SPME Applications Guide - Overbrook Scientific

(New references added to the 7th edition are in bold) SPME Fiber /
Analyte / Extraction
Matrix Literature Reference Conditions Instrument
421 Amphetamines,
Determination of Amphetamine and Methamphetamine in Human Hair
by Headspace SPME and GC-NPD 100µm PDMS GC-NPD
methamphetamine J. Chromatogr. B: Biomed. Sci. Appl. (1998), 707(1+2) 99-104 15 min @45°C
in hair Koide, I., Noguchi, O., Okada, K., Yokoyama, A., Oda, H.,
Yamamoto, S., Kataoka, H.
immersed, NaOH added
194 Methamphetamine,
Rapid Analysis of Methamphetamine and Cocaine in the
Urine of Drug Abusers with SPME 100µm PDMS GC-FTD
cocaine Chromatography 18 (3): 185-188 (1996) 15 min
in urine Makino, Y., Takgi, T., Ohta, S., Hirobe, M.
Screening Procedure for 21 Amphetamine-Related
immersion
pH 10.5
198 Amphetamines Compounds in Urine Using SPME and 100µm PDMS GC-MS
in urine Gas Chromatography-Mass Spectrometry 80°C, 10 min
J. Chromatogr. Sci. 36: 1-7 (1998) headspace
Battu, C., Marquet, P., Fauconnet, A., Lacassie, E.,
Lachatre, G.
salt added
Automated drug analysis by in-tube SPME-LC-MS
566 Amphetamines in Chromatography. Jun 1999; 20(2): 142-145 60cm x 0.25mm ID tube LC-MS
urine Kataoka,-H; Lord,-HL; Pawliszyn,-J Omegawax 250 electrospray
Simple and rapid determination of amphetamine,
651 Amphetamines methamphetamine and their methylenedioxyl derivatives in In-tube Omegawax 250
60cmx0.25mmi.d.x0.25µ
LC-MS
in urine urine by automated in-tube SPME coupled with LC-electrospray
ionization mass spectrometry
J. Anal. Toxicol (2000), 24(4), 257-265
Kataoka,-H; Lord,-HL; Pawliszyn,-J
m electrospray
652 Amphetamines
Determination of amphetamine and methamphetamine
in serum via headspace derivatization SPME-GC-MS PDMS GC-MS
methamphetamine J. Chromatogr. A, 896, (2000) 265-273 40 min, headspace
in serum Lee, M., Song, Y., Hwang, B., Chou, C. pH 9.5
heptafluorobutyric
anhydride ethyl acetate
831 Amphetamines
On-fiber derivatization for direct immersion SPME part I:
acylation of amphetamine with pentafluorobenzoyl chloride
J. Sep. Sci. (2001) 24(2), 116-122
Koster, E; Bruins, C.; Wemes, C; De Jong, G.
Determination of automated In-tube SPME-LC-MS
765 Beta blockers for drug analysis In-tube Omegawax 250 LC-MS
in urine, serum J.MIcroSeparation,(2000-9), 12(9), 493-500
Kataoka,-H; Lord,-HL; Pawliszyn,-J
electrospray
794 Beta blockers
Determination of beta-blockers by HPLC w/SPME
from urine and plasma samples 85µm polyacrylate HPLC
in urine, serum Analytical Letters (2001) 34(1), 91-101
Tanabe, S; Shimokawa, K; Matsuda, Y.,Katayama, M;
Daimon, H,Hara. I; Kaneko, S; Sato, T.
Comparison of New Solid Phase Extraction Methods for
71
Amphetamines,
alcohols Chromatographic Identification of Drugs in Clinical 100µm PDMS, GC-FID
in urine, serum Toxicology Analysis 85µm polyacrylate
Degel, F., Weidemann, G.
Some Problems of Detecting Amphetamines in Biological
60°C, 15 min
headspace
485 Amphetamines in Materials by using Triage 100µm PDMS GC-MS
biological fluids Pract. Forens. Med. 40:99-102 (1997) 5 min @ 80°C
Watanabe,T., Namera,A., Yashiki,M., Iwasaki,Y., Kojima,T. CaCO3 added
headspace
Ambient temperature, unless otherwise indicated. 115