TABLE OF CONTENTS - BGB Analytik AG

GC and GC/MS
Solvent Retention Data
Solvent Retention Data
Column: DB-624
125-1334
30 m x 0.53 mm, 3.00 µm
Carrier: Helium, constant pressure at 30 cm/sec (40°C)
Oven: 40°C for 5 min
40-260°C at 10°min
260°C for 3 min
Injection: Split 1:10, 250°C
Detector: FID, 300°C
Column: DB-1
125-1034
30 m x 0.53 mm, 3.00 µm
Carrier: Helium, constant pressure at 30 cm/sec (40°C)
Oven: 40°C for 5 min
40-260°C at 10°/min
Injection: Split 1:10, 250°C
Detector: FID, 300°C
Column: DB-WAX
125-7032
30 m x 0.53 mm, 1.00 µm
Carrier: Helium, constant pressure at 34 cm/sec (40°C)
Oven: 40°C for 5 min
40-230°C at 10°/min
230°C for 7 min
Injection: Split 1:10, 250°C
Detector: FID, 300°C
These solvent tables have many uses, not least of which is
to determine impurities in bulk solvents. All of the columns were
selected for their capacity, selectivity and reproducibility.
Warning: Other manufacturers' look-a-like columns do not have
the same selectivity as Agilent J&W GC Columns. We do not
recommend using this data on other manufacturers' columns.
Analyte DB-624 DB-1 DB-WAX
1,1,1,2-tetrachloroethane 14.38 13.43 13.80
1,1,1-trichloroethane 8.05 7.56 4.85
1,1,2,2-tetrachloroethane 16.38 14.67 17.73
1,1,2-trichloroethane 12.60 11.00 13.80
1,1,2-trichlorotrifluoroethane (Freon 113) 4.00 4.09 2.13
1,10-decanediol 27.43 25.84 34.11
1,1-dichloroethane 6.11 5.02 9.10
1,1-dichloroethylene (vinylidine chloride) 4.00 3.75 2.65
1,1-dichloropropane 8.72 8.55 9.71
1,1-dichloropropene 8.34 7.85 4.56
1,2,3-trichlorobenzene 22.23 21.28 21.25
1,2,3-trichloropropane 16.46 14.84 17.06
1,2,3-trimethylbenzene (hemimellitene) 18.18 17.61 15.29
1,2,4,5-tetrachlorobenzene 24.02 23.35 22.08
1,2,4-trichlorobenzene 21.41 20.63 20.03
1,2,4-trimethylbenzene (pseudocumene) 17.47 16.99 14.27
1,2-dibromo-3-chloropropane (DBCP) 20.02 18.50 20.57
1,2-dibromoethane (EDB) 13.43 12.10 13.80
1,2-dichlorobenzene 18.69 17.81 17.80
1,2-dichloroethane (ethylene dichloride) 9.62 7.17 7.20
1,2-dichloropropane 10.17 8.93 4.95
1,3,5-trichlorobenzene 20.35 19.85 18.19
1,3,5-trimethylbenzene (mesitylene) 16.82 16.41 13.55
1,3-butanediol 16.10 13.30 20.96
1,3-dichlorobenzene 17.96 17.20 16.60
1,3-dichloropropane 12.86 11.35 12.38
1,3-diisopropylbenzene 20.35 20.02 15.47
354 www.agilent.com/chem/supplies
Analyte DB-624 DB-1 DB-WAX
1,3-dioxolane 7.30 4.09 7.09
1,3-propanediol 13.13 9.95 18.97
1,4-butanediol 17.70 15.03 23.14
1,4-dichlorobenzene 18.79 17.31 17.06
1,4-diisopropylbenzene 20.73 20.42 16.20
1,4-dioxane 10.38 9.18 9.65
1,5-pentanediol 19.52 17.17 24.43
1,6-hexanediol 21.30 19.17 25.75
1,7-heptanediol 22.97 21.03 27.26
1,8-octanediol 24.54 22.73 29.06
1,9-nonanediol 26.02 24.33 31.29
1-butanol 9.73 7.90 11.48
1-chloro-4-nitrobenzene (diisopropyl ketone) 3.06 21.34 23.97
1-chlorobutane 8.25 7.56 3.99
1-chlorohexane 14.21 13.69 9.10
1-decanol 22.65 21.85 21.12
1-heptanol 17.22 16.13 16.91
1-hexanol 15.06 13.81 15.31
1-methyl-2-pyrrolidone 19.66 17.21 20.71
1-nonanol 20.97 20.11 19.80
1-octanol 19.17 18.21 18.40
1-pentanol 12.63 11.11 13.54
1-penten-3-ol 10.20 8.54 11.77
1-penten-3-one (ethyl vinyl ketone) 10.03 8.40 8.56
1-propanol 6.34 4.44 9.11
2,2-dichloropropane 7.16 6.34 3.99
2,3-butanediol 14.14 11.40 18.70
2,3-butanedione (diacetal) 6.99 5.09 7.44
2,3-pentanedione 10.34 8.66 9.49
2,4-dimethyl-3-pentanone 12.94 11.90 7.94
2,6-dimethyl-4-heptanone 17.06 16.26 12.03
2-butanone (MEK) 7.19 5.41 5.35
2-buten-1-ol (crotyl alcohol) 9.87 7.99 12.95
2-butoxyethanol (butyl cellosolve) 15.89 14.72 16.31
2-chlorotoluene 16.71 16.07 14.71
2-ethoxyethanol (cellosolve) 10.98 9.39 13.11
2-ethoxyethyl acetate 15.57 14.40 14.31
2-ethyl-1-hexanol 18.40 17.42 17.41
2-heptanol 15.63 14.61 14.71
2-heptanone 15.46 14.26 12.27
2-hexanol 13.31 12.06 12.95
2-hexanone 13.01 11.60 10.04
2-methoxyethanol (methyl cellosolve) 8.67 6.74 12.25
2-methyl-1-butanol (active amyl alcohol) 11.87 10.30 12.73
2-methyl-2-butanol (tert-amyl alcohol) 8.73 7.14 8.43
2-methyl-3-buten-2-ol 7.91 6.17 9.11
2-methyl-3-pentanone 11.85 10.59 7.94
2-methylbutyl acetate 14.82 14.81 12.05
2-nitrotoluene 21.60 20.02 22.62
2-octanone 17.63 16.46 14.20
2-pentanol 10.60 9.10 10.94
2-pentanone 10.11 8.46 7.44
2-penten-1-ol 12.63 11.11 14.65
2-phenoxyethanol 22.65 20.92 26.14
2-propen-1-ol (allyl alcohol) 6.21 4.09 10.78
2-propyn-1-ol (propargyl alcohol) 7.55 4.57 15.16
3-buten-1-ol 9.02 6.95 12.02
3-chloropropene (allyl chloride) 4.57 3.96 3.46
3-chlorotoluene 16.82 16.07 14.90
3-heptanol 15.53 14.54 14.29
3-heptanone 15.29 14.19 11.66
3-hexanol 13.16 11.97 12.49
3-hexanone 12.80 11.52 9.34
3-methyl-1-butanol (iso-amyl alcohol) 11.78 10.17 12.73
3-methyl-2-butanone 9.21 7.60 6.15
3-methyl-2-buten-1-ol 12.85 11.33 14.82
3-nitrotoluene 22.40 20.72 21.92
3-octanone 17.45 16.46 13.66
3-pentanol 10.60 9.10 10.66
3-pentanone 10.34 8.80 7.44
3-penten-2-one (methyl vinyl ketone) 6.93 5.09 6.61
4-chlorostyrene (diisobutyl ketone) 19.35 18.56 18.19
4-chlorotoluene 16.82 16.07 14.90
4-heptanone 14.95 13.88 11.06
4-hexen-3-one 14.24 12.76 12.55
4-hydroxy-4-methyl-2-pentanone 14.98 12.89 15.70
4-methyl-2-pentanol 12.28 10.93 11.89
4-methyl-2-pentanone 11.64 10.22 8.19
4-methyl-3-penten-3-one 13.20 11.90 11.26
4-methylstyrene 17.68 16.99 15.61
4-nitrotoluene 22.79 21.05 23.14
4-phenyl-2-butanone (benzyl acetone) 22.91 21.36 22.76
4-tert-butyltoluene 19.35 18.97 15.13
5-methyl-2-hexanone 14.73 13.46 11.40