transport of dangerous goods and risk management - Kirilo Savić

TRANSPORT OF DANGEROUS GOODS AND RISK MANAGEMENT 44• Waste cooking oil belongs to the group of 20 to the catalog of waste (20 01 25) and a harmless waste (unlessprovided for disposal to the environment-deposit, upon the ground, the dump or discharge into waterways).Waste used oils are categorized in the Republic of Serbia under the Regulation on management of waste oils(Official Gazette 60/2008) in the following categories:• 1. category - waste oil mineral halogen content below 0.2% and total polychlorinated bi-and terfenilima below20mg/kg. This oil can be processed and re-used for the production of fresh oil.• 2. categories - waste mineral oils, synthetic and plant origin halogen content above 0.2% and below 0.5% andtotal polihlorovnim bi-and terfenilima above 20 mg/kg and less than 30 mg/kg. This oil can be used as fuel inenergy production facilities and equipment installed power greater than or equal to 3 MW or in furnaces for theproduction of clinker in cement.• 3. categories - waste oil of unknown origin and all other waste oil with a halogen content above 0.5%, totalpolychlorinated bi-and terfenilima above 30 mg/kg and the ignition temperature below 55°C. This oil must beburned in furnaces for burning of dangerous waste a minimum efficiency of 99.99%.• 4. categories - poliglikoli/oligoglikoli, waste oil on the basis of poliglikola/oligoglikola nemešavanja that workswith other oils 1 and 2 categories and special requests in the process of removing the need to collect separately.Regulation has prohibited mixing different categories of waste oil, and allowed the mixing of waste oil only 1 and 2category if they are designed for heat treatment.Characterization of waste oil used is done in the study used waste oil management for further proceedings. Wasteused oils are tested on different physical-chemical parameters such as: net caloric value, the contents of PCB-b, thecontent of toxic heavy metals and arsenic content of fuel viscosity, the content of easily volatile compounds,chlorine content of Cl, with sulfur, fluorine F, bromine, etc. No.Waste oil can be dangerous following characteristics:- H5 harm (R65): total concentration of hydrocarbons (C8-C40) in the trash 25% or more (250000mg/kg(ppm));- H7 canceration - for waste oils which are basically used to fuel canceration category 3 (1%), while for otherwaste oils and lubricants used canceration category 2 (0.1%)a) if the content of hydrocarbons, C6 - C10 (gas fraction), 0.1% (1000 mg/kg) or more or a diesel fraction,C10 - C25, 1% (10000mg/kg) or more;b) If the waste contains hydrocarbons 0.1% (1000mg/kg) or more if the Polycyclic Aromatic Hydrocarbons(PAH) concentrations greater than 1%.- H14 ecotoxicity (R51/53): if the total fuel concentration 2.5% (25000mg/kg) or more, or if the totalconcentration of hydrocarbons 25% (250000mg/kg) or more;- H13 can each way, after the delay, for example squeeze through produce any of the above features (BaselConvention) or H15 Directive 2008/98/EC: the total hydrocarbons 20 000 mg/kg, total hydrocarbons in theliquid waste 100 mg/l, respectively through of liquids 1000mg/kg dry weight.Depending on the characterization and content of dangerous components in waste used oil or solid waste that iscontaminated with oil is determined by the method of transport.