SPME Applications Guide - Overbrook Scientific

(New references added to the 7th edition are in bold) SPME Fiber /
Analyte / Extraction
Matrix Literature Reference Conditions Instrument
Use of the SPME-GC-MS technique to study the thermal degradation
2822 Thermal of isotactic polypropylene: Effects of temperature and reaction time, heaspace GC-MS
byproducts of and analysis of the reaction mechanism
polypropylene E-Polymers Jan 30 2008
Bortoluzzi, J.; Carasek, E.; Cristiano, R.; Gallardo, H..; Soldi, V.
SPME to concentrate volatile products from thermal
1763 Thermal degradation of polymers 100µm PDMS, GC-MS
byproducts of Polym Degradation Stab, 89, #1, 33-37 75µm Carboxen
polypropylene Bortoluzzi, J.; Carasek, E; Pinheiro, E.; Soldi, V
2880 Degradation
Comparison of extraction methods for sampling of low molecular
compounds in polymers degraded during recycling headspace GC
products of Eur Polym J 44, #6, 1583-1593 (June 2008)
polymers Karlsson, Sigbritt; Moller, Johanna; Stromberg, Emma
Emission of possible odourous low molecular weight
1764 Odours from compounds in recycled biofibre/polypropylene composites heaspace GC-MS
polypropylene monitored by head-space SPME-GC-MS
composites Polym Degradation Stab, 90. #3, 555-562
De Las Heras, Luis A.; Espert, Ana; Karlsson, Sigbritt
Development and analytic of odor absorber
1765 Odor Tenside Surfactants Deterg, 41, #6, 282-286 headspace GC
removal by Bohmer, Thomas; Muller, Felix; Peggau, Jorg
Zn ricinoleate
Headspace-SPME-GC-MS identification of volatile organic
1766 Volatiles from compounrds released from expanded polystyrene 75µm Carboxen GC-MS
polystyrene J. Polym. Environ., 12, #2, 83-87 headspace
Knupp, Gerd; Kusch, Peter
Correlation between emitted and total amount of
1767 2-cyclopentyl- 2-cyclopentyl- cyclopentanone in polamide 6.6 headspace GC-MS
cyclo- allows rapid assessment by Head Space and HS-SPME . GC-RI
pentanone in under non-equilibrium conditions
polamide 6.6 J. Chromatogr. A, 1052, #1-2, 151-159
Groning, Mikael; Hakkarainen, Minna
Identification and migration of degradation compounds from irradiation
2864 Degradation of multilayer polyamide 6 films for meat foodstuffs and cheese 100µm PDMS GC-MS
compounds Anal. Bioanal. Chem. 391, #3, 847-857 (June 2008) 20 min, 80 °C
of Polamide 6 Felix, J.S.; Manzoli, J.E.; Monteiro, M.; Nerin, C.; Padula, M.;
Pezo, D.; Romero, J.
Multiple headspace SPMEof 2-cyclopentyl- cyclopentanone
1768 2-cyclopentyl- in polyamide 6.6: Possibilities and limitations in the headspace GC-MS
cyclopentanone headspace analysis of solid hydrogen-bonding matrices
in polamide 6.6 J. Chromatogr. A, 1052, #1-2, 61-68
Groning, Mikael; Hakkarainen, Minna
Chemical characterization of oil-based asphalt release agents
2308 Volatiles from and their emissions headspace GC/MS
Asphalt release Fuel 85 #9, 1232-1241 (2006)
agents Isacsson, Ulf; Tang, Bing
Determination of aromatic hydrocarbons in asphalt release
1769 Hydrocarbons agents using headspace SPME-GC-MS headspace GC-MS
from asphalt J Chromatogra, A, 1069, #2, 235-244
Isacsson, Ulf; Tang, Bing
Natural Products
401 Volatiles
Analysis of Tobacco Volatiles with SPME
Dr. W.D. Koller, Federal Research Centre for Nutrition, 100µm PDMS GC-MS
in tobacco Institute of Process Engineering, Engesserstr. 20, 10 min
76131 Karlsruhe/Deutschland headspace
402 Pesticides in
A Simple Screening for Pesticide Residues in Tobacco
Dr. W.D. Koller, Federal Research Centre for Nutrition, 100µm PDMS GC-MS
water/MeOH extract Institute of Process Engineering, Engesserstr. 20, 10 min
76131 Karlsruhe/Deutschland immersion
Ambient temperature, unless otherwise indicated. 72