Polymerisation von Ethylen und 1-Olefinen in wässrigen Medien mit ...

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Experimenteller Teil
1 H NMR (600 MHz, CD2Cl2) δ/ppm = 8.22 (d, 4 JHH = 2.0 Hz, 2 H, 4-H), 8.18 (2 H, 7-H),
7.73 (d, 4 JHH = 2.0 Hz, 2 H, 6-H), 7.14 (4 H, 10-H), 4.04 (2 H, 14-H), 2.98 (sept,
3 JHH = 6.8 Hz, 4 H, 12-H), 1.21 (d, 3 JHH = 6.8 Hz, 24 H, 13-H).
13 C NMR (151 MHz, CD2Cl2) δ/ppm = 165.09 (C 7 ), 160.59 (C 2 ), 149.31 (C 4 ), 143.01 (C 8 ),
140.80 (C 6 ), 139.10 (C 9 ), 138.99 (C 11 ), 123.82 (C 10 ), 120.31 (C 1 ), 87.05 (C 5 ),
79.64 (C 3 ), 41.75 (C 14 ), 28.26 (C 12 ), 23.44 (C 13 ).
EA für C39H42I4N2O2 (M = 1078.38 g mol -1 ).
berechnet: C 43.44 % H 3.93 % N 2.60 %
gefunden: C 43.47 % H 4.20 % N 2.53 %
ES-MS m/z = 1077.9 (M + ).
[{(2,6-(3,5-(CF3)2C6H3)2-4-yl-C6H2)-N=C(H)-(3,5-I2-2-(OH)-C6H2)}2] CF3Benz/I
Blass-gelber Feststoff; Ausbeute: 79 %
1 H NMR (400 MHz, CD2Cl2) δ/ppm = 12.94 (2 H, OH), 8.14 (d, 4 JHH = 1.5 Hz, 2 H, 4-H),
8.01 (8 H, 13-H), 7.95 (4 H, 15-H), 7.90 (6 H, 7-H, 10-H), 7.29 (d, 4 JHH = 1.5 Hz,
2 H, 6-H).
I
I
F 3C
OH
F 3C
CF 3
13 C NMR (101 MHz, CD2Cl2) δ ppm 168.04 (C 7 ), 159.76 (C 2 ), 150.53 (C 4 ), 144.51 (C 8 ),
140.73 (C 6 ), 140.39 (C 12 ), 138.15 (C 11 ), 133.17 (C 9 ), 131.95 (q, 2 JCF = 33.7 Hz,
C 14 ), 130.16 (C 13 ), 129.94 (C 10 ), 123.24 (q, 1 JCF = 272.5 Hz, C 16 ), 121.78 (C 15 ),
119.33 (C 1 ), 86.55 (C 5 ), 80.15 (C 3 ).
F3C 15
16
CF3 14
13 6
10 9
12
7 1
N
11 8
N 2
HO
CF 3
F 3C
CF 3
5
3
I
I
4