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PL-6At the same time, other exciting possibilities will clearly emerge. In particular, the possibilityto develop spatially resolved NMR thermometry techniques for the studies of heat transport inchemical engineering, including hot spots formation and evolution in catalysis, will bediscussed. Multinuclear imaging of solids can be useful for the direct visualization of, e.g.,transport of granular solids in various geometries including fluidized beds. Imaging ofmaterials comprising a solid finely dispersed in a porous solid matrix will be useful, forinstance, for mapping NaCl distribution in building materials, LiCl and other salts in selectivewater sorbents, etc.Another direction pursued in our studies is the combination of multinuclear MRI ofliquids (solutes) with that of solids. This approach appears to be promising for the in situstudies of the preparation of supported catalysts and composite water sorbents. During theimpregnation stage, transport of the solute (catalyst precursor, salt) can be visualized as itpermeates the porous support immersed in the impregnation solution. Imaging of the solidphase is helpful to evaluate the final distribution of a catalyst or salt after the pellet is dried.Comparison of the imaging results of the liquid and solid phases allows one to studyinteraction of the active component with the porous support and to assess its redistributionwithin the support during the drying stage.Acknowledgments. This work was partially supported by RFBR (# 05-03-32472),RFBR-NWO (03-03-89014-NWO, 047.015.006) and CRDF (RU-C1-2581-NO-04). Theauthor thanks Russian Science Support Foundation for financial support.References:1 Igor V. Koptyug and Anna A. Lysova, in Stapf, S., Han, S.-I (Eds.), NMR Imaging inChemical Engineering. Wiley-VCH, 2005, pp. 570-589.2 I.V. Koptyug, A.A. Lysova, A.V. Kulikov, V.A. Kirillov, V.N. Parmon, R.Z. Sagdeev,Appl. Catal. A: General, 2004, v. 267, pp. 143-148.3 I.V. Koptyug, A.A. Lysova, A.V. Matveev, V.N. Parmon, R.Z. Sagdeev, Topics inCatalysis, 2005, v. 32, pp. 83-91.4 A.A. Lysova, I.V. Koptyug, R.Z. Sagdeev, V.N. Parmon, J.A. Bergwerff,B.M. Weckhuysen, J. Amer. Chem. Soc., 2005, V. 127, pp. 11916-11917.5 I.V. Koptyug, D.R. Sagdeev, E. Gerkema, H. Van As, R.Z. Sagdeev, J. Magn. Reson.,2005, V. 175, pp. 21-29.20
KEYNOTE SECTIONALLECTURESSECTION ISECTION IISECTION IIIHETEROGENEOUS CATALYSIS OFREDOX REACTIONSACID-BASE HETEROGENEOUS ANDHOMOGENEOUS CATALYSISMETHODS OF INVESTIGATION OF THEMECHANISM OF CATALYTIC REACTIONS
Page 1: Сибирское отделени
Page 5: PLENARY LECTURES
Page 8 and 9: PL-1“nucleophily”, “electroph
Page 10 and 11: PL-2This presentation will focus on
Page 12 and 13: PL-3NOBLE METALS CONTAINING CATALYS
Page 14 and 15: PL-4KINETICS AND MECHANISM OF SELEC
Page 16 and 17: PL-5the possibility of performing s
Page 18 and 19: PL-6MULTINUCLEAR NMR IMAGING IN CAT
Page 23 and 24: KS-I-1THE EFFECTS OF ACTIVE SITE CO
Page 25 and 26: С 2 -С 3 OLEFIN PRODUCTION PATHWA
Page 27 and 28: - process (3) can be important in t
Page 29 and 30: OOOOZ mO OXOO XO nYO O n-2(I) HY(II
Page 31 and 32: KS-I-4В настоящей раб
Page 33 and 34: TAP-APPROACH IN CATALYTIC MECHANISM
Page 35 and 36: KS-I-6pressure study. For this inve
Page 37 and 38: NEW ADVANCED CATALYSTS ON THE BASIS
Page 39 and 40: KS-II-1Многочисленны
Page 41 and 42: KS-II-2The following approaches tha
Page 43 and 44: KS-II-4KINETIC FEATURES AND MECHANI
Page 45 and 46: KS-II-4от характера ли
Page 47 and 48: KS-II-5В работе проана
Page 49 and 50: KS-II-6Me 3 , 1,2,4-Me 3 , Me 4 ).
Page 51 and 52: KS-III-1INTENSITY OF IR-ADSORPTION
Page 53 and 54: APPLICATION OF SURFACE SCIENCE PHYS
Page 55 and 56: KS-III-2преимуществом
Page 57 and 58: KS-III-3ON THE REGULARITIES OF THE
Page 59 and 60: KS-III-3пропилена, то н
Page 61 and 62: KS-III-4K on the same sites that ac
Page 63 and 64: KS-III-5комплекс вопро
Page 65: CAN QUANTUM CHEMISTRY HELP TO TAYLO
Page 69 and 70: OP-I-1MECHANISMS OF HETEROGENEOUS C
Page 71 and 72:
OP-I-2Рис. 1. Зависимос
Page 73 and 74:
CARBON OXIDE HYDROGENATION OVER Fe-
Page 75 and 76:
OP-I-3значения полос
Page 77 and 78:
OP-I-4цеолита, а при с
Page 79 and 80:
IRON EFFECT UPON ALKANES CRACKING O
Page 81 and 82:
OP-I-5На поверхности
Page 83 and 84:
OP-I-6acidity measurements of the H
Page 85 and 86:
OP-I-7Н 2 -D 2 обмен иссл
Page 87 and 88:
OP-I-8NOVEL WAY TO THE SYNTHESIS OF
Page 89 and 90:
OP-I-8глиоксалю - сост
Page 91 and 92:
OP-I-9their intensities, new appear
Page 93 and 94:
OP-I-10activity even with platinum.
Page 95 and 96:
OP-I-10part of CPSS was straightfor
Page 97 and 98:
OP-I-11Однако при гидр
Page 99 and 100:
OP-I-12MOLECULAR MECHANISM OF THE L
Page 101 and 102:
OP-I-12по сравнению с
Page 103 and 104:
OP-I-13over other catalysts in fine
Page 105 and 106:
OP-I-14поперек и под у
Page 107 and 108:
OP-I-15After performing an ageing t
Page 109 and 110:
OP-I-16oxidized to Sn 4+ [4,5]. In
Page 111 and 112:
OP-I-17INFLUENCE OF THE LATTICE OXY
Page 113 and 114:
OP-I-18NEW CATALYST OF LOW-TEMPERAT
Page 115 and 116:
OP-I-19COMPARATIVE STUDY OF METHANE
Page 117 and 118:
OP-I-19syngas selectivity is due to
Page 119 and 120:
OP-I-20EFFECT OF OXYGEN MOBILITY ON
Page 121 and 122:
селективности. В эт
Page 123 and 124:
OP-I-21поликристаллич
Page 125 and 126:
OP-I-22SELECTIVE СО OXIDATION: RE
Page 127 and 128:
OP-I-22Как видно из ри
Page 129 and 130:
OP-I-23установлению к
Page 131 and 132:
OP-I-24CATALYTIC PERFORMANCE OF COP
Page 133 and 134:
OP-I-25MECHANISMS OF METHANE CHLORI
Page 135 and 136:
OP-I-25При исследован
Page 137 and 138:
OP-I-26За модельные мо
Page 139 and 140:
OP-I-27INFLUENCE OF SECOND METAL AD
Page 141 and 142:
OP-I-28ACTIVITY AND DEACTIVATION OF
Page 143 and 144:
OP-I-28а содержание бе
Page 145 and 146:
OP-I-29хлористого вод
Page 147 and 148:
THE MECHANISM OF CHLORINE GENERATIO
Page 149 and 150:
OP-I-30Значения конст
Page 151 and 152:
OP-I-31ТХБ, растворите
Page 153 and 154:
OP-I-32Наряду с хлорид
Page 155 and 156:
CATALYTIC TRANSFORMATIONS OF ALIPHA
Page 157 and 158:
OP-I-34STRONG METAL-SUPPORT INTERAC
Page 159 and 160:
OP-I-34The reduction extent of Ni 2
Page 161 and 162:
OP-I-35impregnating solutions for c
Page 163 and 164:
FEATURES OF CATALYSTS EMPLOYMENT FO
Page 165 and 166:
OP-I-361 - NH 3 (14,5), H 2 S (4,1)
Page 167 and 168:
OP-I-37В условиях реак
Page 169 and 170:
OP-I-38ROLE OF REDOX- AND ACIDIC CE
Page 171 and 172:
OP-I-38Таблица 2. Актив
Page 173 and 174:
OP-I-39Таблица 1. Влиян
Page 175 and 176:
OP-I-40гидроксосилика
Page 177 and 178:
OP-I-41(рис.1). Дегидрир
Page 179 and 180:
PROTON TRANSFER REACTIONSIN TRANSIT
Page 181 and 182:
OP-II-1elucidation of the mechanism
Page 183 and 184:
OP-II-2oscillations of E Pt and pH
Page 185 and 186:
OP-II-3гексана в польз
Page 187 and 188:
OP-II-3более мягкий пу
Page 189 and 190:
R 1OCa 2+OH -OHR 2Рис. 1. Пер
Page 191 and 192:
STUDY OF THE MECHANISM OF CATALYTIC
Page 193 and 194:
MECHANISM OF PHENOL AND ANILINE ALK
Page 195 and 196:
OP-II-7MECHANISM OF FORMATION OF HY
Page 197 and 198:
OP-II-8CATALYTIC AND PHYSICOCHEMICA
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OP-II-8To sum up we can say that Pt
Page 201 and 202:
OP-II-9величины изоме
Page 203 and 204:
OP-II-9увеличением со
Page 205 and 206:
OP-II-10the second metal are still
Page 207 and 208:
OP-II-11которых химизм
Page 209 and 210:
OP-II-116. Co(Ni)Mo-катализ
Page 211 and 212:
OP-II-12гг-1, которая от
Page 213 and 214:
OP-II-13ROLE OF THE SOLVENT IN THE
Page 215 and 216:
OP-II-14KINETICS AND MECHANISM OF P
Page 217 and 218:
O 2H 2 OFeX 2FeX 3I 2HIBuOHP n , Zn
Page 219 and 220:
OP-II-15capable of asymmetric oxida
Page 221 and 222:
OP-II-16Систематическ
Page 223 and 224:
OP-II-17MECHANISM OF ETHYLENE METHO
Page 225 and 226:
OP-II-18MECHANISM OF LIQUID-PHASE C
Page 227 and 228:
OP-II-18катализатора и
Page 229 and 230:
OP-II-19Основным недос
Page 231 and 232:
OP-II-19Литература:1 Шн
Page 233 and 234:
OP-II-20Surprising is the finding t
Page 235 and 236:
OP-II-21ºC) [7]. Полученн
Page 237 and 238:
OP-II-21Настоящая рабо
Page 239 and 240:
OP-II-22W(VI), Ti(IV), Re(VII), х
Page 241 and 242:
OP-II-23MECHANISM OF ACTIVATION AND
Page 243 and 244:
OP-II-23содержащей сис
Page 245 and 246:
2+2+OP-II-24O25 31 (R=Me)OORD 2/ Ru
Page 247 and 248:
OP-II-25ASYMMETRIC HYDROGENATION OF
Page 249 and 250:
MECHANISM OF TRIMETHYLPENTANE AND D
Page 251 and 252:
OP-II-26СХЕМА 3. Наибол
Page 253 and 254:
OP-II-27диенофилов - ма
Page 255 and 256:
OP-II-28H 2 MoO 4 и FeMoO 4 поз
Page 257 and 258:
OP-II-29THE CATALYTIC ACTION OF AMM
Page 259 and 260:
OP-II-29Как и в случае
Page 261 and 262:
THE KINETICS AND MECHANISM OF P-TOL
Page 263 and 264:
OP-II-30PhCH-CH 2O+SHKk1 +PhCH-CH 2
Page 265 and 266:
OP-II-31Согласно данны
Page 267 and 268:
OP-II-32TRANSFORMATION OF SULFUR OR
Page 269 and 270:
Рисунок 1OP-II-32269
Page 271 and 272:
OP-II-33скорость образ
Page 273 and 274:
FCC GASOLINE SULFUR REDUCTION ADDIT
Page 275 and 276:
OP-II-35NOVEL HETEROGENIZED NICKEL
Page 277 and 278:
OP-II-35повышена до 60-80
Page 279 and 280:
OP-II-36provide stable experimentat
Page 281 and 282:
DISCRIMINATION OF KINETIC MODELS OF
Page 283 and 284:
OP-II-37Однако при уве
Page 285 and 286:
OP-II-38Для этих систе
Page 287 and 288:
OP-II-39раскрывается п
Page 289 and 290:
OP-II-40TITANIUM-MAGNESIUM CATALYST
Page 291 and 292:
OP-II-41MECHANISM OF BUTADIENE POLY
Page 293 and 294:
OP-II-41Нами установле
Page 295 and 296:
OP-II-42тщательно пром
Page 297 and 298:
OP-II-43обрыва или пер
Page 299 and 300:
OP-II-44MECHANISMS OF HIGHER α-OLE
Page 301 and 302:
OP-II-44С учётом разни
Page 303 and 304:
OP-II-45сополимеры, пр
Page 305 and 306:
OP-III-1Разбавление аз
Page 307 and 308:
OP-III-1Из таблицы 1 ви
Page 309 and 310:
OP-III-2OPERANDO INFRARED STUDY OF
Page 311 and 312:
OP-III-2with formation of diketene
Page 313 and 314:
OP-III-3С этих позиций
Page 315 and 316:
OP-III-4центров двух т
Page 317 and 318:
OP-III-5аналогов, соде
Page 319 and 320:
OP-III-6QUANTUM-CHEMICAL STUDY OF T
Page 321 and 322:
OP-III-6Hn(H 2 C) ON BHH 3 BBH 3HPh
Page 323 and 324:
OP-III-7положения заме
Page 325 and 326:
OP-III-8поверхностног
Page 327 and 328:
OP-III-9поверхностных
Page 332 and 333:
OP-III-11THERMODYNAMIC CHARACTERIST
Page 334 and 335:
OP-III-11which corresponds to ΔS°
Page 336 and 337:
OP-III-12i[ Cp2ZrHCl⋅2] 2iiX6= HA
Page 338 and 339:
OP-III-13MOLECULAR MECHANISM OF 1,2
Page 340 and 341:
OP-III-13changes to the formation o
Page 342 and 343:
OP-III-14Рис. Синергиче
Page 344 and 345:
OP-III-15Содержание во
Page 346 and 347:
OP-III-16XPS AND NEXAFS IN-SITU INV
Page 348 and 349:
OP-III-17THERMAL STABILITY OF GOLD
Page 350 and 351:
OP-III-17Там, где спека
Page 352 and 353:
OP-III-18Окисление Н 2 .
Page 354 and 355:
OP-III-18режима протек
Page 356 and 357:
OP-III-19палладия адсо
Page 358 and 359:
OP-III-20THE ADSORBED OXYGEN SPECIE
Page 360 and 361:
OP-III-20Воздействие н
Page 362 and 363:
OP-III-21and selective oxidation of
Page 364 and 365:
OP-III-22STM/XPS STUDY OF MODEL CAT
Page 366 and 367:
OP-III-22Разработанная
Page 368 and 369:
OP-III-23Образцы редко
Page 370 and 371:
OP-III-24IN SITU GAS-PHASE X-RAY PH
Page 372 and 373:
OP-III-24Перед каталит
Page 374 and 375:
OP-III-25width ΔH = 7-100G. The pa
Page 376 and 377:
OP-III-26структуры, но
Page 378 and 379:
OP-III-27скорости реак
Page 380 and 381:
OP-III-28STUDIES OF THE MECHANISM O
Page 382 and 383:
OP-III-28и (iv) повторной
Page 384 and 385:
OP-III-29При Т
Page 386 and 387:
OP-III-30ACTIVE PHASE TRANSFORMATIO
Page 388 and 389:
OP-III-30- Au, above 650° and for
Page 390 and 391:
OP-III-31с участием раз
Page 392 and 393:
OP-III-32- high-activity zone - in
Page 394 and 395:
OP-III-33MATHEMATICAL MODEL OF THE
Page 396 and 397:
OP-III-33a) b)Temperature [K]Pressu
Page 398 and 399:
OP-III-34В настоящем со
Page 400 and 401:
OP-III-35кластера имее
Page 402 and 403:
OP-III-36APPLICATION OF MULTINUCLEA
Page 404 and 405:
OP-III-36simultaneous occurrence of
Page 406 and 407:
OP-III-37металлических
Page 408 and 409:
OP-III-38METHODS FOR INVESTIGATION
Page 410 and 411:
OP-III-39CIDNP IN ANALYSIS OF RADIC
Page 412 and 413:
OP-III-39солей переход
Page 414 and 415:
OP-III-40similar π-alkyne CpNi( Ph
Page 416 and 417:
OP-III-41взаимодействи
Page 419 and 420:
MECHANISM OF ARYLHALIDES CATALYTIC
Page 421 and 422:
YP-1Из полученных да
Page 423 and 424:
YP-2В развитие указа
Page 425 and 426:
INVESTIGATION OF THE INFLUENCE OF C
Page 427 and 428:
Таблица 1. Диаметр п
Page 429 and 430:
YP-4При использовани
Page 431 and 432:
YP-5В этой связи пред
Page 433 and 434:
N-PENTANE ISOMERIZATION AT THE SUPE
Page 435 and 436:
CYCLOHEXANOL CONVERTION OVER Cu-CON
Page 437 and 438:
YP-7основных центров
Page 439 and 440:
YP-8Разработана преп
Page 441 and 442:
YP-9размер наночасти
Page 443 and 444:
YP-10фольги очищалас
Page 445 and 446:
YP-11STUDIES OF SELECTIVE HETEROGEN
Page 447 and 448:
YP-11быстрее потенци
Page 449 and 450:
YP-12водорода происх
Page 451 and 452:
YP-13CATALYTIC ACTIVITY AND PHYSICO
Page 453 and 454:
YP-13Hydrogen consumption [a.u.]543
Page 455 and 456:
KS-I-6 Zemlyanov D., Aszalos-Kiss B
Page 457 and 458:
OP-I-8 Magaev O.V., Fedotova M.P.,
Page 459 and 460:
OP-I-30 Rozdyalovskaya T.A., Chudin
Page 461 and 462:
OP-II-12 Lavrenov A.V., Duplyakin V
Page 463 and 464:
OP-II-37 Балаев А.В., Гр
Page 465 and 466:
OP-III-16 Beloshapkin S., Zemlianov
Page 467 and 468:
OP-III-40 Saraev V.V., Kraikivskii
Page 469:
VII РОССИЙСКАЯ КОНФЕ
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