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Air quality expert group - Fine particulate matter (PM2.5) in ... - Defra

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3.7.3 Bonfires and fireworks<br />

Concentrations and composition of <strong>PM2.5</strong><br />

30 Episodes of elevated <strong>PM2.5</strong> concentrations are clearly associated with emissions<br />

from bonfires and/or fireworks, as is evident <strong>in</strong> the peaks last<strong>in</strong>g for several<br />

hours that frequently occur around Bonfire night (see the example shown <strong>in</strong><br />

Figure 3.16). The concentrations at these four London sites rose sharply on the<br />

Saturday even<strong>in</strong>g, 7 November 2010, before decl<strong>in</strong><strong>in</strong>g more slowly. Although<br />

Bonfire night was the day before, there was only a small peak on the Friday<br />

even<strong>in</strong>g. The w<strong>in</strong>d speed was very low on the Saturday night but stronger<br />

on the Friday, show<strong>in</strong>g the importance of local meteorological conditions <strong>in</strong><br />

determ<strong>in</strong><strong>in</strong>g whether an episode will occur. Separate analysis (not shown)<br />

revealed that the peaks were almost entirely <strong>PM2.5</strong>, with very little <strong>PM2.5</strong>-10.<br />

Also, concentrations of NOx rose at the same time as the <strong>PM2.5</strong>, but there<br />

was no impact on NO2 concentrations, which is evidence of fresh NOx<br />

emissions. Such episodes can contribute around 0.1 µg m -3 to the annual<br />

mean concentration. <strong>PM2.5</strong> episodes due to bonfires and fireworks are<br />

of short duration and will only have a small effect on annual mean<br />

concentrations.<br />

<strong>PM2.5</strong><br />

300<br />

200<br />

100<br />

Nov 04<br />

Nov 05 Nov 06 Nov 07<br />

London N. Kens<strong>in</strong>gton London Bloomsbury<br />

London N. Kens<strong>in</strong>gton London Bloomsbury<br />

Nov 04 Nov 05 Nov 06 Nov 07<br />

Figure 3.16: <strong>PM2.5</strong> concentrations (µg m -3 ) over four days <strong>in</strong> November 2010 at<br />

four London sites. The date markers are for midnight.<br />

300<br />

200<br />

100<br />

65

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