transport of dangerous goods and risk management - Kirilo SaviÄ

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TRANSPORT OF DANGEROUS GOODS AND RISK MANAGEMENT 62Classification, characterisation and labelling of waste for the purposes of multimodal transportHazardous waste from the exploitation of vessels, after the reception on behalf of expert teams in a harbour, istransported by road or rail transport to the final destination for their treatment or disposal. For that reason, it isnecessary to carry out the preparation of waste which has labels for vessel labelling on the received containers orpacking (Tables 3 – 3g). Drawing on the fact that the national regulations on hazardous materials transport need tobe mainly in line with the international regulations ADN 8 and IMDG 9 (internal and maritime navigation), ADR 10(land transport) and RID 11 (rail transport), it turned out that it was necessary to conduct a classification for all theabove-stated dangerous waste materials, to determine the methods of labelling and to define the conditions oftransporting these materials, in accordance with the requirements of these regulations. Apart from that, it isnecessary to fulfil the requirements of other international institutions (the OECD, the UN, and the EuropeanCommission), conventions (the Basel Convention 12 , the MARPOL 73/78 Convention 13 ) and Decisions. Apart fromthe classification of hazardous waste, it is necessary to determine the categories of waste to be checked 12 , dangerouscharacteristics of waste and national waste labels.An additional problem is connected with different labels for labelling vehicles for transporting hazardous waste incertain types of traffic and packing for hazardous materials, which is particularly noticeable in the case of combined(multimodal) transport. National regulations in certain countries in the field of labelling waste materials are notreconciled with the stated international regulations, which additionally complicates the preparation of hazardouscargos for transport. That is why the adoption of universal labels for labelling packing according to GloballyHarmonised System of Classification and Labelling Chemicals for hazardous materials (GHS) 14 should be aspiredto.Legal claim for the classification of waste materials from the exploitation of vesselsIn the project, a thorough classification of waste was performed according to the following regulative:the list of waste from Annex VIII (List A) or Annex IX (List B) of the Basel Convention 12 and theEuropean Commission Regulations, which were transferred into the Law of the Republic of Serbia 16 ; the OECD lists (Green, Amber and Red) pursuant to No 1999/816/EC and the Decision of the Council C,the Amendments to this Decision, as well as the Code of the Republic of Serbia 4 ;European Catalogue of Waste (EWC List) 8 , in line with the Decision of the European Commission 19 , theRider to the Decision 2000/532/EC on the waste lists 20 , the Regulations of EC No 1013/2006 21 and theCode of the Republic of Serbia 4 .Additional classification in terms of the types of danger and labelling (through R-phrases for warning and S-phrasesfor announcement) was carried out pursuant to the EU Directives (Annex I B Directive 2001/59/EC 22 and Directive67/548/EEC 23 ) and the National Regulative 24 .According to the stated Regulative, there is a List with warning signs (of risk) R1 – R64 and the List with thepossible combinations of warning signs (in total 57 signs for all possible combinations). The warning signs R50 –R53 refer to the danger to aquatic organisms (R50 – very poisonous to aquatic organisms; R51 – poisonous toaquatic organisms and R52 – hazardous to aquatic organisms), whereas R53 and R58 indicate potential long-lastingundesirable effects on the aquatic, i.e. natural environment.With this Directive 23 the List of Chemicals was established (Chemical Legislation) of the European Union whichincludes the data for over 2500 substances on the degree of toxicity, risk, eco-toxicity, physical characteristics etc.In that way the following data on hazardous materials can be obtained:
TRANSPORT OF DANGEROUS GOODS AND RISK MANAGEMENT 63the R phrases – the degree of risk,the European code of hazardous materials,toxicity for the reproduction and degree of toxicity,mutagenicity and the category of mutagenicity.These data, together with the determined per cent content of a hazardous substance in waste (according to theanalyses) and the data on the burning point (from the data on safety lists), represent a basis for the successfulcharacterisation of hazardous waste.The List with announcement signs includes the signs S1 – S62. The List with the possible combinations ofannouncement signs is comprised of 17 signs in total, for all possible combinations.Legal claim for the categorisation of waste materials from the exploitation of vesselsThe categories of waste to be checked (Y List of the OECD) were determined pursuant to Annex I of the BaselConvention 12 and the Law of the Republic of Serbia 16 . The categories of waste, from the perspective of the activitiesfor operating waste, were determined according to the OECD Lists Q, D and R, which are included in Annex I (QList), Annex IIa (D List – with the labels of waste disposal procedures D1 – D15) and Annex IIb (R List – with thelabels of procedures for the reuse of waste R1 – R13) of the Directive 75/442/EEC 25 .Legal claim for the characterisation of waste materials from the exploitation of vesselsThe characterisation of Waste, i.e. the identification of the hazardous characteristic of waste, on the basis of H Listof the OECD (IWIC List) from Annex III of the Basel Convention 12 and H List from Annex III of the Directive91/689/EEC 26 , the Law of the Republic of Serbia 16 and the Code of the Republic of Serbia 27 . The waste ingredientswhich make waste dangerous were determined according to C List from Annex II of the Directive 91/689/EEC 28 . Inthe list, there are signs for 15 dangerous characteristics (H1 – H13). The sign H12 refers to eco-toxic wastecontents, and the sign H13 refers to waste which can, after disposal (e.g. drying), produce some of the dangerouscharacteristics of the previous 14.Identification and classification of waste materials, goods and waste according to Dangerous Goods List of theUNChemicals in transport, when on the market, i.e. when they are in transport, have their identification numbers. Forthe materials on the market the CAS Numbers are applied – the numbers of known substances from the register ofchemicals abstracts 29 (Chemicals Abstract Service).Certain lists for hazardous materials do not include raw materials and waste, hence, for the identification, we haveused the UN list of Dangerous Goods in Transport which is published by the Expert Committee for DangerousGoods Transport 29 under the auspices of the United Nations, which covers all types of dangerous goods andmaterials, regardless of the type of danger which they carry and the field of their application. The identificationnumber UN and the Class UN were determined according to the recommendations of the UN for the transport ofdangerous materials (recommendations of the UN for the transport of dangerous goods –the Model ofRegulations 30 ). This document defines and classifies the goods which are considered to be dangerous and regulatesthe safety and technical requirements in terms of packing, labelling and their manipulation. The document is thebasic instrument for the harmonisation of numerous international and national regulations on dangerous goodstransport. The European Accord on Transport of Dangerous Goods by land (ADR 10 ), rail (RID 11 ) and watertransport (ADN 8 ) completely adopted its structure and incorporated all its requirements. The main part of thisdocument is the list of dangerous goods, divided into nine classes, according to the type of basic danger.
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ISBN 978-86-83059-06-5Editor-in-Chi
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TRANSPORT OF DANGEROUS GOODSAND RIS
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EDITORIALLand transport Pan- Europe
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Contents:INTEGRATED MODEL AND INFOR
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TRANSPORT OF DANGEROUS GOODS AND RI
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Figure 3. Algorithm of Security Dat
Page 19 and 20: Figure 5. Algorithm of Ship Waste M
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Page 25 and 26: Figure 11. Original Algorithm of th
Page 27 and 28: Figure 13. Original Algorithm of th
Page 29 and 30: Figure 15. Original Algorithm of Ot
Page 33 and 34: Figure 18. The original algorithm o
Page 35 and 36: Figure 20. Original Algorithm of Ac
Page 39 and 40: Figure 23. Original Algorithm of In
Page 41 and 42: Figure 25. Original Algorithm of Ac
Page 59 and 60: Table 1. Classification of waste th
Page 61 and 62: Table 3 Classification of waste tha
Page 63 and 64: Table 3b Classification of waste th
Page 65 and 66: Table 3d: Classification of waste t
Page 67 and 68: Table 3f: Classification of waste t
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Page 75 and 76: Table 6 Classes of the compounds th
Page 77 and 78: Table 6b Classes of the compounds t
Page 85 and 86: Table 8. Typical hazardous waste ma
Page 87 and 88: Figure 5.- Life cycle for oiled sol
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Page 107 and 108: Software part of Sledat systemTRANS
Page 109 and 110: BIBLIOGRAPHYTRANSPORT OF DANGEROUS
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UDK:614.83:624.21TRANSPORT OF DANGE
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INTEGRATED C4I SYSTEMSTRANSPORT OF
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Oil, gas and mineralsTRANSPORT OF D
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UDK:811.111'25TRANSPORT OF DANGEROU
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