transport of dangerous goods and risk management - Kirilo SaviÄ

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TRANSPORT OF DANGEROUS GOODS AND RISK MANAGEMENT 44• Waste cooking oil belongs to the group of 20 to the catalog of waste (20 01 25) and a harmless waste (unlessprovided for disposal to the environment-deposit, upon the ground, the dump or discharge into waterways).Waste used oils are categorized in the Republic of Serbia under the Regulation on management of waste oils(Official Gazette 60/2008) in the following categories:• 1. category - waste oil mineral halogen content below 0.2% and total polychlorinated bi-and terfenilima below20mg/kg. This oil can be processed and re-used for the production of fresh oil.• 2. categories - waste mineral oils, synthetic and plant origin halogen content above 0.2% and below 0.5% andtotal polihlorovnim bi-and terfenilima above 20 mg/kg and less than 30 mg/kg. This oil can be used as fuel inenergy production facilities and equipment installed power greater than or equal to 3 MW or in furnaces for theproduction of clinker in cement.• 3. categories - waste oil of unknown origin and all other waste oil with a halogen content above 0.5%, totalpolychlorinated bi-and terfenilima above 30 mg/kg and the ignition temperature below 55°C. This oil must beburned in furnaces for burning of dangerous waste a minimum efficiency of 99.99%.• 4. categories - poliglikoli/oligoglikoli, waste oil on the basis of poliglikola/oligoglikola nemešavanja that workswith other oils 1 and 2 categories and special requests in the process of removing the need to collect separately.Regulation has prohibited mixing different categories of waste oil, and allowed the mixing of waste oil only 1 and 2category if they are designed for heat treatment.Characterization of waste oil used is done in the study used waste oil management for further proceedings. Wasteused oils are tested on different physical-chemical parameters such as: net caloric value, the contents of PCB-b, thecontent of toxic heavy metals and arsenic content of fuel viscosity, the content of easily volatile compounds,chlorine content of Cl, with sulfur, fluorine F, bromine, etc. No.Waste oil can be dangerous following characteristics:- H5 harm (R65): total concentration of hydrocarbons (C8-C40) in the trash 25% or more (250000mg/kg(ppm));- H7 canceration - for waste oils which are basically used to fuel canceration category 3 (1%), while for otherwaste oils and lubricants used canceration category 2 (0.1%)a) if the content of hydrocarbons, C6 - C10 (gas fraction), 0.1% (1000 mg/kg) or more or a diesel fraction,C10 - C25, 1% (10000mg/kg) or more;b) If the waste contains hydrocarbons 0.1% (1000mg/kg) or more if the Polycyclic Aromatic Hydrocarbons(PAH) concentrations greater than 1%.- H14 ecotoxicity (R51/53): if the total fuel concentration 2.5% (25000mg/kg) or more, or if the totalconcentration of hydrocarbons 25% (250000mg/kg) or more;- H13 can each way, after the delay, for example squeeze through produce any of the above features (BaselConvention) or H15 Directive 2008/98/EC: the total hydrocarbons 20 000 mg/kg, total hydrocarbons in theliquid waste 100 mg/l, respectively through of liquids 1000mg/kg dry weight.Depending on the characterization and content of dangerous components in waste used oil or solid waste that iscontaminated with oil is determined by the method of transport.
TRANSPORT OF DANGEROUS GOODS AND RISK MANAGEMENT 45In Table 2 there is an example of the classification of certain wastes which comprise or contain or are contaminatedwith oil. Classification is made according to international regulations for road transport - ADR (EuropeanAgreement Concerning the International Carriage of Dangerous Goods by Road - European agreement oninternational road transport of dangerous goods) 3 .THE TYPE OF WASTEUSED OILOther motor oils, gearoils and lubricationTable 2. Classification of waste used oil and wastes that contain oil transportWASTECHARACTERINDEXNUMBEROF WASTEADRCLASSPACKINGGROUPUNNUMBERdangerous waste 13 02 08* It is not classified according to ADRCast waste oils, mixturesof dangerous waste oilWaste oil emulsion, saltemulsionSolid waste contaminatedwith oildangerous waste 13 08 99 3 III 1993dangerous waste 13 08 02 It is not classified according to ADRdangerous waste 15 02 02 4.1 III 1325The remains of fuel dangerous waste 13 07 03 3 III 1202Of oil filters dangerous waste 16 01 07 4.1 III 3175Contaminated waste oilpackagingPackaging waste washedfrom the oildangerous waste 15 01 10 3 III 199315 01 04INVESTIGATION OF WASTE OIL USED IN THE REPUBLIC OF SERBIATesting of waste oil used in the Republic of Serbia for their classification are carried out since 2002. year. Thecomposition of used oils extremely varied depending on the source, and mixing and processing procedures.Samples of waste used motor oil, observed during the 2003rd by 2009. years were analyzed, the total concentrationof 8 heavy metals (Cr, Cu, Zn, Ni, Cd, Pb, Ba, As) of which As, metalloid. Heavy metals are defined as elementsthat show the properties of metals (ductility, conductivity, stability as cations, etc.) and atomic number greater of 20They are important environmental pollutants and many of them are toxic even at very low concentrations.Samples of waste used oil is extracted, by 1 gr. oil is treated with 10cm³ in the ratio of 1:1 HNO 3 . The sample isheated with reflux from 10 to 15 minutes without boiling. After cooling, 5 cm³ concentrated HNO 3 , added to, andcontinues with heating by reflux for 30 minutes. Mixture evaporation to about 5 cm³. The sample is cooled, afterwhich it is added to water 2cm and 3cm³ 30% H 2 O 2 . The vessel is covered with sahat glass and heated again tobegin the reaction of peroxide. After cooling, H 2 O 2 (30%), added in 1 cm³ solution.
Page 1 and 2: ISBN 978-86-83059-06-5Editor-in-Chi
Page 3 and 4: TRANSPORT OF DANGEROUS GOODSAND RIS
Page 5 and 6: EDITORIALLand transport Pan- Europe
Page 7 and 8: Contents:INTEGRATED MODEL AND INFOR
Page 9 and 10: TRANSPORT OF DANGEROUS GOODS AND RI
Page 17 and 18: Figure 3. Algorithm of Security Dat
Page 19 and 20: Figure 5. Algorithm of Ship Waste M
Page 21 and 22: Figure 7. Original Algorithm of Imp
Page 25 and 26: Figure 11. Original Algorithm of th
Page 27 and 28: Figure 13. Original Algorithm of th
Page 29 and 30: Figure 15. Original Algorithm of Ot
Page 33 and 34: Figure 18. The original algorithm o
Page 35 and 36: Figure 20. Original Algorithm of Ac
Page 39 and 40: Figure 23. Original Algorithm of In
Page 41 and 42: Figure 25. Original Algorithm of Ac
Page 51: TRANSPORT OF DANGEROUS GOODS AND RI
Page 59 and 60: Table 1. Classification of waste th
Page 61 and 62: Table 3 Classification of waste tha
Page 63 and 64: Table 3b Classification of waste th
Page 65 and 66: Table 3d: Classification of waste t
Page 67 and 68: Table 3f: Classification of waste t
Page 75 and 76: Table 6 Classes of the compounds th
Page 77 and 78: Table 6b Classes of the compounds t
Page 85 and 86: Table 8. Typical hazardous waste ma
Page 87 and 88: Figure 5.- Life cycle for oiled sol
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TRANSPORT OF DANGEROUS GOODS AND RI
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Figure 13. Original algorithm of th
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Software part of Sledat systemTRANS
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BIBLIOGRAPHYTRANSPORT OF DANGEROUS
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UDK:614.83:624.21TRANSPORT OF DANGE
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INTEGRATED C4I SYSTEMSTRANSPORT OF
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UDK:355.69614.878.084TRANSPORT OF D
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Oil, gas and mineralsTRANSPORT OF D
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UDK:811.111'25TRANSPORT OF DANGEROU
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transport of dangerous goods and risk management - Kirilo SaviÄ