SPME Applications Guide - Overbrook Scientific

(New references added to the 7th edition are in bold) SPME Fiber /
Analyte / Extraction
Matrix Literature Reference
Determination of Lead in Blood and Urine by SPME-GC
Conditions Instrument
492 Lead in Anal. Chem. 1999, 71(15), 2998-3002
whole blood & Urine Yu, X., Yuan, H., Gorecki, T., Pawliszyn, J.
Speciation of Alkyllead and Inorganic lead by derivatization
headspace
sodium tetraethyl
borate derivative
747 Lead in with deuterium-labeled sodium tetraethylborate and 100µm PDMS GC-MS
whole blood & Urine SPME GC-MS 10 min, headspace
Anal. Chem. 2000, 72,1788-1792 sodium tetraethyl
Yu, X, Pawliszyn, J. borate derivative
2519 Methylmercury
Production of artifact methylmercury during the analysis of
certified reference sediments: Use of ionic exchange in the either ethylated GC-MIP-AED
in sediment sample treatment step to minimise the problem
Anal. Chim. Acta 582, #1, 109-115 (Jan 16 2007)
de Diego, Alberto; Delgado, Alejandra; Madariaga, Juan Manuel;
Prieto, Ailette; Zuloaga, Olatz
derivatives GC-MS
Optimisation of the headspace-SPME for organomercury and
2914 Methylmercury organotin compound determination in sediment and biota 30µm PDMS GC-MS
in sediment J Separation Science 31, #4, 768-774 (MAR 2008) headspace
Delgado, A.; Usobiaga, A.; Prieto, A.; Zuloaga, O.; de Diego, A.; NaBEt4 derivative
Madariaga, Juan 3-24 min @ 20-90 °C
416 Methylmercury
Determination of Methylmercury in Biological Samples and
Sediments by Capillary GC Coupled with Atomic Adsorption 5cm fused silica fiber GC-AA
in biological fluids after hydride derivatization and SPME 90 min
or sediment J. Anal. At. Spectrom. (1998), 13(10), 1141-1144 headspace
He, B., Jiang, G., Ni, Z. KBH4 derivative
493 Alkalated Hg, Pb, Sn
Simultaneous determination of Hg(III) and alkylated Hg, Pb,
and Sn species in human body fluids using SPME-GC-MS-MS 100µm PDMS GC-MS-MS
in urine Fresenius' J.. Anal. Chem. (1999), 363(5-6), 466-468 10 min
Dunemann, L., Hajimiragha, H., Begerow, J.
Coupling of SPME and GC-AED for the determination of
NaBEt4 derivatives
pH 5.3
661 Organometallic organometallic compounds
Mikrochim Acta, (2000) 135 (No.1&2) 91-95
Mothes, S, Wennrich, R.
GC-AED
329 Methanol
Simple Extraction of Methanol in Human Whole Blood by
Headspace SPME Carboxen/PDMS GC-FID
in blood Jpn. J. Forensic Toxicol. 16 (1): 64-68 (1998) 60°C, 10 min
Lee, X., Kumazawa, T., Jurosawa, T., headspace
Akiya, K., Akiya, Y., Fruta, S., Sato, K. stirring
330 Aromatic amines in
Solid Phase Microextraction of Monocyclic Aromatic Amines
from Biological Fluid 65µm PDMS/DVB GC-FID
urine, blood, milk Anal. Chem. 70 (9): 1986-1992 (1998) 45°C, 15 min
DeBruin, L., Josephy, P., Pawliszyn, J.
Quantitative determination of trimethylamine in urine by
headspace, salt added
KOH added, pH >13
65µm Carboxen/PDMS,
494 Trimethylamineuria SPME-GC-MS
100µm PDMS GC-MS
in urine J. Chromatogr. B: Biomed Sci. Appl., 1999, 723(1+2), 281-285 15 min @ 59°C
Mills, G., Walke, V., Mughal, H.
Determination of acrolein by headspace SPME-GC-MS
headspace
stirred
950 Acrolein J. Chromatogr., B: Biomed (2001), 758(1), 123-128
in bioligical fluids Takamoto, S.; Sakura, N.; Yashiki, M.; Kojima, T.
331 PAHs
Fast Screening Method for the Profile Analysis of Polycyclic
Aromatic Hydrocarbon Metabolites in Urine, Using 85µm polyacrylate GC-MS
in urine Derivatization-SPME 35°C, 45 min
J. Chromatogr. G: Biomed. Sci. Appl. 705 (1): 132-138 (1998) stirring
Gmeiner, G., Krassnig, C., Schmid, E., Tausch, H. BSTFA derivative
Ambient temperature, unless otherwise indicated. 123