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AMMONIUM SULFATE CAS N°: 7783-20-2

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OECD SIDS<br />

<strong>AMMONIUM</strong> <strong>SULFATE</strong><br />

For freshwater fish, the greatest sensitivity to ammonium sulfate was shown by alevins of<br />

Oncorhynchus gorbuscha before complete yolk absorption, with effects on the length and weight of<br />

fry at migration seen at a LOEC (61 d) of 22 mg/l (NH 4 ) 2 SO 4 (calculated from 2.4 ppb NH 3 ). The<br />

associated NOEC (61 d) is 11 mg/l (NH 4 ) 2 SO 4 (calculated from 1.2 ppb NH 3 ) (Rice and Bailey,<br />

1980). Exposure of the catfish Channa punctatus to commercial ammonium sulfate fertilizer at<br />

100 mg/l showed significant effect on ovarian growth, and also on testicular development, where<br />

spermatogenesis did not process beyond the spermatocyte stage, and sperm was totally absent. In<br />

this experiment correlative histological changes were also observed in the pituitary gonadotrophes<br />

(Ram and Sathyanesan, 1986, 1987).<br />

Table 6 Toxicity of ammonium sulfate to fish in long term tests<br />

Species<br />

Pimephales<br />

promelas<br />

(fresh water)<br />

Pimephales<br />

promelas<br />

(fresh water)<br />

Oncorhynchus<br />

gorbuscha<br />

(fresh water)<br />

Channa<br />

punctatus<br />

(fresh water)<br />

Channa<br />

punctatus<br />

(fresh water)<br />

Clarias<br />

batrachus<br />

Test<br />

Type<br />

Flow<br />

through<br />

Flow<br />

through<br />

Flow<br />

through<br />

Semistatic<br />

Semistatic<br />

Semistati<br />

c<br />

Exposure<br />

Period<br />

pH<br />

Temp.<br />

[° C]<br />

Effect, mg (NH 4 ) 2 SO 4 /l<br />

10 days 7.3 <strong>20</strong> ± 1 Length and weight of young<br />

fish:<br />

NOEC = 300<br />

LOEC = 531<br />

10 days 7.2 <strong>20</strong> ± 1 Length and weight of young<br />

fish:<br />

NOEC = 603<br />

LOEC= 1021<br />

61 days 6.3-<br />

6.5<br />

3.7-4.8 Length and weight of fry at<br />

migration.<br />

NOEC = 11<br />

LOEC= 22<br />

6 months 7.2 <strong>20</strong> to 35 Ovarian growth<br />

LOEC: 100 mg/l:<br />

6 months 7.2 Testicular development:<br />

LOEC: 100 mg/l<br />

Reference<br />

Nebeker and<br />

Schuytema, <strong>20</strong>00<br />

Nebeker and<br />

Schuytema, <strong>20</strong>00<br />

Rice and Bailey,<br />

1980<br />

Ram and<br />

Sathyanesan,<br />

1986<br />

Ram and<br />

Sathyanesan,<br />

1987<br />

12 month 7 LOEC = 100 mg/l Sathyanesan AG<br />

et al., 1978<br />

No data is available for chronic toxicity to invertebrates.<br />

Chronic toxicity to algae is discussed together with acute toxicity above.<br />

Toxicity to Aquatic Species Conclusions<br />

Freshwater Environment<br />

Information on acute toxicity in aquatic freshwater systems is available from all three trophic levels,<br />

fish, invertebrates, and algae. Fish are the most sensitive trophic level, with the most sensitive<br />

species being juvenile Salmo gairdneri (Thurston and Russo, 1983), with an LC 50 (96 h) of ca.<br />

173 mg/l. For invertebrates, the lowest LC 50 (24 h)of 393 mg/l is observed for juveniles of the<br />

32<br />

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