SPME Applications Guide - Overbrook Scientific

(New references added to the 7th edition are in bold) SPME Fiber /
Analyte / Extraction
Matrix Literature Reference Conditions Instrument
New method for the rapid determination of volatile
786 Volaitle amines substances: The SPME-direct method. Part II. Determination GC-FID, NPD
in fish of the freshness of fish
Sens Actuators, B Chem (2001) 72(3), 204-207 headspace
Bene, A.; Hayman, A.; Luisier, J.L.; Reynard, E.; Villettaz, J
SPME-GC-MS integrated with chemometrics for detection of
2468 Volatiles from Salmonella typhimurium contamination in a packaged fresh vegetable headspace GC-MS
salmonella Anal. Chim. Acta 581, #1, 63-70 (2 Jan. 2007)
infected
alfalfa sprouts
Siripatrawan, Ubonrat; Harte, Bruce R
SPME/GC of Salmonella-Infected Beef
619 Volatiles from J Agric Food Chem, 2000, 48, 2253-2259 75µm Carboxen/PDMS GC-FID
salmonellas infected Ogihara, H., Horimoto, Y., Hai, Z., Skura, B., Nakai, S. 10 min
beef
Use of Digital Aroma Technology and SPME GC-MS to
25% NaCl
393 Volatiles from compare Volatile compounds Produced by Bacteria 100µm PDMS GC-MS
processed poultry isolated from Processed Poultry 30 min @ 37°C
J. Sci. food Agric. 1998, 78, 343-348 headspace
Arnold, J., Senter, S. stirred
862 Allyl isothiocyanate
Formation of allyl isothiocyanate from sinigrin in the
digestive tract of rats monoassociated with a human colonic GC-MS
in rats strain of Bacteroides thetaiotaomicron
FEMS Microbiology Letters (2001) 197(1) 99-103
Rabot, S; Duguay, A; Elfoul, L; Khelifa, N; Quinsac,A; Rimbault, A
headspace
253 Putrescine,
An Electrodeposition Device for the Determination of
Putrescine and Cadaverine by High-Resolution GC carbon fibers HPLC
cadaverine in J. High Resolut. Chromatogr. 19 (5): 294-297 (1996) 0-60 min, immersion (C18 column)
borate buffer solution Conte, E., Miller, D.
Measurement of volatile oxidation products from milk using .
stirring
pH 8
2727 Oxidative products solvent-assisted flavour evaporation and SPME headspace GC-MS
from milk Intl Dairy Journal 17, #7, 746-752 (2007)
Havemose, M. S.; Justesen, P.; Bredie, W. L. P.; Nielsen, J. H.
40°C
620 Hexanal, pentanal
Shelf-life prediction of processed milk by SPME -MS and
multivariate analysis 75µm Carboxen/PDMS GC-MS
metabolites in milk J. Agric Food chem (2000), 48(8), 3470-3475 20min. @ 50°C
Marsili, R. headspace
Comparison of SPME and Dynamic Headspace Methods for
386 Oxidative byproducts the GC-MS Analysis of Lighted Induced Lipid Oxidation 75µm Carboxen/PDMS GC-MS
in milk Products in Milk 45°C, 15 min
J. Chromatogr. Sci. 1999, 37, 17-23 headspace
Marsili, R. salt added
Influence of flavor variability in skim milk powder on consumer
2274 Off-flavors acceptability of ingredient applications headspace GC/MS
in skim milk powder J Food Science 70 #7, S427-S431 (2005)
Caudle, Alissa D.; Yoon, Youngmo; Drake, Maryanne
Quantitative determination of thermally derived off-flavor
2301 Off-flavor compounds in milk using SPME-GC headspace GC/MS
compounds J Dairy Science 88 #11, 3764-3772 (2005)
in milk Vazquez-Landaverde, P. A.; Velazquez, G.; Torres, J. A.; Qian, M.
372 Off-flavors
SPME-MS-MVA as an Electronic Nose for the Study of
Off-Flavors in Milk 75µm Carboxen/PDMS GC-MS
in milk J. Agric. Food Chem. 1999, 47, 648-654 45°C, 12 min
Marsili, R. headspace
2627 Volatile flavors
Research advances: Squeezing more shelf life out of milk
J Chem Educ 84, #4, 572-574 (April 2007) headspace GC/MS
in milk King, Angela G.
Ambient temperature, unless otherwise indicated. 23