TABLE OF CONTENTS - BGB Analytik AG

Free Organic Acids/C4-C5 Isomers
Column: HP-INNOWax
19091N-133
30 m x 0.25 mm, 0.25 µm
Carrier: Helium 42 cm/sec, 24 psi (120°C)
1.8 mL/min constant flow
Oven: 110°C for 1 min
110-133 at 2°C/min
133-160°C at 3°C/min
Injection: Split, 250°C
Split ratio 40:1
Detector: FID 300°C
Sample: 1 µL
Volatile Amines
Column: DB-1
125-1035
30 m x 0.53 mm, 5.00 µm
Oven: 30°C isothermal
Sampler: Headspace
Injection: Split ratio 1:10
Detector: FID
Nitrogen makeup gas at 30 mL/min
Trace Active Amines, 10 ng on-column
Column: HP-5ms
19091S-213
30 m x 0.32 mm, 1.00 µm
Carrier: Helium, constant pressure 9.79 psi
Oven: 75°C for 0.5 min
75-250°C at 10°C/min
250-320°C at 25°C/min
320°C for 5 min
Injection: On-column
Oven tracking mode
Detector: FID 300°C
Sample: 0.5 µL of each standard in methanol
100
80
60
40
20
pA
100
80
60
40
20
www.agilent.com/chem/supplies
1
2
3
4
Industrial Chemical Applications
5
0 5 10
Time (min)
15
20
HP-5ms
1
2
3
5 min
pA Butylbenzene
Ethanolamine
6
7
8 9
GCIC007
1. Isobutyric acid
2. Butyric acid
3. Valerolactone
4. 2-Methyl butyric acid
5. Valeric acid
1. Methylamine
6. 4-Pentenoic acid
7. trans-2-Methyl-2-butenoic acid
8. trans-3-Pentenoic acid
9. trans-2-Pentenoic acid
2. Dimethylamine
3. Trimethylamine
GCIC006
0 2 4 6 8 10 12 14 16
FID 1A, (AMNCOL1000680603.D)
Another 5% Phenyl Amines Column
Ethanolamine
Butylbenzene
Nonylamine
Nonylamine
Triethanolamine
Triethanolamine
0 2 4 6 8
Time (min)
10 12 14 16
GCIC008
GC and GC/MS
419