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Air quality expert group - Fine particulate matter (PM2.5) in ... - Defra

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VI<br />

2.5 Summary 39<br />

2.5.1 What does the <strong>PM2.5</strong> metric measure? 39<br />

2.5.2 How do PM10 and <strong>PM2.5</strong> measurement issues compare? 39<br />

2.5.3 Do we have robust measurements of <strong>PM2.5</strong>? 39<br />

2.5.4 What about measurements of chemical components of <strong>PM2.5</strong>? 41<br />

2.6 Recommendations 41<br />

Annex 1 <strong>PM2.5</strong> measurement sites <strong>in</strong> the UK 42<br />

Chapter 3: Concentrations and composition of <strong>PM2.5</strong> 45<br />

3.1 Introduction 45<br />

3.2 <strong>PM2.5</strong> concentrations across the UK: Temporal variations and trends 45<br />

3.2.1 Diurnal variations of <strong>PM2.5</strong> at urban background sites 46<br />

3.2.2 Diurnal variations of <strong>PM2.5</strong> at roadside and <strong>in</strong>dustrial sites 48<br />

3.2.3 Diurnal variations at a site <strong>in</strong> Lisburn, Northern Ireland 49<br />

3.2.4 Seasonal variations <strong>in</strong> <strong>PM2.5</strong> at urban background sites 50<br />

3.3 Trends <strong>in</strong> <strong>PM2.5</strong> concentrations 51<br />

3.4 Relationship of <strong>PM2.5</strong> with other pollutants 52<br />

3.4.1 Relationship of <strong>PM2.5</strong> with PM10 52<br />

3.4.2 Relationship of <strong>PM2.5</strong> with PM10, NOx and NO2 54<br />

3.5 Spatial patterns 55<br />

3.5.1 Spatial homogeneity of <strong>PM2.5</strong> hourly mean concentrations 55<br />

3.5.2 Differences <strong>in</strong> annual mean <strong>PM2.5</strong> concentrations by site type 56<br />

3.6 Relationship with w<strong>in</strong>d direction and air mass trajectory 57<br />

3.6.1 Relationship of hourly mean <strong>PM2.5</strong> concentrations<br />

with w<strong>in</strong>d direction 57<br />

3.6.2 Relationship of hourly mean <strong>PM2.5</strong> concentrations with<br />

air mass trajectory 59<br />

3.7 <strong>PM2.5</strong> episodes 62<br />

3.7.1 W<strong>in</strong>ter episodes 62<br />

3.7.2 Transport from cont<strong>in</strong>ental Europe 63<br />

3.7.3 Bonfires and fireworks 65<br />

3.8 <strong>PM2.5</strong> concentrations <strong>in</strong> relation to standards 66<br />

3.8.1 EU and UK requirements for <strong>PM2.5</strong> 66<br />

3.8.2 Relationship between <strong>PM2.5</strong> and PM10 limit values and<br />

objectives 67

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