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Molecular beam epitaxial growth of III-V semiconductor ... - KOBRA

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Chapter 1<br />

Introduction<br />

Modern <strong>semiconductor</strong> microelectronics technology is mainly based on silicon<br />

as a key material, several advantages <strong>of</strong> silicon such as the very good electrical<br />

properties, high thermal conductivity, cheapness and the large scale availability<br />

made silicon the best candidate among other <strong>semiconductor</strong> materials in the<br />

current microelectronics industry. However, silicon has a very poor optical emission<br />

properties due to it is indirect band gab, and <strong>of</strong> very weak non-linearities,<br />

which is needed for optical switches, LEDs, lasers etc applications. In contrast,<br />

<strong>III</strong>-V materials are the dominate materials in today optoelectronics market due<br />

to their very excellent optical properties, because <strong>of</strong> their high eciency optical<br />

transitions, which originate from their direct fundamental band gap energy.<br />

The monolithic integration <strong>of</strong> the <strong>III</strong>-V on silicon holds a great promise for the<br />

future demonstration <strong>of</strong> the practical integrated <strong>III</strong>-V optoelectronic devices on a<br />

Si complementary metal oxide <strong>semiconductor</strong> (CMOS) platform as well as it will<br />

shift the optoelectronic market from using very expensive substrates like GaAs<br />

and InP to Si substrates. However, the hetero<strong>epitaxial</strong> <strong>growth</strong> <strong>of</strong> <strong>III</strong>-V quantum<br />

dots (QDs) directly on silicon substrates has proven to be quite challenging due<br />

to the defects caused by dislocations and anti-phase domains, which originate<br />

from the large lattice and thermal mismatches and polar/non-polar nature <strong>of</strong><br />

<strong>III</strong>/V and Si systems [1, 2]. These structural defects are closely related to carrier<br />

dynamics in the QDs and have severe inuence on their optical quality. So far,<br />

only few details on the <strong>growth</strong> mechanism <strong>of</strong> InAs and InGaAs nanostructures<br />

on at silicon substrates have been provided in literature [3, 4]. However, in this<br />

1

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