TABLE OF CONTENTS - BGB Analytik AG

GC and GC/MS
Environmental Applications, Pesticides and Herbicides
Organochlorine Pesticides I
Column: DB-5
125-5037
30 m x 0.53 mm, 0.50 µm
Carrier: Helium at 30 cm/sec (4.0 mL/min)
Oven: 150-275°C at 4°/min
275°C for 30 min
Injection: Splitless, 250°C
Detector: ECD, 300°C
Nitrogen makeup gas at 30 mL/min
Sample: 0.7 µL of 100 pg/µL standard in isooctane
Suggested Supplies
Liner: Splitless, single taper, deactivated,
4 mm ID, 5181-3316
Septum: 11 mm Advanced Green septa,
5183-4759
Syringe: 10 µl tapered, FN 23-26s/42/HP,
5181-1267
Organochlorine Pesticides II
Column: DB-608
125-6837
30 m x 0.53 mm, 0.50 µm
Carrier: Helium at 30 cm/sec (4.0 mL/min)
Oven: 150-275°C at 4°/min
275°C for 30 min
Injection: Splitless, 250°C
Detector: ECD, 300°C
Nitrogen makeup gas at 30 mL/min
Sample: 0.7 µL of 100 pg/µL standard in isooctane
Suggested Supplies
Liner: Splitless, single taper, deactivated, 4 mm ID,
5181-3316
Seal: 11 mm Advanced Green septa, 5183-4759
Syringe: 10 µl tapered, FN 23-26s/42/HP, 5181-1267
1. 2,4,5,6-Tetrachloro-m-xylene (IS)
2. α-BHC
3. b-BHC
4. γ-BHC
5. δ-BHC
6. Heptachlor
7. Aldrin
8. Heptachlor epoxide
366 www.agilent.com/chem/supplies
1
2
3
4 5
6 7
10
8 9 11
12, 13
14
15
16 18
0 10 20
30 40
Time (min) GCEP009
1. 2,4,5,6-Tetrachloro-m-xylene (IS)
2. α-BHC
3. b-BHC
4. γ-BHC
5. δ-BHC
6. Heptachlor
7. Aldrin
8. Heptachlor epoxide
1
2
4
3
5
6
7
8 9
0 10 20
30 40
Time (min) GCEP010
17
10
11
9. γ-Chlordane
10. Endosulfan I
11. α-Chlordane
12. Dieldrin
13. p,p’-DDE
14. Endrin
15. Endosulfan II
16. p,p’-DDD
19
12
13
20
21
9. γ-Chlordane
10. Endosulfan I
11. α-Chlordane
12. Dieldrin
13. p,p’-DDE
14. Endrin
15. Endosulfan II
16. p,p’-DDD
14 15 19
18
16
17
17. Endrin aldehyde
18. Endosulfan sulfate
19. p,p’-DDT
20. Endrin ketone
21. Methoxychlor
22. Decachlorobiphenyl (IS)
21
20
22
17. Endrin aldehyde
18. Endosulfan sulfate
19. p,p’-DDT
20. Endrin ketone
21. Methoxychlor
22. Decachlorobiphenyl (IS)
22