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The j C (B) dependence at 50 K <strong>for</strong> <strong>the</strong> Y-enriched films <strong>and</strong> <strong>for</strong> <strong>the</strong> st<strong>and</strong>ard film from <strong>the</strong>stoichiometric target are shown in Fig. 6. The st<strong>and</strong>ard film has a ra<strong>the</strong>r high j C (0 T),4.5×10 6 A/cm -2 (about 2×10 6 A/cm -2 at 77 K), but all Y-enriched films show higher j C .The j C (B) dependence remains almost <strong>the</strong> same with increasing thickness of <strong>the</strong> film,proving <strong>the</strong> preservation of <strong>the</strong> film structure during film growth.3.3 YBCO thin films on yttria decorated substratesYBCO thin films (~240 nm) were simultaneously deposited from <strong>the</strong> stoichiometrictarget on two LSAT samples with different yttria decoration <strong>and</strong> on a reference bareLSAT substrate. The morphology of <strong>the</strong> obtained samples is shown in Fig. 7. Largeelongated particles are present on <strong>the</strong> surfaces of <strong>the</strong> films on yttria layers (Fig. 7a, c).The particles are oriented along two orthogonal directions on <strong>the</strong> film surfaces, suchbehavior is typical <strong>for</strong> a-oriented particles. This supposition, though, is not confirmed by<strong>the</strong> XRD measurements. Peaks of a-orientation are absent <strong>for</strong> <strong>the</strong> YBCO film on atemplate layer of nanoparticles (Fig. 8). A weak peak from an a-oriented part of <strong>the</strong> filmis observed only <strong>for</strong> <strong>the</strong> film on a uni<strong>for</strong>m yttria layer (top curve, Fig. 8), <strong>and</strong>, probably,corresponds to <strong>the</strong> small elongated particles on <strong>the</strong> film surface (Fig. 7b), that are rare onAFM micrographs of o<strong>the</strong>r films.The crystal structure of <strong>the</strong> c-oriented grains seems to be of higher quality <strong>for</strong> <strong>the</strong> filmson yttria layers: <strong>the</strong> peaks on <strong>the</strong> XRD θ/2θ-scans are smeared <strong>for</strong> <strong>the</strong> YBCO film on abare LSAT substrate, while clear K α1 /K α2 splitting can be seen on both o<strong>the</strong>r curves(Fig. 8, left). The reason is strain, <strong>for</strong> films on yttria layers δd/d = 0.3%, while on a baresubstrate it increases to 0.5%. The c lattice constant is <strong>the</strong> same <strong>for</strong> all three films <strong>and</strong>equals to 11.673 ±0.005 Å. A small c lattice constant implies a high critical temperature;indeed, all three films showed very high T c , 91.4-91.8 K. The YBCO film on a baresubstrate showed both <strong>the</strong> lowest T c <strong>and</strong> <strong>the</strong> widest superconducting transition (Fig. 9).As <strong>the</strong> c lattice constant in <strong>the</strong> films does not differ, this variation in superconductingtransition should be attributed to <strong>the</strong> difference in lattice perfection.Fig. 9. AC susceptibility curves <strong>for</strong> YBCO films deposited from a stoichiometric targeton LSAT substrates with yttria decoration. Solid line: bare LSAT substrate; dashed line:uni<strong>for</strong>m yttria layer; dotted line: template yttria nanoparicles layer.Risø International <strong>Energy</strong> Conference 2011 Proceedings Page 246

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