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Molecular beam epitaxial growth of III-V semiconductor ... - KOBRA

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MBE Growth <strong>of</strong> Self-Assembled InAs and InGaAs Quantum Dots Embedded in<br />

Silicon Matrix<br />

which were kept xed and only the <strong>growth</strong> temperature was varied in the range <strong>of</strong><br />

400 − 500 ◦ C. Atomic force microscopy (AFM) images in Fig 5.6 shows that the<br />

InAs QDs density is slightly increased with increasing the <strong>growth</strong> temperature in<br />

the range <strong>of</strong> 400−450 ◦ C, while the QDs lateral dimensions (L) and average height<br />

(H av ) decreased from L = 33 - 55 nm and H av = 6.62 nm at 400 ◦ C (Fig. 5.6(a))<br />

to values <strong>of</strong> L = 15 - 40 nm and H av = 4.5 nm at 450 ◦ C (Fig. 5.6(b)). The<br />

main reason for these changes are related to Indium desorption, which starts to<br />

be signicant at 450 ◦ C (Fig. 5.6(b)). This causes a reduction <strong>of</strong> the dot sizes<br />

at 450 ◦ C and do not allow any InAs nucleation at 500 ◦ C (Fig. 5.6(c)), which<br />

is in agreement with literature where no nano-islands formation are observed at<br />

temperatures higher than 450 ◦ C [3].<br />

Figure 5.6:<br />

(1 × 1 µm 2 ) AFM images <strong>of</strong> 2 MLs InAs QDs grown using SK mode at<br />

dierent <strong>growth</strong> temperatures (a) 400 ◦ C, (b) 450 ◦ C, and (c) 500 ◦ C.<br />

5.3.3.4 V/<strong>III</strong> Ratio<br />

In this investigation only V/<strong>III</strong> ratio values were varied. By increasing the V/<strong>III</strong><br />

ratio from 15 to 35, the QDs density is strongly modied and increased from<br />

∼ 10 8 cm −2 (Fig. 5.7(a)) to ∼ 10 11 cm −2 (Fig. 5.7(c)). AFM measurements show<br />

denser QDs for samples grown at higher As 4 pressures. The V/<strong>III</strong> ratio has a<br />

similar impact on the layer <strong>growth</strong> as the substrate temperature. Too high values<br />

72

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