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Molecular beam epitaxial growth of III-V semiconductor ... - KOBRA

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Chapter 8<br />

Conclusions<br />

In summary, self-assembled MBE <strong>growth</strong> <strong>of</strong> InAs and InGaAs QDs on at Si(100)<br />

has been intensively studied. Reection high energy diraction (RHEED) streak<br />

patterns conrm that the combination <strong>of</strong> the atomic hydrogen followed by thermal<br />

desorption is an ecient surface cleaning method. An additional improvement<br />

for the cleaning and <strong>growth</strong> is achieved by exposing the Si surface with Ga at low<br />

uxes resulted in a strong reduction <strong>of</strong> the lateral size <strong>of</strong> InAs QDs from 50-70 nm<br />

down to 25-30 nm and a signicant enhancement <strong>of</strong> the homogeneity <strong>of</strong> the dot<br />

size and distribution. The evolution <strong>of</strong> size, density and shape <strong>of</strong> the QDs are exsitu<br />

characterized by AFM and TEM. Dierent <strong>growth</strong> parameters such as InAs<br />

coverage, <strong>growth</strong> temperature, In-<strong>growth</strong> rate and V/<strong>III</strong> ratio are examined on<br />

dierently prepared silicon surfaces. The InAs QDs density is strongly increased<br />

from 10 8 to 10 11 cm −2 at V/<strong>III</strong> ratios in the range <strong>of</strong> 15-35 (<strong>beam</strong> equivalent<br />

pressure values). InAs QD formations are not observed at temperatures as high<br />

as 500 ◦ C. Moreover, InAs quantum dashes are observed on at higher In-<strong>growth</strong><br />

rate <strong>of</strong> 0.3 ML/s.<br />

TEM characterizations <strong>of</strong> InAs QDs embedded in silicon matrix with dierent<br />

nominal thicknesses on dierent o-cuts substrates showed semi-coherent QDs<br />

with good crystal quality inside the dots and mist dislocations at the interface <strong>of</strong><br />

InAs/Si. The substrate ocut found to have inuence on the QDs shape and geometry.<br />

A very homogeneous narrow QDs size with D= 5-8 nm distribution with<br />

spherical to multi-facet shape has been observed on ocut substrate, compared<br />

to a broader size distribution with D= 15-25 nm observed on exactly oriented<br />

127

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