SPME Applications Guide - Overbrook Scientific

(New references added to the 7th edition are in bold) SPME Fiber /
Analyte / Extraction
Matrix Literature Reference
Analysis of Drugs and Poisons in Legal Medicine
Conditions Instrument
234 Drug Summary J. Mass Spectrom. Soc. Jpn. 44: 321-333 (1996) Various fibers &
Suzuki, O., Seno, H., Ishii, A. conditions
79 Drugs of abuse
Determination of Drugs of Abuse Using SPME (German)
Labor-Med. 18 (2): 112-118 (1995) 100µm PDMS, GC-MS
in urine Singer, K., Wenz, B., Seefeld, V., Speer, U. 85µm polyacrylate
40°C, 20 min
immersion, stirring
2541 Cocaine in
Determination of cocaine and cocaethylene in plasma by SPME-GC-MS
J. Chromatogr., B: 845, #1, 90-94 (2007-01-01) headspace GC-MS
plasma Alvarez, I.; Bermejo, A. M.; Tabernero, M. J.; Fernandez, P.; Lopez, P
2534 Cocaine
Evidence on unusual way of cocaine smuggling: Cocaine-polymethyl
methacrylate (PMMA) solid solution-study of clandestine laboratory
samples GC-MS
in polymethyl FORENSIC SCI. INT. 169, #2-3, 210-219 (04 JUL 2007)
methacrylate Gostic, T.; Klemenc, S.
81 Cocaine
Detection of Cocaine in Human Urine by SPME and Capillary
GC with Nitrogen-Phosphorus Detection 100µm PDMS GC-FPD
in urine Jpn. J. Forensic Toxicol. 13 (3): 207-210 (1995) 30 min
Kumazawa, T., Watanabe, K., Sato, K., Seno, H., immersion, stirring
Ishii, A., Suzuki, O. NaF added
Focused microwave-assisted extraction combined with SPME-
2210 Cocaine from GC-MS for the selective analysis of cocaine from coca leaves 100µm PDMS GC-MS
coca leaves J. Chromatogr. A, 1112, #1-2,127-132 (2006) immersion
Bicchi, C.; Bieri, Stefan; Christen, P.; Ilias, Yara; Veuthey, J.
SPME/GC-MS characterization of volatiles associated
653 Volatiles with cocaine and heroin
30/50Carboxen/DVB/PD
MS GC-MSD
from cocaine, heroin Am. Lab, Sept. 2000, 32-34 85µm polyacrylate
Vu, D., Nicholas, P. Erikson, C.
Field and Laboratory comparison of the sensitivity and
90 min
headspace
486 Methyl Benzoate reliability of cocaine detection on currency using GC-MS-MS
on currency chemical sensors, humans, K-Os and SPME/GC/MS
Proceeding SPIE-Int. Soc. Opt. Eng, 3576:41-46 (1999)
Furton, K., Hsu, Y., Luo, T., Norelus, A., Rose, S.
907 Daidzein, isoflavon
Detection of the isoflavone aglycones genistein and daidzein
in urine using SPME-HPLC-electrospray MS LC-MS
aglycones genistein J. Chromatogr. B (2001), 759(1) 33-41
in urine Satterfield, M., Black, D., Brodbelt, J.
164 Barbiturates
Determination of Barbiturates by SPME and Ion Trap GC-MS
J. Chromatogr. A 777: 275-282 (1997) 65µm Carbowax/DVB GC-MS
in water Hall, B., Brodbelt, J.
Aqueous phase hexyl chloroformate derivatization and SPME
20 min
immersion, stirring
572 Benzoylecgonine determination of benzoylecgonine in urine by GC- 100µm PDMS GC-EMIS
in urine Quadrapole ion trap mass spectrometry 10 mi. @ 55°C
J-Forensic-Sci. May 1999; 44(3): 527-534 hexyl chloroformate
Hall,-BJ; Parikh,-AR; Brodbelt,-JS derivative
224 Barbiturates
Determination of Barbiturates by SPME and Capillary
Electrophoresis polyvinyl coated electrophoresis
in urine and serum Anal. Chem. 69: 1217-1222 (1997) metal rod 230nm
Li, S., Weber, S. 5, 10, 30 min
80 Meperidine
Detection of Meperidine (Pethidine) in Human Blood and Urine
Artificial receptor-facilitated SPME of barbiturates. 100µm PDMS GC-FID
596 Barbiturates Anal-Chem. 1 Jun 1999; 71(11): 2146-2151 PVC/steel rod CE
in urine/serum Li,-S; Sun,-LF; Chung,-Y; Weber,-SG 5 min
immersed
Ambient temperature, unless otherwise indicated. 116