SPME Applications Guide - Overbrook Scientific

(New references added to the 7th edition are in bold) SPME Fiber /
Analyte / Extraction
Matrix Literature Reference
Determination of triazines in soil leachates by SPME
Conditions Instrument
718 Triazines, coupled to GC-MS 85µm polyacrylate GC-MS
in soil leachates J. Chromatogr. A 2000, 874(2), 247-255 30min @ 20°C
Zambonin, C.., Palmisano, F. aggitation
530 Organophosphorus
Determination of organophosphorus pesticides in soil
by headspace SPME 85µm polyacrylate GC-FID
pesticides in Fresenius'J. Anal. Chem (1999), 363(7), 673-679 1 hr @ 80°C
soil Ng, W., Teo, M., Lakso, H. headspace over soil
76 Lindane
Analysis of Lindane in Water and Soil by Solid Phase
Microextraction 30µm & 100µm PDMS GC-ECD
in water and soil Request from: Dept. Soil Science, University of Manitoba, 58°C
Winnipeg MB, Canada R3T 2N2. 40 min (headspace)
Anderson, K., Sarna, L., Webster, B. 15-20 min (immersion)
A novel headspace SPME method for the exact determination
2170 Organochlorine of organochlorine pesticides in environmental soil samples GC-ECD
pesticides in Anal. Bioanal. Chem. 384, #7-8, 1584-1589 (2006)
soil Fu, Shan; Jiang, Ting; Wang, Xia; Xu, Xiaobai; Yuan, Jinpeng; Zhao, R.
880 Organochlorine
Determination of organochlorine pesticides and their
metabolities in soil samples using headspace SPME 100µm PDMS, GC-ECD
pesticides in J.Chromatogr. A (2001) 918(1), 177-188 65µm DVB/PDMS
soil Doong, R., Liao, P. 60min@70°C
heahspace
stirred
881 Fipronil in
Determination of fipronil by SPME and GC-MS
J chromatogr. A 919(2001) 215-221 85µm polyacrylate GC-MS
water, soil, urine Vilchez, J., Prieto, A., Araujo, L., Navalon, A.
Determination of metolachlor volatile flux from
30min. @ 60°C
stirred
9.5 pH
857 Metochlor soil using SPME
from soil Prepr. Ext. Abstr. ACS (2001) 41(1) 307-311
McConnell, L.; Kim, H; Nochetto, C; Gish, T; Prueger, J
833 Halobenzenes
Gas chromatography/ion-trap tandem mass spectrometry
for the analysis of halobenzenes in soils by SPME 100µm PDMS GC-MS
in soil and water Rapid Commun Mass Spectrometry (2000) 14(23) 2271-2281
Sarrion, M. N.; Santos, F. J.; Galceran, M. T.
45min
92 Chlorobenzenes
Analysis of Chlorobenzenes in Soils by Headspace SPME
and GC-Ion Trap MS 100µm PDMS GC-Ion Trap
in soil and water J. Chromatogr. A 771: 181-189 (1997)
Santos, F., Sarrion, M., Galceran, M.
headspace MS
921 Chlorobenzenes
Strategies for the analysis of chlorobenzenes in soils using
SPME coupled with GC-ion trap mass spectrometry GC-Ion Trap
in soil J. Chromatogr. A (1998), 819(1-2), 197-209
Sarrión, M., Santos, F., Galceran, M.
MS
238 Chlorobenzenes,
Analysis of Chloro- and Nitroanilines and Benzenes in Soil
by Headspace Solid-Phase Microextraction 85µm polyacrylate GC-ECD
nitrobenzenes, J. Chromatogr. A 746: 71-81 (1996) headspace
anilines in soil, water Fromberg, A., Nilsson, T., Larsen, R., Montanarella, L.,
Facchetti, S., Madsen, J.
50°C, 30 min
97 Semivolatiles
Coupled Subcritical Water Extraction with SPME for
Determining Semivolatile Organics in Environmental Solids 100µm PDMS GC-MS
in solids Anal. Chem. 68: 3892-3898 (1996) 15 min
Hageman, K., Mazeas, L., Grabanski, C., Miller, D., Hawthorne, S. immersion
793 Phenols
Fast determination of phenols in contaminated soils
J. Chromatogr., A (2001) 911(1), 135-141 85µm polyacrylate GC-FID
Ambient temperature, unless otherwise indicated. 197