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Given that the rele<strong>as</strong>e of P from the WWTP and septic tanks would have been<br />

relatively consistent during the period of monitoring, we concluded that loadings<br />

from diffuse sources were probably responsible for the majority of violations of the<br />

target concentration value for TP. We therefore set w<strong>as</strong>teload allocations for the<br />

WWTP and septic tanks at the estimated values for the period of monitoring, and<br />

set the load allocation for diffuse sources <strong>as</strong> the estimated value for the period of<br />

monitoring minus the amount by which the actual flux of TP must be reduced in<br />

order to meet the target concentration value for TP. In order to allow for a margin<br />

of safety in our load allocation budget, we derived mean probable errors for best<br />

and worse c<strong>as</strong>e data acquisition scenarios using results published in the literature<br />

(Figures 4 and 5). Sources of error in load calculations may be grouped into four<br />

main categories, namely errors <strong>as</strong>sociated with the me<strong>as</strong>urement of flow, errors<br />

<strong>as</strong>sociated with sample collection, errors <strong>as</strong>sociated with sample storage and errors<br />

<strong>as</strong>sociated with laboratory analysis. Further sources of error also arise when using<br />

process-b<strong>as</strong>ed models and GIS tools to estimate source loadings, but these have<br />

yet to be satisfactorily quantified. Therefore, the error ranges presented should be<br />

viewed <strong>as</strong> minimum estimates.<br />

Figure 4: Time series of best c<strong>as</strong>e uncertainty (± 17 %) in daily phosphorus<br />

loads at Coull Bridge during the period of monitoring. At this level<br />

of uncertainty, a 49% reduction in diffuse P loading is required to<br />

achieve the target concentration value of 0.05 mg/L for TP<br />

50

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