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Processing and Bioavailability (WG2) page 10<br />

__________________________________________________________________________________________<br />

2. Hazard Analysis<br />

2.1 - Prepare a list of steps where significant hazards occur and describe the preventive<br />

measures<br />

The Hazards for Lycopene are identified as L, D, O, I<br />

L means Quantitative Loss<br />

D means Thermal Degradation<br />

O means Chemical Oxidation<br />

I means Isomerisation<br />

L occurs when a considerable quantity of tomatoes or portion of fruit rich in lycopene is lost.<br />

D occurs when the thermal treatment causes a lycopene degradation<br />

O occurs when lycopene reacts with oxygen. Oxidation is an irreversible step, since volatile<br />

hydroxylic and ketonic groups are formed.<br />

I occurs when all-trans-lycopene isomerises to cis-lycopene. Lycopene may alter in one of<br />

two ways: the first involves the transformation (reversible) from the all-trans to the cis form,<br />

which is less coloured and more readily oxidisable; whereas the second is practically the<br />

oxidation (irreversible) of both all-trans and cis-lycopene to a series of volatile compounds<br />

with a consequent discolouring of the product. Both mechanisms are described in the section<br />

relating to the activity of WG1.<br />

Referring to Section WG1 for the analysis of the themes sub A, for the Technological<br />

aspects (Themes B and C), we have identified the hazards for lycopene maintenance in<br />

processed tomatoes; these are reported in Table 2 below.<br />

In the same Table 2 we have also identified the preventive measures normally used to<br />

reduce damage of quality characteristics. Generally, the same preventive measures allow for a<br />

reduction in lycopene content degradation.

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