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Molecular beam epitaxial growth of III-V semiconductor ... - KOBRA

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Theoretical Background <strong>of</strong> Semiconductor Nanostructures<br />

level can enhance material functions and characteristics, leading to considerable<br />

energy savings and environmental load reduction. However, according to this<br />

approach which is based on the monolithic integration <strong>of</strong> nanostructures <strong>semiconductor</strong>,<br />

such as (quantum dots QDs, quantum wells QWs, etc.) on silicon<br />

substrates. Nanostructures, such as quantum dots (QDs), can be fabricated with<br />

either a top-down technique or bottom-up technique. Top-down techniques are<br />

great for generating a uniform distribution <strong>of</strong> diameters. Unfortunately, top-down<br />

approaches like lithography are limited by the diraction limit and implies material<br />

damage and defects. The most common way to create a QD is through a<br />

bottom-up approach. This can be done either with metal-organic chemical vapor<br />

deposition (MOCVD) or MBE. Self-assembled quantum dots (SAQDs) nucleate<br />

spontaneously under certain conditions during MBE and metal-organic vapor<br />

phase epitaxy (MOVPE), when a material is grown on a substrate to which<br />

it is not lattice-matched. The resulting strain produces coherently strained islands<br />

on top <strong>of</strong> a two-dimensional wetting layer. This <strong>growth</strong> mode is known as<br />

Stranski-Krastanov (SK) <strong>growth</strong> (like InAs QDs on GaAs system). The islands<br />

can be subsequently buried to form the quantum dot. Therefore, the fundamental<br />

understanding <strong>of</strong> low-dimensional <strong>semiconductor</strong> physics and the electronic con-<br />

nement inside these structures is essential for the <strong>growth</strong> and characterization<br />

<strong>of</strong> these systems including their new structural and optical properties, etc. The<br />

next section will bring the focus on the underlaying physics, which explains these<br />

interesting nanostructures.<br />

2.3 Low-Dimensional Semiconductor (Nanostrtuctures)<br />

With the advent <strong>of</strong> <strong>epitaxial</strong> <strong>growth</strong> techniques like molecular <strong>beam</strong> epitaxy<br />

(MBE), the realization <strong>of</strong> low-dimensional structures became feasible. However,<br />

when one <strong>of</strong> the three spatial dimensions <strong>of</strong> a bulk solid, like in <strong>semiconductor</strong><br />

material, is <strong>of</strong> a size comparable to de Broglie wavelength (λ B ) (Eq. 2.1) <strong>of</strong> the<br />

electrons or smaller, this means we are dealing with a material or a structure<br />

<strong>of</strong> low-dimensionality (nanostructure) [18], which is referred as two-dimension<br />

12

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