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Modern Engineering Thermodynamics

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viii<br />

Contents<br />

3.9 Thermodynamic Equations of State ............................................76<br />

3.10 Thermodynamic Tables . . . ..................................................84<br />

3.11 How Do You Determine the “Thermodynamic State”?..............................86<br />

3.12 Thermodynamic Charts . . . ..................................................87<br />

3.13 Thermodynamic Property Software ............................................89<br />

Summary . ...................................................................90<br />

CHAPTER 4 The First Law of <strong>Thermodynamics</strong> and Energy Transport Mechanisms . . . . . . . . . . . 99<br />

4.1 Introducción (Introduction). .................................................100<br />

4.2 Emmy Noether and the Conservation Laws of Physics . ...........................100<br />

4.3 The First Law of <strong>Thermodynamics</strong> ...........................................101<br />

4.4 Energy Transport Mechanisms . . . ...........................................104<br />

4.5 Point and Path Functions . . .................................................107<br />

4.6 Mechanical Work Modes of Energy Transport . . . ................................108<br />

4.7 Nonmechanical Work Modes of Energy Transport ................................116<br />

4.8 Power Modes of Energy Transport. ...........................................124<br />

4.9 Work Efficiency . . . .......................................................124<br />

4.10 The Local Equilibrium Postulate . . ...........................................126<br />

4.11 The State Postulate .......................................................127<br />

4.12 Heat Modes of Energy Transport . . ...........................................127<br />

4.13 Heat Transfer Modes ......................................................128<br />

4.14 A Thermodynamic Problem Solving Technique . . ................................130<br />

4.15 How to Write a <strong>Thermodynamics</strong> Problem. .....................................134<br />

Summary . ..................................................................138<br />

CHAPTER 5 First Law Closed System Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147<br />

5.1 Introduction . . ............................................................147<br />

5.2 Sealed, Rigid Containers . . . .................................................148<br />

5.3 Electrical Devices. . . .......................................................150<br />

5.4 Power Plants . ............................................................151<br />

5.5 Incompressible Liquids .....................................................152<br />

5.6 Ideal Gases . . ............................................................154<br />

5.7 Piston-Cylinder Devices .....................................................155<br />

5.8 Closed System Unsteady State Processes . ......................................157<br />

5.9 The Explosive Energy of Pressure Vessels ......................................159<br />

Summary . ..................................................................160<br />

CHAPTER 6 First Law Open System Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167<br />

6.1 Introduction . ............................................................167<br />

6.2 Mass Flow Energy Transport ................................................168<br />

6.3 Conservation of Energy and Conservation of Mass Equations for Open Systems . . . .....171<br />

6.4 Flow Stream Specific Kinetic and Potential Energies . . . ...........................173<br />

6.5 Nozzles and Diffusers. .....................................................174<br />

6.6 Throttling Devices . .......................................................179<br />

6.7 Throttling Calorimeter .....................................................182<br />

6.8 Heat Exchangers . . .......................................................184<br />

6.9 Shaft Work Machines ......................................................187<br />

6.10 Open System Unsteady State Processes . ......................................190<br />

Summary . ..................................................................197<br />

CHAPTER 7<br />

Second Law of <strong>Thermodynamics</strong> and Entropy Transport<br />

andProductionMechanisms .........................................205<br />

7.1 Introduction . ............................................................205<br />

7.2 What Is Entropy? . . .......................................................206<br />

7.3 The Second Law of <strong>Thermodynamics</strong> . . . ......................................207<br />

7.4 Carnot’s Heat Engine and the Second Law of <strong>Thermodynamics</strong> .....................208<br />

7.5 The Absolute Temperature Scale . . ...........................................212

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