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Proceedings of the 12th European Conference on Knowledge ...

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Sim<strong>on</strong>a-Clara Bârsan, Mihaela-Georgia and Dan Săvescu<br />

and <str<strong>on</strong>g>the</str<strong>on</strong>g> soluti<strong>on</strong>s have a complex compositi<strong>on</strong>) (Dubitski, 1992).<br />

The technology is based <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> electrolysis <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> soluti<strong>on</strong>s that are to be dec<strong>on</strong>taminati<strong>on</strong>, collected<br />

from current clients, after a preliminary treatment. The methods used are electrochemical, specific for<br />

accelerating <str<strong>on</strong>g>the</str<strong>on</strong>g> electrolysis process. After an advanced recovery <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> silver i<strong>on</strong>s, <str<strong>on</strong>g>the</str<strong>on</strong>g> i<strong>on</strong>s remained<br />

in <str<strong>on</strong>g>the</str<strong>on</strong>g> soluti<strong>on</strong> precipitate and are removed through filtrati<strong>on</strong>. One works in batches (<str<strong>on</strong>g>the</str<strong>on</strong>g> average time<br />

does not exceed 8 hours and depends <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> c<strong>on</strong>centrati<strong>on</strong> and compositi<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> respective<br />

soluti<strong>on</strong>). The purified soluti<strong>on</strong> is finally discharged into <str<strong>on</strong>g>the</str<strong>on</strong>g> sewage system.<br />

The applicati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> this technology provides a superior management <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> diluted liquid waste,<br />

c<strong>on</strong>taining silver i<strong>on</strong>s, due to <str<strong>on</strong>g>the</str<strong>on</strong>g> original advanced purificati<strong>on</strong> method <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> soluti<strong>on</strong>. The resulted<br />

metallic silver (small amounts) can be sold as such.<br />

3.5 Technology for processing galvanic sludge in hazardous waste (19 03 05<br />

category)<br />

The high toxic potential <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> galvanic sludge makes <str<strong>on</strong>g>the</str<strong>on</strong>g> latter improper for direct discharge or to be<br />

deposited as such in envir<strong>on</strong>ment and <str<strong>on</strong>g>the</str<strong>on</strong>g>ir very complex compositi<strong>on</strong> requires a complicated,<br />

laborious and expensive processing so as to be dec<strong>on</strong>taminati<strong>on</strong>. Thus, <str<strong>on</strong>g>the</str<strong>on</strong>g> galvanic sludge collected<br />

from clients, toge<str<strong>on</strong>g>the</str<strong>on</strong>g>r with <str<strong>on</strong>g>the</str<strong>on</strong>g> 3 previous presented technologies, are neutralized (are brought to a<br />

neutral pH), <str<strong>on</strong>g>the</str<strong>on</strong>g>n are embedded (toge<str<strong>on</strong>g>the</str<strong>on</strong>g>r with o<str<strong>on</strong>g>the</str<strong>on</strong>g>r comp<strong>on</strong>ents) in <str<strong>on</strong>g>the</str<strong>on</strong>g> compositi<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> some special<br />

c<strong>on</strong>crete tiles (Untea, 2002).<br />

The galvanic sludge processing technology in hazardous waste is original, simple and cheap and<br />

involves <str<strong>on</strong>g>the</str<strong>on</strong>g> embedment <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> galvanic sludge in stable structures, namely, special c<strong>on</strong>crete tiles,<br />

which can be used, for example, to stabilize and fix <str<strong>on</strong>g>the</str<strong>on</strong>g> waste or tailing dumps.<br />

3.6 Transfer <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> phot<strong>on</strong>ic field heating / drying technology, with separati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g><br />

mediums<br />

Nowadays, <str<strong>on</strong>g>the</str<strong>on</strong>g> ec<strong>on</strong>omic agents working in <str<strong>on</strong>g>the</str<strong>on</strong>g> shipbuilding (shipyards) or in <str<strong>on</strong>g>the</str<strong>on</strong>g> machinery and<br />

equipments field, as well as those from <str<strong>on</strong>g>the</str<strong>on</strong>g> service stati<strong>on</strong>s, bodywork / paint etc., use hot air for<br />

drying <str<strong>on</strong>g>the</str<strong>on</strong>g> fresh painted surfaces.<br />

The technology <str<strong>on</strong>g>of</str<strong>on</strong>g> heating / drying in phot<strong>on</strong>ic field, with separati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> mediums, is mainly based <strong>on</strong><br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> process <str<strong>on</strong>g>of</str<strong>on</strong>g> focusing <str<strong>on</strong>g>the</str<strong>on</strong>g> radiati<strong>on</strong> with colour temperature <str<strong>on</strong>g>of</str<strong>on</strong>g> a halogen lamp filament (Untea,<br />

2002).<br />

Thus, <strong>on</strong>e can heat / dry at high temperatures materials <str<strong>on</strong>g>of</str<strong>on</strong>g> surfaces with no direct c<strong>on</strong>tact between<br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> heating element and <str<strong>on</strong>g>the</str<strong>on</strong>g> heated object. The heating element can be situated outside <str<strong>on</strong>g>the</str<strong>on</strong>g> working<br />

area, being in this way separated from <str<strong>on</strong>g>the</str<strong>on</strong>g> possible existing reactive / oxidant atmosphere. According<br />

to <str<strong>on</strong>g>the</str<strong>on</strong>g> clients’ necessities, <str<strong>on</strong>g>the</str<strong>on</strong>g> technology can be very easily adapted for o<str<strong>on</strong>g>the</str<strong>on</strong>g>r drying / heating<br />

processes, such as preparing various surfaces for technological processes, drying / heating in food<br />

industry.<br />

Outline:<br />

So as to assess <str<strong>on</strong>g>the</str<strong>on</strong>g> impact that <str<strong>on</strong>g>the</str<strong>on</strong>g> technologies implementati<strong>on</strong> would have <strong>on</strong> envir<strong>on</strong>ment, an<br />

envir<strong>on</strong>mental impact study was made. The c<strong>on</strong>clusi<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> carried-out study was that <str<strong>on</strong>g>the</str<strong>on</strong>g> possibility<br />

<str<strong>on</strong>g>of</str<strong>on</strong>g> affecting <str<strong>on</strong>g>the</str<strong>on</strong>g> envir<strong>on</strong>mental factors and populati<strong>on</strong> health because <str<strong>on</strong>g>of</str<strong>on</strong>g> setting-up <str<strong>on</strong>g>the</str<strong>on</strong>g> phot<strong>on</strong>ic field<br />

generators workshop, as well as <str<strong>on</strong>g>the</str<strong>on</strong>g> applying, at industrial scale, <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> technology for surfaces<br />

heating / drying in phot<strong>on</strong>ic field was reduced, even negligible. So, <str<strong>on</strong>g>the</str<strong>on</strong>g> negative effects up<strong>on</strong><br />

envir<strong>on</strong>ment are minor, while as <str<strong>on</strong>g>the</str<strong>on</strong>g> positive effects, reflected in reduced operati<strong>on</strong>al costs and large<br />

range <str<strong>on</strong>g>of</str<strong>on</strong>g> utilizati<strong>on</strong> possibilities <str<strong>on</strong>g>of</str<strong>on</strong>g> utilizati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> product and transferred technology, are<br />

c<strong>on</strong>siderable.<br />

As a result, it is advisable to accept, even to encourage <str<strong>on</strong>g>the</str<strong>on</strong>g> promoti<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> technology for heating /<br />

drying <str<strong>on</strong>g>of</str<strong>on</strong>g> painted surfaces in phot<strong>on</strong>ic field, as well as <str<strong>on</strong>g>the</str<strong>on</strong>g> producti<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> necessary equipment,<br />

namely, <str<strong>on</strong>g>the</str<strong>on</strong>g> phot<strong>on</strong>ic field generator. Its maintenance and reparati<strong>on</strong>s are simple, with relatively<br />

reduced costs. The main problem that may occur in <str<strong>on</strong>g>the</str<strong>on</strong>g> generator functi<strong>on</strong>ing is represented by <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

mirrors distorti<strong>on</strong> (because <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> high operating temperature, as well as <str<strong>on</strong>g>the</str<strong>on</strong>g> great temperature<br />

variati<strong>on</strong>s) and <str<strong>on</strong>g>the</str<strong>on</strong>g> loss <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g>ir luster, which leads to an imprecise focalisati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> phot<strong>on</strong>ic field<br />

70

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