Polymerisation von Ethylen und 1-Olefinen in wässrigen Medien mit ...

tEA für C58H24F24I4N2O2 (M = 1744.4 g mol -1 ).
berechnet: C 39.93 % H 1.39 % N 1.61 %
gefunden: C 41.79 % H 1.92 % N 1.58 %
ES-MS m/z = 1742.8 (M + ).
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Experimenteller Teil
[CH2{(2,6-(3,5-(CF3)2C6H3)2-4-yl-C6H2)-N=C(H)-(3,5-I2-2-(OH)-C6H2)}2] (CF3Met/I)
Blass-gelber Feststoff; Ausbeute: 60 %
1
H NMR (600 MHz, CD2Cl2) δ/ppm = 13.01 (2 H, OH), 8.11 (2 H, 4-H), 7.93 (8 H, 13-H),
7.91 (4 H, 15-H), 7.84 (2 H, 7-H), 7.53 (4 H, 10-H), 7.24 (2 H, 6-H), 4.35 (2 H, 17-
H).
13 C NMR (151 MHz, CD2Cl2) δ/ppm = 168.32 (C 7 ), 160.06 (C 2 ), 150.65 (C 4 ),143.56 (C 8 ),
140.90 (C 6 ), 139.81 (C 11 ), 132.93 (C 9 ), 132.14 (q, 2 JCF = 34.0 Hz, C 14 ), 130.38
(C 13 ), 130.07 (C 12 ), 123.54 (q, 1 JCF = 272.7 Hz, C 16 ), 121.81 (C 15 ), 119.66 (C 1 ),
86.79 (C 5 ) , 80.34 (C 3 ), 40.89 (C 17 ).
EA für C59H26F24I4N2O2 (M = 1758.43 g mol -1 ).
berechnet: C 40.30 % H 1.50 % N 1.59 %
gefunden: C 39.65 % H 1.67 % N 1.55 %
ES-MS m/z = 1756.4 (M + ).
I
F 3C
I
F 3C
16
CF3 17
11
10
9 12 13
N
8
N
7
1
6
2
OH
HO 3
I
F3C F3C CF3 14
15
CF 3
CF 3
5
4
I