SPME Applications Guide - Overbrook Scientific

(New references added to the 7th edition are in bold) SPME Fiber /
Analyte / Extraction
Matrix Literature Reference Conditions Instrument
Bicchi, C., Panero, O., Pellegrino, G., Vanni, A.
Obtention of a Brewed Coffee Aroma Extract by an
60°C, 5 min
headspace
302 Volatile aroma Optimized Supercritical CO2-Based Process 100µm PDMS GC-MS
in brewed coffee J. Agric. Food Chem. 1998, 46, 4011-4016 60°C, 10 min
Ramos, E., Valero, E., Ibanez, E., Reglero, G., Tabera, J. headspace
623 Aroma volatiles
SPME Method Development for Headspace analysis of
volatile flavor compounds PDMS/DVB GC-MS
in coffee J. Agri. Food Chem 2000, 48, (6) 2430-2437 60 min headspace
Roberts, D., Pollien, P., Milo, C. pH 2
Screening for 2-Acetyl-1-pyrroline in the Headspace of Rice
624 2-Acetyl-1-pyrroline using SPME/GC-MS
80µm
Carboxen/DVB/PDMS GC-MS
in rice J. Agric. Food Chem 2001, 49, 245-249 80°C, 15 min
Grimm, C, Bergman, jC., Delgado, J., Bryant, R.
Removal of geosmin and 2-methylisorboneol (2-MIB) in water from
headspace
.75gm in 100µl H20
2642 2-MIB, geosmin Zuikerbosch Treatment Plant (Rand Water) using β-cyclodextrin headspace GC-MS
in water polyurethanes
Water SA 33, #2, 223-227 (April 2007)
Krause, R.; Malefetse, T.; Mamba, B.; Mhlanga, S.; Nxumalo, E.;
Salipira, K.L.; Sithole, S.
Microwave mediated distillation with SPME
464 2-MIB, geosmin determination off-flavors, geosmin and 100µm PDMS GC-MS
in water methylisoborneol, in catfish tissue 25 min
J. Chromatogr. A (1999), 833(2), 223-230 immersed
Zhu, M., Aviles, F., Conte, E., Miller, D., salt added
Perschbacher, P.
Microwave Distillation-SPME-GC Analysis of
625 2-MIB, geosmin 2-methylisoboreneol and Geosmin in Catfish
80µm
Carboxen/DVB/PDMS GC-IC-MS
in water Am-Lab Feb 2000: 32(3), 40-48 60°C, 20 min
Lloyd, S., Grimm, C. heaspace
Analysis of 2-Methylisoboreneol and Geosmin in Catfish
2-MIB, geosmin by Microwave Distillation-SPME 100µm PDMS GC-MS
in water J. Agri. Food Chem., 47, No. 1, pg. 164-169, 1999 40°C, 15 min
Lloyd, S., Grimm, C. saturated salt
stirring
362 MIB & geosmin
Determination of Geosmin and 2-Methylisoboreneol in Water
Using SPME and GC-Chemical Ionization/Electron Impact Carboxen/DVB/PDMS GC-MS
in water Ionization Ion Trap MS 60°C, 30 min
Analyst (Cambridge, U.K.) (1998), 123 (10), 2155-2160 headspace
McCallum, R., Pendleton, P., Scumann, R., Trinh, M. stirring
salt added
2429 MTBE in
Evaluating peats for their capacities to extract methyl tertiary
butyl ether from contaminated water using SPME-GC headspace GC-MS
drinking water J Environ Sci Health A 43, #2, 132-43 (2008 Feb)
Rizzuti, Anthony M; Cohen, Arthur D; Nguyen, Dung D
Evaluating peats for their capacities to extract methyl tertiary
2871 MTBE in butyl ether from contaminated water using SPME-GC headspace GC-MS
drinking water J EnviSci and Health Part A 43, #6, 672-673 (2008)
Rizzuti, Anthony
Evaluation of zeolite for control of odorants emissions from
2531 VOCs from simulated poultry manure storage headspace GC-MS
poultry manure J. ENVIRON. QUAL. 36, #1,184-193 (2007)
Cai, L.; Koziel, J. A.; Liang, Y.; Nguyen, A. T.; Xin, H.
Evaluating Peats for their capacities to remove
465 C2-C10 acid, odorous compounds from liquid swine manure 85µm polyacrylate GC-MS
aldehydes, phenols using headspace SPME 20 min @ 72°C
Ambient temperature, unless otherwise indicated. 25