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Modern Engineering Thermodynamics

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794 Index<br />

Case studies (Cont.)<br />

hydrodynamic flow systems, 305<br />

Sandia hypervelocity gun, 25<br />

Stanley steamer, 519–520<br />

Stirling engine, 523–524<br />

vortex tube, 302<br />

Cavitation process, 315<br />

C (coulomb), 17, 697<br />

Cells, 636–641<br />

ion gradients across membranes, 695<br />

thermodynamics of biological, 695–699<br />

Celsius, Anders, 40<br />

Celsius temperature scale, 8<br />

Center of gravity, 48<br />

Centrifugal governor, 454<br />

CFC’s, 552–554<br />

Change of state, entropy produced by, 250<br />

Characteristic temperature<br />

diatomic materials, 753t<br />

rotational, 753t<br />

vibrational, 753t<br />

Charge (q), 38, 100, 117, 696<br />

Charles, Jacques, 41, 56<br />

Charles’ law, 397<br />

Charts, generalized, 384–396<br />

Chemical equilibrium, 634–635<br />

and dissociation, 626–634<br />

Chemical potential, 696, 697<br />

Chemical thermodynamics, 591–645<br />

Chemical units, 14–15, 25<br />

Chemical work, 122–123<br />

Choked flow, 652, 665–669<br />

Circulatory system, 711<br />

Clapeyron, Benoit Pierre Emile, 370<br />

Clapeyron-Clausius equation, 371<br />

Clapeyron equation, 370–372<br />

Clausius, Rudolph, 210, 211, 218, 456, 728<br />

Clausius equation, 83<br />

Clausius inequality, 221<br />

Clerk, Dugald, 503<br />

Closed loop, 470, 486, 488, 490<br />

Closed system, 35, 56, 148<br />

applications<br />

availability, 327–331<br />

first law, 147<br />

second law, 249<br />

availability, 327–331<br />

balance equation, 135, 138<br />

defined, 105, 323<br />

entropy for, 219, 240<br />

mass in, 133<br />

time derivative, 670<br />

real irreversible, heat engine, 214<br />

stationary, 362<br />

unsteady state processes, 157–159<br />

Coefficient of performance (COP), 217–218,<br />

537<br />

Collision, 732–734<br />

cross section, 732, 732f, 759<br />

frequency, 733–734, 742<br />

probability, 743<br />

Combinations, two die, 742t<br />

Combustion, 486, 507, 609t, 610t<br />

amount of air required, 595<br />

of a typical hydrocarbon, 596<br />

Compensation law, 719<br />

Compensation temperature, 719<br />

Compounding (series staging), 466<br />

Compound probability, 744<br />

Compressibility of gases, 386<br />

Compressibility factor (Z), 384–396, 433<br />

Compressible flow<br />

defined, 652<br />

fluid, 652<br />

Compression loading, leg bones, 711<br />

Compression<br />

of a pure gas, 127<br />

work, 109<br />

Compressor, 316t, 542, 548<br />

Condensation, 69, 664<br />

Condensation shock, 664<br />

Condenser, 185, 453, 488, 581<br />

Conditional probability, 744<br />

Conduction heat transfer, 128, 322<br />

Conductor, 116, 769<br />

Conservation, 46–50, 100–101<br />

of charge, 46<br />

of energy, 46, 48, 171–173<br />

of mass, 46, 50–51, 133, 171–173<br />

in wet airstreams, 428<br />

for an incompressible fluid, 178<br />

of momentum, 48<br />

Conservative fields, 320–321<br />

Conservative forces, 321<br />

Constant volume, 91, 220, 335, 377, 408,<br />

613<br />

Constitutive equations, 236<br />

Container system boundary, 148<br />

Continuous rate processes, 124<br />

Continuum hypothesis, 43, 126<br />

Convection heat transfer, 198t<br />

coefficient of, 129<br />

Converging-diverging flows, 660–664<br />

Converging-diverging nozzle<br />

diameter ratio variation, 668, 668f<br />

normal shock waves from, 675<br />

pressure distribution, 675f<br />

Copper, beta and kappa for, 61<br />

Cotton gin, 449<br />

Coulomb (C), 16<br />

Coulomb’s law, 354<br />

Coupled phenomena, 763–784<br />

Critical condition (throat), 662<br />

Critical height of trees, 669<br />

Critical mass fraction, 294, 295f<br />

Critical opalescence, 70<br />

Critical point, 384<br />

Critical region, 70f<br />

Critical state<br />

properties of, 70t<br />

pseudo specific volume, 386<br />

specific volume, 68<br />

Curie constant (C), 144<br />

Curie substance, 144<br />

Curr, John, 528<br />

Curtis, Charles Gordon, 476<br />

c (velocity of light), 738, 748<br />

Cycle. See also Air standard cycle (ASC);<br />

Atkinson cycle; ATP-ADP cycle; Binary<br />

cycle system; Brayton cycle; Carnot<br />

cycle; Diesel cycle; Ericsson cycle; Gas<br />

power cycles; Heat engine cycle;<br />

Lenoir cycle; Newcomen cycle; Otto<br />

cycle; Power cycles; Rankine cycle;<br />

Refrigeration cycle; Stirling cycle<br />

mechanical, 39<br />

thermodynamic, 39, 212, 457, 502<br />

D<br />

Dalton, John, 413, 593<br />

Dalton compressibility factor, partial pressure<br />

(p Di ), 431<br />

Dalton’s law, 414<br />

mixtures of real gases, 435<br />

Dalton specific volume (v Di ), 431<br />

Darcy-Weisbach friction factor, 314<br />

Davy, Humphry, 764t<br />

Death, 716–721<br />

Death rate constant, 718–719<br />

de Broglie, Louis Victor Pierre Raymond, 748<br />

Debye, Peter, 728<br />

Deficit air, 595, 597<br />

Degeneracy (energy level), 749–750<br />

Degree of superheat, 467<br />

Degrees of freedom<br />

gases, 756<br />

linear polyatomic molecules, 756<br />

nonlinear polyatomic molecules, 758<br />

Degree symbol, use of, 17<br />

Dehumidification, 425f, 427<br />

DeLaval, Carl Gustaf Patrik, 476<br />

DeLaval impulse turbine, 476, 477f<br />

Density, 83, 174, 651, 655<br />

Dew point, 418<br />

water vapor and dry air mixtures, 418f<br />

Diamagnetic materials, 120<br />

Dielectric materials, 116<br />

Diesel, Rudolf Christian Karl, 512<br />

Diesel cycle, 512–516<br />

air standard, 513f<br />

Dieterici equation, 83<br />

Diethyl ether, 547<br />

Differential entropy balance, 227–229<br />

Diffuser efficiency, 683–684<br />

Diffuser pressure recovery coefficient (C p ), 684<br />

Diffusers<br />

subsonic, 662, 684<br />

supersonic, 661, 685<br />

thermodynamic process path, 684f<br />

Diffusion, mixing by, and entropy, 271<br />

Dimensional analysis, 6<br />

Dimensions, 6, 11<br />

Dipstick heater, 276<br />

Direct calorimetry, 703<br />

Dissipative flow<br />

hydraulic, 300<br />

viscous, 179<br />

Dissociation<br />

and chemical equilibrium, 626–634<br />

versus equilibrium temperature, 632<br />

versus reaction pressure, 632t<br />

Double-acting cylinder, 520<br />

Duality principle of matter, 749<br />

Duty (engine), 452, 526<br />

Dyne, defined, 11

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