TABLE OF CONTENTS - BGB Analytik AG

Organotin Compounds II
Column: HP-5
19091J-002
25 m x 0.20 mm, 0.11 µm
Carrier: Helium, 0.75 mL/min constant flow
Oven: 60-360°C at 5°C/min
Injection: Splitless, 300°C
Detector: AED, 300°C
Hg selective at 254 mm
Sample: 1 µL
Suggested Supplies
Septum: 11 mm Advanced Green septa, 5183-4759
Liner: Direct connect, single taper, deactivated, 4 mm ID, G1544-80730
Syringe: 10 µl tapered, FN 23-26s/42/HP, 5181-1267
PBDEs
Column: DB-XLB
122-1231
30 m x 0.25 mm, 0.10 µm
Carrier: Helium at 38 cm/sec at 100°C (1.2 mL/min), constant flow
mode
Oven: 100°C for 1 min; 100°C to 340°C at 20°C/min, 340°C for
12 min
Injection: Cool on-column, oven-track mode
Detector: Agilent 5973 MSD, 325°C transfer line, EI SIM
(ions monitored: 231.8, 248.0, 327.9, 398.6, 400.5,
405.8, 845.7, 563.6, 643.5, 721.4, 799.3)
Sample: 0.5 µL
For a complete Application Note, visit www.agilent.com/chem,
select "Online Literature" from the Literature Library and type
5989-0094EN into the "Keyword" field.
Abundance
Abundance
Abundance
Abundance
1000
500
1000
500
0
1000
500
0
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Environmental Applications, Semivolatiles
Standard Solution
Solvent
Vent
0 10 20 30
Time (min)
40 50
Harbor Sediment
Solvent
Vent
Me 2 SnPh
Bu 4 Sn
14 pg
Bu 2 SnPh
Bu 2 SnPh 2
17 pg
Bu 2 SnPh 2
BuSnPh 2
35 pg
BuSnPh 2
Bu 2 SnPh 2
78 pg
0 10 20 30
Time (min)
40
Ion 485.70 (485.40 to 486.40): PBDE-105.D
Tetra-BDE
100 ppb each
0
10:00 11:00 12:00 13:00
1000
Ion 563.60 (563.30 to 564.30): PBDE-105.D
Penta-BDE
500
0
150 ppb each
10:00 11:00 12:00 13:00
Ion 643.50 (643.50 to 644.20): PBDE-105.D
10:00 11:00 12:00 13:00
Ion 721.70 (721.40 to 722.40): PBDE-105.D
Ph 4 Sn
35 pg
10:00 11:00 12:00 13:00
Oct 2 SnPh
Oct 2 SnPh
GCES013
Hexa-BDE
200 ppb each
Hepta-BDE
250 ppb each
GCES014
GC and GC/MS
381