SPME Applications Guide - Overbrook Scientific

(New references added to the 7th edition are in bold) SPME Fiber /
Analyte / Extraction
Matrix Literature Reference
Analysis of Substituted Benzene Compounds in
Conditions Instrument
6 BTEX, gasoline Groundwater Using SPME 56µm PDMS GC-FID
in water J. Env. Sci. Technol. 26: 979-983 (1992) 2-6 min
Arthur, C., Potter, D., Lim, M., Motlagh, S.,
Killam, L., Pawliszyn, J.
stirring
2616 BTEX compounds
Determination of benzene, toluene, ethylbenzene, xylenes in water at
sub-ng l(-1) levels by SPME coupled to cryo-trap GC-MS 75µm Carboxen GC-MS
in water Chemosphere 69, #9, 1381-1387 (NOV 2007) 15 min @ 25°C
Lee, Maw-Rong; Chang, Chia-Min; Dou, Jianpeng sat. salt
7 BTEX compounds
Dynamics of Organic Compounds Extraction from
Water Using Liquid-Coated Fused Silica Fibers 56µm PDMS GC-FID
in water Anal. Chem. 64: 1187-1199 (1992) 2-6 min
Louch, D., Motlagh, S., Pawliszyn, J. stirring
10 BTEX compounds
Detection of Substituted Benzenes in Water at the pg/mL
Level Using Solid Phase Microextraction and 100µm PDMS GC-FID
in water GC-Ion Trap Mass Spectrometer 30 min
J. Chromatogr. 625: 247-255 (1992)
Potter, D., Pawliszyn, J.
stirring
11 Organics
Environmental Analysis of Organic Compounds in
Water Using Solid Phase Microextraction 100µm PDMS GC-MS
in water J. High Res. Chromatogr. 15: 741-744 (1992) 14 min
Arthur, C., Pratt, K., Belardi, R., Motlagh, S., Pawliszyn, J. stirring
14 Phenols
Determination of Phenols by SPME and GC Analysis
J. Environ. Sci. Technol. 27 (13): 2844-2848 (1993) 85µm polyacrylate GC-FID, -MS
in water Buchholz, K., Pawliszyn, J. 60 min
stirring
salt added, pH 2
Determination of Phenolic Compounds in Waste Water
230 Phenols by Solid-Phase Microextraction GC-MS
in water Fresenius’ J. Anal. Chem. 357: 326-332 (1997)
Moeder, M., Schrader, S., Franck, U., Popp, P.
670 Phenols
Sorption of phenols to dissolved organic matter
investigated by SPME
in water Sci. Total Environ. (2000), 253(1-3), 63-74
Ohlenbusch, G., Kumke, M., Frimmel, F.
922 Phenolic compounds
SPME coupled to liquid chromatography for the analysis
of phenolic compounds in water 50µm CW/TPR HPLC
in water J. Chromatogr. A (2001) 923(1-2), p45-52 65µm DVB/PDMS
Toledo, E., Prat, M., Alpendurada, M. 30min immersed
salt added, pH 2
951 Chlorinated phenolics
Application of SPME in pre-concentration of chlorinated
phenolic compounds from cellulose bleaching effluents
in water J. Sep. Sci (2001), 24(4), 309-312
Dos Santos, L.; Vale, M.; De Araujo, M.
Bertrand C.; Caramao, E.; Oliveira, E.
Recent Advances in Solid-Phase Microextraction
15 VOCs, phenols, (SPME) of Environmental Samples 100µm PDMS GC-MS
semivolatiles Proceedings Water Quality Technology Conference 5 min (volatiles)
in water Miami, FL, Nov. 1993 10 min (semivolatiles)
Arthur, C., Pratt, K., Belardi, R., Motlagh, S., Pawliszyn, J. headspace
stirring, salt added
671 4-Quinolones
Influence of pH and other modifying factors on the
distribution behaviors of 4-Quinolones to Solid phase and CW/TPR HPLC
in water humic acids studied by "negligible-depletion" SPME-HPLC 10min. 260NM
Environ Sci Technol. 2000, 34, 4989-4994 pH 3-5.5
Lutzhoft, H. Vaes, W., Freidig, A., Halling-Sorrensen, B.
Hermens, J.
stirred
Ambient temperature, unless otherwise indicated. 142