Apéndice 2. Construcción de diagramas logΣΠ-xC, aq-xCA Los valores de ΣΠ para cada par de equilibrio XC, aq y XCA ( B1− xCx A) sat. correspondiente al sistema SrCO3, ortorrómbico-CaCO3, ortorrómbico-H2O (figuras 2.4, 2.5, 2.6, 2.7, 2.8, y A2.1) aparecen recogidos en la tabla A2.I. La tabla A2.II muestra estos valores para el sistema SrCO3, romboédrico-CaCO3, romboédrico-H2O (figura 3.1). La tabla A2.III es el resultado de comparar celdas equivalentes de las tablas anteriores y escoger aquellas que presentan el valor más bajo de ΣΠ . Las casillas de color amarillo pertenecen al sistema SrCO ( B1− xCx A) sat. 3, romboédrico-CaCO3, romboédrico-H2O mientras que las restantes pertenecen al sistema SrCO3, ortorrómbico- CaCO3, ortorrómbico-H2O. Las celdas de color rojo, indican los pares de equilibrio que definen el equilibrio termodinámico. 264
TABLA A2.I. Valores de ΣΠ ( B1 C A) para cada par de equilibrio − x x sat. XC, aq y XCA del sistema SrCO3, ortorrómbico-CaCO3, ortorrómbico-H2O 1,000 0,975 0,950 0,925 0,900 0,875 0,850 0,825 0,800 0,775 0,750 0,725 0,700 0,675 0,650 0,625 0,600 0,575 0,550 0,525 0,500 0,475 0,450 0,425 0,400 0,375 0,350 0,325 0,300 0,275 0,250 0,225 0,200 0,175 0,150 0,125 0,100 0,075 0,050 0,025 0,000 0,000 - -6,7339 -7,0350 -7,2111 -7,3360 -7,4329 -7,5121 -7,5790 -7,6370 -7,6882 -7,7339 -7,7753 -7,8131 -7,8479 -7,8801 -7,9100 -7,9381 -7,9644 -7,9892 -8,0127 -8,0350 -8,0562 -8,0764 -8,0957 -8,1142 -8,1319 -8,1489 -8,1653 -8,1811 -8,1963 -8,2111 -8,2253 -8,2391 -8,2525 -8,2654 -8,2780 -8,2902 -8,3021 -8,3137 -8,3250 -8,3360 0,000 0,025 - -6,7933 -7,0865 -7,2579 -7,3794 -7,4736 -7,5505 -7,6154 -7,6716 -7,7211 -7,7654 -7,8054 -7,8419 -7,8754 -7,9063 -7,9351 -7,9620 -7,9872 -8,0109 -8,0333 -8,0545 -8,0746 -8,0937 -8,1119 -8,1293 -8,1459 -8,1617 -8,1769 -8,1914 -8,2053 -8,2187 -8,2314 -8,2436 -8,2552 -8,2661 -8,2764 -8,2859 -8,2944 -8,3013 -8,3048 - 0,025 0,050 - -6,8419 -7,1273 -7,2940 -7,4121 -7,5036 -7,5782 -7,6411 -7,6955 -7,7435 -7,7862 -7,8248 -7,8599 -7,8922 -7,9219 -7,9495 -7,9753 -7,9994 -8,0220 -8,0433 -8,0634 -8,0824 -8,1004 -8,1175 -8,1338 -8,1492 -8,1639 -8,1778 -8,1911 -8,2037 -8,2156 -8,2269 -8,2374 -8,2472 -8,2562 -8,2642 -8,2709 -8,2760 -8,2782 -8,2739 - 0,050 0,075 - -6,8891 -7,1667 -7,3288 -7,4434 -7,5322 -7,6045 -7,6654 -7,7180 -7,7643 -7,8056 -7,8428 -7,8766 -7,9076 -7,9361 -7,9625 -7,9871 -8,0101 -8,0316 -8,0518 -8,0708 -8,0888 -8,1057 -8,1217 -8,1368 -8,1511 -8,1646 -8,1774 -8,1894 -8,2006 -8,2111 -8,2209 -8,2298 -8,2378 -8,2448 -8,2505 -8,2545 -8,2562 -8,2537 -8,2415 - 0,075 0,100 - -6,9368 -7,2066 -7,3639 -7,4751 -7,5611 -7,6311 -7,6901 -7,7409 -7,7856 -7,8254 -7,8611 -7,8936 -7,9233 -7,9507 -7,9759 -7,9994 -8,0212 -8,0416 -8,0607 -8,0787 -8,0955 -8,1114 -8,1262 -8,1402 -8,1534 -8,1657 -8,1773 -8,1880 -8,1979 -8,2071 -8,2153 -8,2226 -8,2288 -8,2338 -8,2372 -8,2385 -8,2367 -8,2296 -8,2096 - 0,100 0,125 - -6,9856 -7,2476 -7,4002 -7,5080 -7,5913 -7,6590 -7,7160 -7,7650 -7,8081 -7,8463 -7,8807 -7,9119 -7,9403 -7,9664 -7,9905 -8,0128 -8,0335 -8,0528 -8,0709 -8,0877 -8,1035 -8,1182 -8,1320 -8,1449 -8,1569 -8,1680 -8,1784 -8,1878 -8,1964 -8,2042 -8,2109 -8,2166 -8,2210 -8,2240 -8,2251 -8,2237 -8,2185 -8,2066 -8,1789 - 0,125 0,150 - -7,0360 -7,2901 -7,4381 -7,5425 -7,6230 -7,6884 -7,7434 -7,7907 -7,8321 -7,8689 -7,9018 -7,9317 -7,9589 -7,9838 -8,0067 -8,0278 -8,0474 -8,0656 -8,0826 -8,0983 -8,1130 -8,1266 -8,1393 -8,1511 -8,1620 -8,1719 -8,1810 -8,1893 -8,1965 -8,2029 -8,2081 -8,2121 -8,2148 -8,2158 -8,2146 -8,2105 -8,2018 -8,1853 -8,1497 - 0,150 0,175 - -7,0882 -7,3345 -7,4778 -7,5788 -7,6566 -7,7197 -7,7727 -7,8182 -7,8580 -7,8932 -7,9248 -7,9533 -7,9792 -8,0029 -8,0246 -8,0447 -8,0631 -8,0802 -8,0961 -8,1107 -8,1243 -8,1369 -8,1485 -8,1591 -8,1688 -8,1776 -8,1855 -8,1925 -8,1984 -8,2033 -8,2071 -8,2095 -8,2104 -8,2094 -8,2059 -8,1990 -8,1870 -8,1657 -8,1223 - 0,175 0,200 - -7,1423 -7,3808 -7,5194 -7,6169 -7,6920 -7,7529 -7,8038 -7,8475 -7,8857 -7,9195 -7,9496 -7,9768 -8,0015 -8,0239 -8,0445 -8,0634 -8,0807 -8,0967 -8,1115 -8,1251 -8,1376 -8,1490 -8,1595 -8,1690 -8,1776 -8,1852 -8,1919 -8,1976 -8,2022 -8,2057 -8,2080 -8,2088 -8,2079 -8,2049 -8,1991 -8,1895 -8,1740 -8,1481 -8,0969 - 0,200 0,225 - -7,1983 -7,4291 -7,5629 -7,6571 -7,7294 -7,7880 -7,8369 -7,8789 -7,9154 -7,9477 -7,9764 -8,0023 -8,0257 -8,0469 -8,0663 -8,0840 -8,1003 -8,1152 -8,1288 -8,1413 -8,1527 -8,1631 -8,1725 -8,1809 -8,1883 -8,1948 -8,2002 -8,2047 -8,2080 -8,2101 -8,2108 -8,2100 -8,2073 -8,2023 -8,1942 -8,1819 -8,1630 -8,1324 -8,0734 - 0,225 0,250 - -7,2563 -7,4792 -7,6084 -7,6991 -7,7687 -7,8250 -7,8720 -7,9121 -7,9470 -7,9778 -8,0051 -8,0297 -8,0518 -8,0718 -8,0901 -8,1066 -8,1218 -8,1356 -8,1481 -8,1595 -8,1699 -8,1791 -8,1874 -8,1947 -8,2010 -8,2063 -8,2105 -8,2137 -8,2156 -8,2163 -8,2156 -8,2131 -8,2087 -8,2016 -8,1913 -8,1762 -8,1539 -8,1186 -8,0518 - 0,250 0,275 - -7,3161 -7,5313 -7,6558 -7,7431 -7,8100 -7,8639 -7,9089 -7,9472 -7,9805 -8,0098 -8,0358 -8,0590 -8,0798 -8,0987 -8,1157 -8,1311 -8,1451 -8,1578 -8,1693 -8,1796 -8,1889 -8,1970 -8,2042 -8,2104 -8,2155 -8,2196 -8,2227 -8,2246 -8,2252 -8,2245 -8,2222 -8,2182 -8,2119 -8,2029 -8,1903 -8,1725 -8,1467 -8,1067 -8,0321 - 0,275 0,300 - -7,3778 -7,5852 -7,7050 -7,7889 -7,8530 -7,9047 -7,9476 -7,9842 -8,0159 -8,0437 -8,0682 -8,0901 -8,1097 -8,1273 -8,1432 -8,1575 -8,1704 -8,1819 -8,1923 -8,2015 -8,2097 -8,2168 -8,2229 -8,2279 -8,2319 -8,2348 -8,2367 -8,2373 -8,2366 -8,2345 -8,2307 -8,2250 -8,2170 -8,2060 -8,1911 -8,1705 -8,1414 -8,0967 -8,0143 - 0,300 0,325 - -7,4413 -7,6408 -7,7559 -7,8364 -7,8978 -7,9472 -7,9882 -8,0230 -8,0530 -8,0793 -8,1024 -8,1230 -8,1413 -8,1577 -8,1724 -8,1855 -8,1973 -8,2078 -8,2171 -8,2252 -8,2323 -8,2383 -8,2433 -8,2472 -8,2500 -8,2518 -8,2524 -8,2518 -8,2498 -8,2463 -8,2410 -8,2337 -8,2238 -8,2108 -8,1936 -8,1704 -8,1378 -8,0884 -7,9982 - 0,325 0,350 - -7,5064 -7,6981 -7,8085 -7,8856 -7,9443 -7,9914 -8,0303 -8,0633 -8,0918 -8,1165 -8,1383 -8,1575 -8,1746 -8,1898 -8,2033 -8,2153 -8,2259 -8,2353 -8,2435 -8,2506 -8,2565 -8,2615 -8,2653 -8,2681 -8,2698 -8,2704 -8,2698 -8,2679 -8,2646 -8,2597 -8,2529 -8,2440 -8,2324 -8,2174 -8,1978 -8,1719 -8,1359 -8,0818 -7,9837 - 0,350 0,375 - -7,5731 -7,7570 -7,8627 -7,9363 -7,9923 -8,0371 -8,0741 -8,1053 -8,1321 -8,1554 -8,1757 -8,1936 -8,2094 -8,2234 -8,2357 -8,2466 -8,2561 -8,2644 -8,2715 -8,2775 -8,2824 -8,2862 -8,2889 -8,2906 -8,2912 -8,2906 -8,2888 -8,2856 -8,2810 -8,2746 -8,2664 -8,2558 -8,2424 -8,2254 -8,2036 -8,1749 -8,1355 -8,0767 -7,9708 - 0,375 0,400 - -7,6412 -7,8173 -7,9183 -7,9885 -8,0418 -8,0843 -8,1192 -8,1487 -8,1739 -8,1956 -8,2146 -8,2311 -8,2457 -8,2584 -8,2696 -8,2793 -8,2877 -8,2949 -8,3009 -8,3058 -8,3096 -8,3123 -8,3140 -8,3145 -8,3140 -8,3122 -8,3092 -8,3047 -8,2988 -8,2910 -8,2813 -8,2691 -8,2539 -8,2349 -8,2108 -8,1794 -8,1365 -8,0731 -7,9594 - 0,400 0,425 - -7,7106 -7,8789 -7,9753 -8,0421 -8,0926 -8,1328 -8,1657 -8,1934 -8,2170 -8,2372 -8,2548 -8,2700 -8,2833 -8,2948 -8,3048 -8,3134 -8,3207 -8,3267 -8,3317 -8,3355 -8,3382 -8,3398 -8,3404 -8,3398 -8,3381 -8,3352 -8,3309 -8,3252 -8,3179 -8,3088 -8,2975 -8,2837 -8,2668 -8,2458 -8,2193 -8,1852 -8,1389 -8,0708 -7,9493 - 0,425 0,450 - -7,7813 -7,9418 -8,0334 -8,0968 -8,1446 -8,1824 -8,2134 -8,2393 -8,2612 -8,2800 -8,2961 -8,3101 -8,3221 -8,3324 -8,3412 -8,3487 -8,3548 -8,3598 -8,3636 -8,3663 -8,3680 -8,3685 -8,3680 -8,3663 -8,3634 -8,3593 -8,3538 -8,3469 -8,3382 -8,3277 -8,3150 -8,2995 -8,2808 -8,2578 -8,2291 -8,1922 -8,1425 -8,0696 -7,9404 - 0,450 0,475 - -7,8530 -8,0057 -8,0926 -8,1525 -8,1976 -8,2332 -8,2622 -8,2863 -8,3066 -8,3239 -8,3386 -8,3512 -8,3619 -8,3710 -8,3787 -8,3850 -8,3900 -8,3939 -8,3966 -8,3982 -8,3988 -8,3982 -8,3966 -8,3938 -8,3898 -8,3845 -8,3778 -8,3696 -8,3596 -8,3477 -8,3334 -8,3164 -8,2959 -8,2709 -8,2399 -8,2003 -8,1472 -8,0696 -7,9325 - 0,475 0,500 - -7,9256 -8,0705 -8,1527 -8,2092 -8,2516 -8,2849 -8,3119 -8,3342 -8,3529 -8,3686 -8,3820 -8,3932 -8,4027 -8,4106 -8,4171 -8,4222 -8,4262 -8,4289 -8,4305 -8,4311 -8,4305 -8,4289 -8,4262 -8,4222 -8,4171 -8,4106 -8,4027 -8,3932 -8,3820 -8,3686 -8,3529 -8,3342 -8,3119 -8,2849 -8,2516 -8,2092 -8,1527 -8,0705 -7,9256 - 0,500 0,525 - -7,9990 -8,1361 -8,2136 -8,2667 -8,3063 -8,3373 -8,3623 -8,3829 -8,3999 -8,4142 -8,4261 -8,4360 -8,4443 -8,4510 -8,4562 -8,4602 -8,4631 -8,4647 -8,4653 -8,4647 -8,4631 -8,4603 -8,4565 -8,4514 -8,4452 -8,4375 -8,4284 -8,4177 -8,4051 -8,3903 -8,3731 -8,3527 -8,3287 -8,2997 -8,2641 -8,2190 -8,1591 -8,0721 -7,9194 - 0,525 0,550 - -8,0730 -8,2023 -8,2751 -8,3248 -8,3617 -8,3904 -8,4134 -8,4321 -8,4476 -8,4603 -8,4709 -8,4795 -8,4864 -8,4919 -8,4960 -8,4989 -8,5006 -8,5011 -8,5006 -8,4990 -8,4962 -8,4924 -8,4874 -8,4813 -8,4738 -8,4650 -8,4547 -8,4427 -8,4288 -8,4126 -8,3939 -8,3719 -8,3461 -8,3151 -8,2772 -8,2294 -8,1660 -8,0744 -7,9139 - 0,550 0,575 - -8,1475 -8,2689 -8,3371 -8,3834 -8,4175 -8,4440 -8,4649 -8,4819 -8,4957 -8,5070 -8,5161 -8,5234 -8,5291 -8,5334 -8,5363 -8,5380 -8,5386 -8,5380 -8,5364 -8,5337 -8,5299 -8,5249 -8,5189 -8,5116 -8,5030 -8,4930 -8,4815 -8,4682 -8,4530 -8,4354 -8,4152 -8,3916 -8,3639 -8,3310 -8,2908 -8,2402 -8,1735 -8,0771 -7,9088 - 0,575 0,600 - -8,2223 -8,3359 -8,3994 -8,4423 -8,4737 -8,4978 -8,5168 -8,5320 -8,5442 -8,5539 -8,5616 -8,5676 -8,5720 -8,5751 -8,5769 -8,5774 -8,5769 -8,5752 -8,5725 -8,5687 -8,5638 -8,5578 -8,5506 -8,5422 -8,5325 -8,5213 -8,5086 -8,4940 -8,4774 -8,4585 -8,4367 -8,4116 -8,3821 -8,3471 -8,3047 -8,2514 -8,1812 -8,0802 -7,9041 - 0,600 0,625 - -8,2972 -8,4031 -8,4619 -8,5013 -8,5300 -8,5518 -8,5688 -8,5822 -8,5928 -8,6010 -8,6073 -8,6120 -8,6151 -8,6170 -8,6176 -8,6170 -8,6153 -8,6126 -8,6087 -8,6038 -8,5979 -8,5908 -8,5825 -8,5730 -8,5621 -8,5498 -8,5358 -8,5200 -8,5021 -8,4817 -8,4585 -8,4317 -8,4004 -8,3635 -8,3187 -8,2627 -8,1891 -8,0834 -7,8995 - 0,625 0,650 - -8,3721 -8,4701 -8,5243 -8,5602 -8,5862 -8,6057 -8,6207 -8,6324 -8,6413 -8,6481 -8,6530 -8,6563 -8,6582 -8,6588 -8,6582 -8,6565 -8,6537 -8,6498 -8,6449 -8,6390 -8,6319 -8,6237 -8,6143 -8,6037 -8,5917 -8,5782 -8,5630 -8,5459 -8,5267 -8,5049 -8,4802 -8,4517 -8,4187 -8,3797 -8,3327 -8,2740 -8,1969 -8,0865 -7,8948 - 0,650 0,675 - -8,4468 -8,5370 -8,5864 -8,6190 -8,6422 -8,6595 -8,6725 -8,6823 -8,6896 -8,6949 -8,6984 -8,7004 -8,7010 -8,7004 -8,6987 -8,6958 -8,6919 -8,6869 -8,6809 -8,6739 -8,6657 -8,6564 -8,6459 -8,6342 -8,6210 -8,6063 -8,5899 -8,5716 -8,5510 -8,5279 -8,5016 -8,4716 -8,4368 -8,3958 -8,3465 -8,2850 -8,2045 -8,0894 -7,8899 - 0,675 0,700 - -8,5211 -8,6035 -8,6482 -8,6773 -8,6978 -8,7128 -8,7238 -8,7318 -8,7375 -8,7413 -8,7434 -8,7441 -8,7434 -8,7416 -8,7387 -8,7347 -8,7297 -8,7236 -8,7165 -8,7083 -8,6991 -8,6887 -8,6771 -8,6643 -8,6500 -8,6341 -8,6165 -8,5969 -8,5750 -8,5504 -8,5227 -8,4910 -8,4544 -8,4115 -8,3598 -8,2956 -8,2118 -8,0920 -7,8846 - 0,700 0,725 - -8,5947 -8,6693 -8,7093 -8,7351 -8,7528 -8,7655 -8,7745 -8,7808 -8,7848 -8,7871 -8,7878 -8,7871 -8,7852 -8,7822 -8,7781 -8,7730 -8,7668 -8,7596 -8,7514 -8,7422 -8,7319 -8,7204 -8,7077 -8,6937 -8,6783 -8,6612 -8,6424 -8,6215 -8,5983 -8,5724 -8,5431 -8,5098 -8,4715 -8,4265 -8,3725 -8,3057 -8,2183 -8,0939 -7,8787 - 0,725 0,750 - -8,6675 -8,7343 -8,7696 -8,7919 -8,8070 -8,8174 -8,8244 -8,8288 -8,8313 -8,8320 -8,8314 -8,8294 -8,8262 -8,8220 -8,8167 -8,8104 -8,8031 -8,7948 -8,7856 -8,7752 -8,7638 -8,7513 -8,7375 -8,7223 -8,7058 -8,6875 -8,6675 -8,6454 -8,6208 -8,5935 -8,5627 -8,5278 -8,4877 -8,4407 -8,3844 -8,3148 -8,2241 -8,0949 -7,8720 - 0,750 0,775 - -8,7392 -8,7982 -8,8289 -8,8478 -8,8601 -8,8681 -8,8732 -8,8759 -8,8767 -8,8759 -8,8738 -8,8705 -8,8661 -8,8606 -8,8542 -8,8468 -8,8384 -8,8290 -8,8186 -8,8072 -8,7947 -8,7810 -8,7662 -8,7499 -8,7322 -8,7128 -8,6915 -8,6681 -8,6423 -8,6135 -8,5813 -8,5447 -8,5028 -8,4538 -8,3953 -8,3229 -8,2288 -8,0949 -7,8642 - 0,775 0,800 - -8,8097 -8,8608 -8,8868 -8,9023 -8,9118 -8,9176 -8,9206 -8,9215 -8,9207 -8,9185 -8,9150 -8,9104 -8,9047 -8,8980 -8,8904 -8,8818 -8,8723 -8,8618 -8,8503 -8,8378 -8,8242 -8,8095 -8,7935 -8,7761 -8,7573 -8,7367 -8,7142 -8,6896 -8,6624 -8,6322 -8,5985 -8,5603 -8,5166 -8,4656 -8,4048 -8,3297 -8,2321 -8,0936 -7,8550 - 0,800 0,825 - -8,8784 -8,9218 -8,9431 -8,9551 -8,9620 -8,9655 -8,9665 -8,9656 -8,9632 -8,9594 -8,9545 -8,9486 -8,9416 -8,9337 -8,9249 -8,9152 -8,9046 -8,8930 -8,8804 -8,8668 -8,8522 -8,8363 -8,8192 -8,8008 -8,7807 -8,7590 -8,7353 -8,7094 -8,6809 -8,6493 -8,6141 -8,5743 -8,5288 -8,4758 -8,4127 -8,3349 -8,2339 -8,0906 -7,8443 - 0,825 0,850 - -8,9453 -8,9809 -8,9974 -9,0061 -9,0102 -9,0114 -9,0104 -9,0077 -9,0037 -8,9984 -8,9921 -8,9848 -8,9766 -8,9675 -8,9575 -8,9467 -8,9349 -8,9222 -8,9086 -8,8939 -8,8782 -8,8612 -8,8430 -8,8234 -8,8023 -8,7793 -8,7544 -8,7273 -8,6974 -8,6645 -8,6277 -8,5863 -8,5390 -8,4840 -8,4186 -8,3381 -8,2337 -8,0857 -7,8315 - 0,850 0,875 - -9,0098 -9,0375 -9,0494 -9,0546 -9,0560 -9,0549 -9,0519 -9,0475 -9,0418 -9,0351 -9,0274 -9,0188 -9,0093 -8,9990 -8,9878 -8,9758 -8,9629 -8,9491 -8,9344 -8,9186 -8,9018 -8,8838 -8,8645 -8,8437 -8,8214 -8,7973 -8,7712 -8,7428 -8,7116 -8,6772 -8,6390 -8,5960 -8,5469 -8,4899 -8,4222 -8,3389 -8,2311 -8,0785 -7,8165 - 0,875 0,900 - -9,0714 -9,0914 -9,0986 -9,1003 -9,0990 -9,0956 -9,0906 -9,0844 -9,0771 -9,0689 -9,0598 -9,0498 -9,0391 -9,0276 -9,0152 -9,0021 -8,9881 -8,9732 -8,9573 -8,9405 -8,9226 -8,9035 -8,8830 -8,8612 -8,8377 -8,8125 -8,7852 -8,7554 -8,7230 -8,6872 -8,6474 -8,6028 -8,5519 -8,4929 -8,4229 -8,3369 -8,2257 -8,0684 -7,7986 - 0,900 0,925 - -9,1295 -9,1416 -9,1441 -9,1425 -9,1385 -9,1328 -9,1258 -9,1178 -9,1088 -9,0991 -9,0886 -9,0773 -9,0653 -9,0526 -9,0391 -9,0248 -9,0097 -8,9937 -8,9767 -8,9588 -8,9398 -8,9196 -8,8981 -8,8751 -8,8505 -8,8241 -8,7955 -8,7646 -8,7307 -8,6936 -8,6523 -8,6060 -8,5534 -8,4924 -8,4201 -8,3314 -8,2167 -8,0547 -7,7771 - 0,925 0,950 - -9,1829 -9,1873 -9,1851 -9,1800 -9,1733 -9,1652 -9,1563 -9,1465 -9,1359 -9,1247 -9,1128 -9,1002 -9,0869 -9,0730 -9,0583 -9,0428 -9,0266 -9,0095 -8,9915 -8,9725 -8,9524 -8,9311 -8,9084 -8,8844 -8,8586 -8,8310 -8,8013 -8,7690 -8,7339 -8,6953 -8,6525 -8,6046 -8,5502 -8,4873 -8,4127 -8,3212 -8,2031 -8,0364 -7,7510 - 0,950 0,975 - -9,2296 -9,2261 -9,2193 -9,2108 -9,2013 -9,1910 -9,1800 -9,1684 -9,1563 -9,1435 -9,1302 -9,1163 -9,1018 -9,0866 -9,0707 -9,0541 -9,0368 -9,0186 -8,9995 -8,9794 -8,9582 -8,9358 -8,9121 -8,8869 -8,8600 -8,8312 -8,8002 -8,7667 -8,7302 -8,6903 -8,6460 -8,5965 -8,5403 -8,4753 -8,3984 -8,3042 -8,1827 -8,0113 -7,7181 - 0,975 1,000 -9,2710 -9,2600 -9,2487 -9,2371 -9,2252 -9,2130 -9,2004 -9,1875 -9,1741 -9,1603 -9,1461 -9,1313 -9,1161 -9,1003 -9,0839 -9,0669 -9,0492 -9,0307 -9,0114 -8,9912 -8,9700 -8,9477 -8,9242 -8,8994 -8,8731 -8,8450 -8,8151 -8,7829 -8,7481 -8,7103 -8,6689 -8,6232 -8,5720 -8,5140 -8,4471 -8,3679 -8,2710 -8,1461 -7,9700 -7,6689 - 1,000 1,000 0,975 0,950 0,925 0,900 0,875 0,850 0,825 0,800 0,775 0,750 0,725 0,700 0,675 0,650 0,625 0,600 0,575 0,550 0,525 0,500 0,475 0,450 0,425 0,400 0,375 0,350 0,325 0,300 0,275 0,250 0,225 0,200 0,175 0,150 0,125 0,100 0,075 0,050 0,025 0,000 XSr 2+ , aq XSrCO3
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UNIVERSIDAD COMPLUTENSE DE MADRID F
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UNIVERSIDAD COMPLUTENSE DE MADRID F
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El detalle íntimo y preciso sirve
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También a la gente de Oviedo: Mano
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-4- Formación a escala molecular d
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-1- INTRODUCCIÓN, OBJETIVOS Y ESTR
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Introducción, objetivos y estructu
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Crecimiento Producto A- +B + +C + A
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Introducción, objetivos y estructu
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Introducción, objetivos y estructu
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Introducción, objetivos y estructu
- Page 23 and 24:
Termodinámica de los sistemas solu
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Termodinámica de los sistemas solu
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Termodinámica de los sistemas solu
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Termodinámica de los sistemas solu
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Termodinámica de los sistemas solu
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Termodinámica de los sistemas solu
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Termodinámica de los sistemas solu
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Termodinámica de los sistemas solu
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Termodinámica de los sistemas solu
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Termodinámica de los sistemas solu
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Termodinámica de los sistemas solu
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-3- COMPORTAMIENTO DE EQUILIBRIO EN
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Comportamiento de equilibrio en los
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Comportamiento de equilibrio en los
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Comportamiento de equilibrio en los
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Comportamiento de equilibrio en los
- Page 55 and 56:
Comportamiento de equilibrio en los
- Page 57 and 58:
Comportamiento de equilibrio en los
- Page 59 and 60:
Comportamiento de equilibrio en los
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Comportamiento de equilibrio en los
- Page 63 and 64:
-4- FORMACIÓN A ESCALA MOLECULAR D
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Formación a escala molecular de so
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Formación a escala molecular de so
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Formación a escala molecular de so
- Page 71 and 72:
Formación a escala molecular de so
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Tabla 4.II. Modos de operación de
- Page 75 and 76:
4.1.3.- Aplicación del AFM a la mi
- Page 77 and 78:
Formación a escala molecular de so
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Formación a escala molecular de so
- Page 81 and 82:
Formación a escala molecular de so
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2µm 2µm a c Formación a escala m
- Page 85 and 86:
Formación a escala molecular de so
- Page 87 and 88:
Formación a escala molecular de so
- Page 89 and 90:
4.2.3.- Sistema (Ba,Ca)CO3-H2O 4.2.
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H + OH - Iones libres y pares ionic
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3µm 1µm c a Formación a escala m
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3µm a Formación a escala molecula
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Formación a escala molecular de so
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Solución 3 Formación a escala mol
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1 µm a Formación a escala molecul
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4.2.4.- Sistema (Sr,Ca)CO3-H2O 4.2.
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Iones libres y pares H + OH - Ca 2+
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4.2.4.2.- Resultados Solución 1 Fo
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3µm g Formación a escala molecula
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3µm a 3µm c Formación a escala m
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Solución 2 Formación a escala mol
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3µm i Figura 4.25. Continuación F
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Solución 3 Formación a escala mol
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5 µm i Formación a escala molecul
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5 µm a Formación a escala molecul
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Formación a escala molecular de so
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Formación a escala molecular de so
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4.2.5.- Sistema (Mn,Ca)CO3-H2O 4.2.
- Page 129 and 130:
Formación a escala molecular de so
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3µm (2) a (3) (1) 3µm c (4) Forma
- Page 133 and 134:
Formación a escala molecular de so
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Formación a escala molecular de so
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3µm a Formación a escala molecula
- Page 139 and 140:
Formación a escala molecular de so
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3µm e Formación a escala molecula
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3µm a Formación a escala molecula
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Formación a escala molecular de so
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4.3.- Discusión Formación a escal
- Page 149 and 150:
Formación a escala molecular de so
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(1014) (1014) (1014) Formación a e
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4.3.2- Sistema (Ba,Ca)CO3-H2O Forma
- Page 155 and 156:
Formación a escala molecular de so
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logΣΠ -5,1 -5,6 -6,1 -6,6 -7,1 -7
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Formación a escala molecular de so
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Formación a escala molecular de so
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1 1 c d β=140 0,9 β=213 0,9 0,8 0
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Formación a escala molecular de so
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Formación a escala molecular de so
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4.3.4- Sistema (Mn,Ca)CO3-H2O Forma
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Formación a escala molecular de so
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Formación a escala molecular de so
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Formación a escala molecular de so
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-5- CRISTALIZACIÓN DE (Ba,Ca)CO3 Y
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Cristalización de (Ba,Ca)CO3 y BaC
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Cristalización de (Ba,Ca)CO3 y BaC
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Cristalización de (Ba,Ca)CO3 y BaC
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a) b) Cristalización de (Ba,Ca)CO3
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Cristalización de (Ba,Ca)CO3 y BaC
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Cristalización de (Ba,Ca)CO3 y BaC
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Concentración (mmol/l) 0,035 0,03
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A/(B+A) 0,6 0,5 0,4 0,3 0,2 0,1 0,0
- Page 195 and 196: Cristalización de (Ba,Ca)CO3 y BaC
- Page 197 and 198: Cristalización de (Ba,Ca)CO3 y BaC
- Page 199 and 200: Cristalización de (Ba,Ca)CO3 y BaC
- Page 201 and 202: Cristalización de (Ba,Ca)CO3 y BaC
- Page 203 and 204: Cristalización de (Ba,Ca)CO3 y BaC
- Page 205 and 206: Cristalización de (Ba,Ca)CO3 y BaC
- Page 207 and 208: Cristalización de (Ba,Ca)CO3 y BaC
- Page 209 and 210: Cristalización de (Ba,Ca)CO3 y BaC
- Page 211 and 212: Cristalización de (Ba,Ca)CO3 y BaC
- Page 213 and 214: Cristalización de (Ba,Ca)CO3 y BaC
- Page 215 and 216: Cristalización de (Ba,Ca)CO3 y BaC
- Page 217 and 218: -6- DISCUSIÓN
- Page 219 and 220: Discusión la existencia como fase
- Page 221 and 222: Discusión 5). Sin embargo, la cris
- Page 223 and 224: -7- CONCLUSIONES
- Page 225 and 226: Conclusiones 6. Con el fin de carac
- Page 227 and 228: Conclusiones carbonatos dobles tien
- Page 229 and 230: Bibliografía Asano, M. y Mugiya, Y
- Page 231 and 232: Bibliografía Chiarello, R.P.; Woge
- Page 233 and 234: Bibliografía Garrels, R.M. y Chris
- Page 235 and 236: Levine, I. (1991): Fisicoquímica.
- Page 237 and 238: Bibliografía Prieto, M.; Putnis, A
- Page 239 and 240: Bibliografía Stipp, S.L.S., Konner
- Page 241 and 242: -9- APÉNDICES
- Page 243 and 244: Apéndice 1. Cálculo de la especia
- Page 245: Apéndice 2. Construcción de diagr
- Page 249 and 250: TABLA A2.III. Valores de ΣΠ ( B1
- Page 251 and 252: Apéndice 3. Representación de dis
- Page 253 and 254: Apéndice 3. Representación de dis
- Page 255 and 256: Apéndice 4. Método de Sverjensky
- Page 257 and 258: Apéndice 4. Método de sverjensky