 3HOOCH 3ResveratrolOHOCH 3Se<strong>co</strong>isolariciresinoltional characteristics, mainly <strong>as</strong> a surfactant <strong>and</strong> emulsifier(Wilson, 2003). However, lecithin <strong>products</strong> from seeds ofrape, sunflower, gl<strong>and</strong>less <strong>co</strong>tton <strong>and</strong> maize are also potential<strong>co</strong>mmercial sources. Seed of gl<strong>and</strong>ed <strong>co</strong>tton <strong>co</strong>ntainsmore phospholipids than any other oilseed (with the exceptionof soybean), but h<strong>as</strong> the disadvantage that gossypol (atoxic <strong>co</strong>mpound normally present in the <strong>co</strong>tton seed) tendsto bind to the phospholipids during the solvent extractionprocess (Pickard, 2005).Information about the chemical structure of lecithinsfrom different oils are presented in Tables 10 <strong>and</strong> 11.Lecithins are used in animal <strong>feed</strong> recipes <strong>as</strong> dustsuppressors, e<strong>co</strong>nomic emulsifiers (e.g. stabilization of milkreplacers for <strong>feed</strong>ing calves) <strong>and</strong> essential FA sources (VanTABLE 10Fatty acid <strong>co</strong>mposition of vegetable lecithins (g/100 g)Fatty acid Soybean Sunflower seed Rapeseed16:0 16 11 718:0 4 4 118:1 17 18 5618:2 55 63 2518:3 7 0 6Others fatty acids 1 4 5Source: Van Nieuwenhuyzen <strong>and</strong> Tom<strong>as</strong>, 2008.Nieuwenhuyzen <strong>and</strong> Tom<strong>as</strong>, 2008). Feeding soy lecithin toruminants w<strong>as</strong> found to favourably change the FA profilein longissimus muscle <strong>and</strong> subcutaneous adipose tissuein lambs (Lough et al., 1992). It also incre<strong>as</strong>ed FAs <strong>and</strong>

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