kimia-anorganik-taro-saito
a Bilangan oksidasi ............................................................................................................46 b Reaksi redoks..................................................................................................................46 c Diagram Latimer.............................................................................................................47 3.4 Asam basa ......................................................................................................... 48 a Asam basa Arrhenius ......................................................................................................49 b Asam basa Bronsted Lowry ............................................................................................49 4 Kimia Unsur Non-Logam ............................................................................ 55 4.1 Hidrogen dan hidrida ...................................................................................... 55 a Hidrogen .........................................................................................................................55 b Hidrida ............................................................................................................................56 4.2 Unsur golongan utama periode 2 dan 3 dan senyawanya ............................ 59 a Boron ..............................................................................................................................59 b Karbon ............................................................................................................................63 c Silikon.............................................................................................................................65 d Nitrogen ..........................................................................................................................66 e Fosfor ..............................................................................................................................66 4.3 Oksigen dan oksida .......................................................................................... 69 a Oksigen ...........................................................................................................................69 b Oksida hidrogen ..............................................................................................................70 c Silikon oksida..................................................................................................................71 d Oksida nitrogen...............................................................................................................74 e Oksida Fosfor..................................................................................................................78 f Belerang oksida..................................................................................................................79 g Oksida Logam.................................................................................................................80 h Oksida unsur golongan 14...............................................................................................87 i Asam isopoli, asam heteropoli, dan garam-garamnya........................................................88 4.4 Khalkogen dan khalkogenida.......................................................................... 90 a Unsu khalkogen...............................................................................................................90 b Kation dan anion poliatom khalkogen ............................................................................91 c Sulfida logam..................................................................................................................92 4.5 Halogen dan halida .......................................................................................... 93 a Produksi halogen.............................................................................................................94 b Senyawa oksigen.............................................................................................................96 c Halida non logam............................................................................................................96 d Halida logam...................................................................................................................98 4.6 Gas mulia dan senyawanya ........................................................................... 103 a Gas mulia ......................................................................................................................103 b Senyawa gas mulia........................................................................................................104 5 Kimia Logam Golongan Utama ................................................................ 107 5.1 Logam golongan 1 .......................................................................................... 107 5.2 Logam golongan 2 .......................................................................................... 109 5.3 Logam golongan 12 ........................................................................................ 111 5.4 Logam golongan 13 ........................................................................................ 112 5.5 Logam golongan 14 ........................................................................................ 115 vi
6 Kimia Logam Transisi ............................................................................... 116 6.1 Struktur kompleks logam.............................................................................. 116 a Atom pusat....................................................................................................................116 b Ligan .............................................................................................................................117 c Bilangan koordinasi dan struktur ..................................................................................118 6.2 Struktur electronik kompleks ....................................................................... 123 a Teori medan ligan .........................................................................................................123 b Kemagnetan ..................................................................................................................136 6.3 Kimia organologam logam blok d................................................................. 138 a Senyawa karbonil logam...............................................................................................139 b Kompleks hidrokarbon..................................................................................................142 c Kompleks Fosfin...........................................................................................................148 d Kompleks molekul kecil ...............................................................................................149 e Ikatan logam-logam ......................................................................................................152 6.4 Reaksi kompleks............................................................................................. 159 a Reaksi substitusi ligan...................................................................................................160 b Reaksi redoks................................................................................................................163 7 Lantanoid dan aktinoid.............................................................................. 166 7.1 Lantanoid........................................................................................................ 166 7.2 Aktinoid........................................................................................................... 167 8 Reaksi dan Sifat-sifat Fisik........................................................................ 171 8.1 Reaksi katalisis ............................................................................................... 171 a Katalis homogen ...........................................................................................................171 b Katalis padat..................................................................................................................174 8.2 Bioanorganik .................................................................................................. 175 a Oksidasi.........................................................................................................................176 b Fiksasi nitrogen.............................................................................................................177 c Fotosintesis ...................................................................................................................178 8.3 Sifat-sifat fisik................................................................................................. 179 a Sifat elektrik..................................................................................................................179 b Kemagnetan ..................................................................................................................183 c Sifat optis ......................................................................................................................183 Solusi......................................................................................................................................185 vii
- Page 2 and 3: 1 BUKU TEKS KIMIA ANORGANIK ONLINE
- Page 4 and 5: Pengantar Penerjemah Untuk mengatas
- Page 6 and 7: alata analitis yang lain. Kini menj
- Page 10 and 11: 1 Unsur dan Periodisitas Unsur-unsu
- Page 12 and 13: elektron didefinisikan dengan empat
- Page 14 and 15: Tabel 1.1 Sistem periodik unsur, an
- Page 16 and 17: Gambar 1.2 Klasifikasi unsur dalam
- Page 18 and 19: terbentuk antara unsur yang keelekt
- Page 20 and 21: 2 Ikatan dan Struktur Jari-jari ato
- Page 22 and 23: sifat kimia senyawa yang diketahui,
- Page 24 and 25: kita dapat mengkompilasi jari-jari
- Page 26 and 27: menentukan jarak antar ion d. A ada
- Page 28 and 29: Gambar 2.3 Susunan ccp bola. Bila k
- Page 30 and 31: Kisi dengan bola lain di pusat kisi
- Page 32 and 33: Gambar 2.7 Struktur NaCl. Cesium kh
- Page 34 and 35: [Jawab] empat kation ada di dalam s
- Page 36 and 37: susunan terjejal anion. Gambar 2.12
- Page 38 and 39: Unsur-unsur gas mulia memiliki stru
- Page 40 and 41: Tabel 2.6 Ke-elektronegativan Pauli
- Page 42 and 43: Walaupun definisi Mulliken jelas se
- Page 44 and 45: Gambar 2.15 Pembentukan orbital mol
- Page 46 and 47: Gambar 2.18 Orbital molekul H 2 . T
- Page 48 and 49: Orbital molekul dua atom yang berbe
- Page 50 and 51: Teori besar dan evaluasi Teori elek
- Page 52 and 53: Proses yang secara termodinamika ir
- Page 54 and 55: Zn +2 (aq) + 2 e - → Zn(s) ∆G 0
- Page 56 and 57: molibdenum adalah reduktor dan beru
6 Kimia Logam Transisi ............................................................................... 116<br />
6.1 Struktur kompleks logam.............................................................................. 116<br />
a Atom pusat....................................................................................................................116<br />
b Ligan .............................................................................................................................117<br />
c Bilangan koordinasi dan struktur ..................................................................................118<br />
6.2 Struktur electronik kompleks ....................................................................... 123<br />
a Teori medan ligan .........................................................................................................123<br />
b Kemagnetan ..................................................................................................................136<br />
6.3 Kimia organologam logam blok d................................................................. 138<br />
a Senyawa karbonil logam...............................................................................................139<br />
b Kompleks hidrokarbon..................................................................................................142<br />
c Kompleks Fosfin...........................................................................................................148<br />
d Kompleks molekul kecil ...............................................................................................149<br />
e Ikatan logam-logam ......................................................................................................152<br />
6.4 Reaksi kompleks............................................................................................. 159<br />
a Reaksi substitusi ligan...................................................................................................160<br />
b Reaksi redoks................................................................................................................163<br />
7 Lantanoid dan aktinoid.............................................................................. 166<br />
7.1 Lantanoid........................................................................................................ 166<br />
7.2 Aktinoid........................................................................................................... 167<br />
8 Reaksi dan Sifat-sifat Fisik........................................................................ 171<br />
8.1 Reaksi katalisis ............................................................................................... 171<br />
a Katalis homogen ...........................................................................................................171<br />
b Katalis padat..................................................................................................................174<br />
8.2 Bio<strong>anorganik</strong> .................................................................................................. 175<br />
a Oksidasi.........................................................................................................................176<br />
b Fiksasi nitrogen.............................................................................................................177<br />
c Fotosintesis ...................................................................................................................178<br />
8.3 Sifat-sifat fisik................................................................................................. 179<br />
a Sifat elektrik..................................................................................................................179<br />
b Kemagnetan ..................................................................................................................183<br />
c Sifat optis ......................................................................................................................183<br />
Solusi......................................................................................................................................185<br />
vii
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