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Molecular beam epitaxial growth of III-V semiconductor ... - KOBRA

Molecular beam epitaxial growth of III-V semiconductor ... - KOBRA

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Chapter 3<br />

Hetero<strong>epitaxial</strong> Growth <strong>of</strong> <strong>III</strong>-V<br />

Semiconductor on Silicon<br />

Substrates<br />

3.1 Overview<br />

In order to realize the monolithic integration <strong>of</strong> <strong>III</strong>-V material on silicon substrate,<br />

high-quality <strong>III</strong>-V compound layers should be grown on a Si substrate. However,<br />

heteroepitaxy between <strong>III</strong>-V lms and silicon substrates induces a large strain<br />

energy in the lms. Due to the large lattice and thermal mismatches, this large<br />

strain is released by the formation <strong>of</strong> structural defects and dislocations in the<br />

<strong>III</strong>-V material [1, 4]. The structural defects resulted from the heteroepitaxy are<br />

closely related to carrier dynamics in the QDs and have severe inuence on their<br />

optical quality. Therefore, the density <strong>of</strong> structural dislocations should be reduced<br />

to an acceptable level or even defect-free structures as an ideal goal, since<br />

the performance <strong>of</strong> light emitting devices is deteriorated and is degraded due<br />

to the irradiative recombination processes occurring at defect centers. However,<br />

structural-defect-free <strong>III</strong>-V compounds have not been grown on Si substrates by<br />

lattice-mismatched heteroepitaxy regardless <strong>of</strong> a great deal <strong>of</strong> research [16, 3, 30].<br />

The key challenges in the heteroepitaxy <strong>of</strong> <strong>semiconductor</strong>s, relative to the development<br />

<strong>of</strong> useful optoelectronic devices, are the control <strong>of</strong> the <strong>growth</strong> morphology,<br />

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