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Modern Engineering Thermodynamics

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Problems 53<br />

Problems (* indicates problems in SI units)<br />

1. Define the following terms: (a) thermostatics, (b) open system,<br />

(c) extensive property, (d) equilibrium, and (e) zeroth law.<br />

2. Define the following terms: (a) thermodynamics, (b) closed<br />

system, (c) intensive property, (d) macroscopic analysis, and (e)<br />

isolated system.<br />

3.* A mixture of 1.0 kg of oxygen and 2.0 kg of hydrogen at<br />

atmospheric temperature and pressure are placed in a closed<br />

container. Explain (a) whether or not this mixture is a pure<br />

substance, and (b) whether or not it is a homogenous substance.<br />

4. Dry ice (solid CO 2 ) and CO 2 vapor are in a sealed rigid<br />

container. Does the CO 2 in this system constitute (a) a pure<br />

substance, (b) a homogenous substance, (c) a simple substance?<br />

5. Which of the following are extensive properties?<br />

(a) Temperature, (b) volume, (c) density, (d) work, (e) mass.<br />

6. Are the following extensive or intensive properties? (a) Total<br />

energy, (b) temperature, (c) pressure, (d) mass.<br />

7. Identify whether the following properties are intensive or<br />

extensive: (a) Specific energy, (b) total energy, (c) temperature,<br />

(d) molar mass.<br />

8. Explain how color could be a thermodynamic property and<br />

indicate whether it would be an intensive or extensive property.<br />

9. Let us say we have 2.00 ft 3 of a liquid/vapor mixture of motor<br />

oil at 70.0°F and 14.7 psia that weighs 97.28. lbf where<br />

g = 32.0 ft/s 2 . List the values of three intensive and two<br />

extensive properties of the oil.<br />

10.* There once was a man who had 1.00 m 3 of air at 20.0°EC and<br />

0.100 MPa with a specific volume of 0.840 m 3 /kg. List the<br />

values of three intensive and two extensive properties of his air<br />

(Figure 2.13).<br />

FIGURE 2.13<br />

Problem 10.<br />

Intensive properties<br />

1.<br />

Extensive properties<br />

11. A woman once collected 2000. lbm of seawater at 50.0°F and<br />

14.7 psia that occupied a volume of 56.0 ft 3 . List the values of<br />

three intensive and two extensive properties of her seawater.<br />

12. How many independent property values are required to fix the<br />

state of a pure substance subject to only one work mode?<br />

13. Determine whether the following statements are true or false:<br />

a. The mass of a closed system is constant and its boundaries<br />

are not movable.<br />

b. An open system is defined as a system that can exchange<br />

only heat and work with its surroundings.<br />

2.<br />

3.<br />

1.<br />

2.<br />

c. An isolated system is completely uninfluenced by the<br />

surroundings.<br />

d. A thermodynamic property is a quantity that depends on the<br />

state of the system and is independent of the process path by<br />

which the system arrived at the given state.<br />

e. When a system in a given state goes through a number of<br />

processes and its final temperature is the same as the initial<br />

temperature, the system has undergone a thermodynamic<br />

cycle.<br />

14. Identify the proper type of system (isolated, closed, or open) to<br />

be used in the analysis of each of the following and explain the<br />

reasons for your choice: (a) the Universe, (b) a kitchen<br />

refrigerator, (c) an electrical generator, (d) a hydraulic pump,<br />

(e) a living human being.<br />

15. Determine the proper type of system (isolated, closed, or open)<br />

to be used in analyzing each of the following items and explain<br />

the reasons for your choice: (a) a bicycle, (b) a personal<br />

computer, (c) a stereo system, and (d) a lawn water sprinkler.<br />

16. Establish the correct type of system (isolated, closed, or open)<br />

to be used in analyzing each of the following items and<br />

explain the reasons for your choice: (a) the solar system,<br />

(b) a carbonated drink dispensing machine, (c) an insulated<br />

box of fruit buried deep in the ground, and (d) a lightbulb.<br />

17. Which of the basic types of systems (isolated, closed, or open)<br />

should be used to analyze each of the following items<br />

and explain the reasons for your choice: (a) a flying insect,<br />

(b) a black hole, (c) Niagara Falls, and (d) the great soaring<br />

whipple bird of Mars.<br />

18.* As chief engineer for Thermodynamic Analysts Inc., your job is<br />

to determine the proper type of system (isolated, closed, or<br />

open) to be used in analyzing each of the following items<br />

submitted to your company and to explain the reasons for your<br />

choice: (a) a water pistol, (b) a flashlight battery, (c) a rubber<br />

boot, and (d) 2 kg chocolate fudge candy in a thermally<br />

insulated box buried deep in the Andes mountains.<br />

19. An alien spacecraft has abducted you from a NASA space station<br />

and demands to know the type of system (isolated, closed, or<br />

open) NASA uses to analyze each of the following items, plus an<br />

explanation of the reasons for the choice: (a) the space station<br />

itself, (b) your pocket computer, (c) a can of tuna fish, and<br />

(d) an old Madonna movie.<br />

20. An automobile internal combustion engine by itself is an open<br />

system because it draws in air and exhausts combustion<br />

products. How could one construct system boundaries around<br />

an operating internal combustion engine to cause it to become a<br />

closed system?<br />

21.* Determine the specific volume of liquid water at 20.0°C that has<br />

a density of 998.0 kg/m 3 .<br />

22. Determine the mass of ammonia having a specific volume of<br />

35.07 ft 3 /lbm in a container measuring exactly 3 ft by exactly<br />

2 ft by exactly 1 ft.<br />

23.* Determine the volume of liquid mercury with a density of<br />

3.87 kg/m 3 having a mass of 2.00 kg.<br />

24. A system consists of a mixture of 2.00 ft 3 of a liquid having a<br />

density of 50.0 lbm/ft 3 and 4.00 lbm of a second liquid having<br />

a specific volume of 0.0400 ft 3 /lbm. The specific volume of<br />

the mixture in the system in ft 3 /lbm is (a) 0.208, (b) 2.08,<br />

(c) 0.022, (d) 2.048, or (e) none of these.

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