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Molecular beam epitaxial growth of III-V semiconductor ... - KOBRA

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Theoretical Background <strong>of</strong> Semiconductor Nanostructures<br />

Structure Degree <strong>of</strong> connement Dimension <strong>of</strong> the structure<br />

Bulk 0 3D<br />

Quantum well (QW) 1 2D<br />

Quantum wire (QWR) 2 1D<br />

Quantum dot (QD) 3 0D<br />

Table 2.1: Classication <strong>of</strong> <strong>semiconductor</strong> nanostructures and their degree <strong>of</strong> quantum<br />

connement.<br />

According to Eq. 2.1 if one-dimension <strong>of</strong> a bulk <strong>semiconductor</strong> (assuming,<br />

box geometry) (L x , L y , L z ) is in the order <strong>of</strong> the de-Broglie wavelength (λ B ) or<br />

smaller (Eq. 2.2), the quantum size eect gets signicant. The wave-like behavior<br />

<strong>of</strong> electrons are also important on much longer dimensions, if you have to care on<br />

coherent phenomena. This is also true for band-structure formation caused by the<br />

coherent interaction with the periodic potential <strong>of</strong> the lattice and is valid in the<br />

whole solid. You would not understand this without using quantum mechanics<br />

[19].<br />

L x , L y , L z ≤ λ B (2.2)<br />

2.3.1 Density <strong>of</strong> States Function <strong>of</strong> Low-Dimensional Systems<br />

In quantum physics, the electronic structure is <strong>of</strong>ten analyzed in terms <strong>of</strong> the<br />

density <strong>of</strong> electron states (DOS). The DOS function, at a given value E <strong>of</strong> energy,<br />

is dened such that g(E)∆E is equal to the number <strong>of</strong> states (i.e. solutions <strong>of</strong><br />

Schrödinger equation) in the interval energy ∆E around E. However, if the<br />

dimensions L i (i = x, y, z) are macroscopic and if proper boundary conditions are<br />

chosen, the energy levels can be treated as quasi-continuous [19]. On the other<br />

hand, in the case where any <strong>of</strong> the dimensions L i gets small enough, the DOS<br />

function becomes discontinuous. Fig. 2.2 describes how the density <strong>of</strong> states<br />

changes as a function <strong>of</strong> dimensionality. It is clear that the density <strong>of</strong> state<br />

function (DOS) in Fig. 2.2 gets sharper as the dimension <strong>of</strong> the structure becomes<br />

14

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