SPME Applications Guide - Overbrook Scientific

(New references added to the 7th edition are in bold) SPME Fiber /
Analyte / Extraction
Matrix Literature Reference
Automated determination of ecstasy and amphetamines
Conditions Instrument
482 Ecstasy and in urine by SPME and capillary GC after 100µm PDMS GC-NPD
amphetamines polylchloroformate derivatization. 16 min, immersed or MS
in urine J. Pharm. Bomed. Anal. (1999), 19(3+4), 463-475
Ugland, H., Kogh, M., Rasmussen, K.
pH10
927 Amphetamine,
Determination of amphetamine, methamphetamine and
dimethamphetamine in human urine by SPME-GC-MS 100µm PDMS GC-MS
methamphetamine J. chromatogr. B (1998), 716(1-2) 359-365 30 min, immersed
pH 12.4 KOH, NaCl
dimethamphetamine Myung, S., Min, H., Kim, S., Kim, M., Cho, J., Kim, T.
added
in urine
Rapid analysis of amphetamine, methamphetamine,
stirred
562 Amphetamines MDA, and MDMA in urine using SPME, direct On-Fiber 100µm PDMS GC-MS
in urine derivatization, and analysis by GC-MS 10 min @ 100°C
J. Anal. Toxicol. 24, 11-16 (2000) headspace, 2N NaOH
Jurado, C., Gimenez, M., Soriano, T., 20 min @ 60°C on fiber
Menedez, M., Repetto, M. trifluoroacetic anhydride
483 Amphetamines
Rapid Analysis Amphetamines in Blood Using SPME
20th Japan Biomedical Mass Spectrometry:127-130(1995) 100µm PDMS GC-MS
in urine & blood Yashiki,M., Kojima,T. 5 min @ 80°C
immersed, NaOH added
484 Amphetamines
Detection of Amphetamines and Inflammable Compounds in
Biological Materials Using GC/MS and SPME 100µm PDMS GC-MS
in urine & blood Jpn. J. Forensic Toxicol. 12(2):120-121(1994) 5 min @ 80°C
Yashiki, M., Kojima,T., Miyazaki,T. immersed, NaOH added
188 Amphetamines
Quantitative and Qualitative Analysis of MDMA, MDEA, MA,
and Amphetamine in Urine by Headspace/SPME and GC/MS 100µm PDMS GC-MS
in urine Forensic Sci. Intl. 83 (3): 161-166 (1996) 5 min @ 90°C
Centini, F., Masti, A., Comparini, I. headspace
70 Amphetamines
Detection of Amphetamines in Urine Using Head Space
SPME and Chemical Ionization Selected Ion Monitoring 100µm PDMS GC-FID
in urine Forensic Sci Intl., 76(2), 169-177 (1995) 5 min
Yashiki, M., Kojima, T., Miyazaki, T., 80°C
Nagasawa, N., Iwasaki, Y., Hara, K. stirring
Rapid Analysis of Amphetamines in Blood Using Headspace
173 Amphetamines SPME and Selected-Ion Monitoring 100µm PDMS GC-SIM-MS
in blood Forensic Sci. Intl. 78 (2): 95-102 (1996) 5 min @ 80°C
Nagasawa, N., Yashiki, M., Iwasaki, Y., Hara, K., Kojima, T.
Method Optimization for the Analysis of Amphetamines in
heptafluorobutyr- amide
derivative
327 Amphetamines Urine by SPME 100µm PDMS GC-FID
in urine Anal. Chem. 69 (19): 3899-3906 (1997) 15-60 min
Lord, H., Pawliszyn, J.
Simple Clean-up of Methamphetamine and Amphetamine in
headspace
stirring
192 Amphetamines Human Urine by Direct-Immersion SPME 100µm PDMS GC-NPD
in urine Jpn. J. Forensic Toxicol. 14 (3): 228-232 (1996) 30 min @ 65°C
Ishii, A., Seno, H., Kumazawa, T., Suzuki, O., Na2CO3 added
Nishikawa, M., Watanabe, K., Hattori, H. immersed
145 Amphetamines
Application of SPME Technique for the Detection of Urinar
Methamphetamine and Amphetamine by GC GC
in urine J. Can. Soc. Forensic Sci. 29(2): 43-48, (1996)
Ameno, K., Fuke, C., Ameno, S., Kinoshita, H., Ijirei, I.
2744 Impurities in
Identification of impurities and the statistical classification of
methamphetamine using headspace SPME-GC-MS Car/DVB 30/50µm GC-MS
metamphetamine Forensic Sci. Int. 160, #1, 44-52 (2006-06-27) 30 min @ 85°C
Kuwayama, K.; Tsujikawa, K.; Miyaguchi, H.; Kanamori, T.; Iwata, Y.;
Inoue, H.; Saitoh, S.; Kishi, T.
headspace
Ambient temperature, unless otherwise indicated. 114